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Bulk polymerization of isoprene in apparatuses with a fixed bed of the reaction mixture

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Abstract

The possibility of the bulk polymerization of isoprene in the presence of a rare-earth catalyst in apparatuses with a fixed bed of the reaction mixture is investigated. The efficiency of polymerization in the apparatus of a disc construction with a thin reaction-mixture bed providing near-isothermic conditions, a high rate of the process, simple regulation of the thermal mode, and a high content of cis-1,4 units in poly-isoprene is shown.

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Authors and Affiliations

  1. Research Institute of Synthetic Rubber, Gapsal’skaya ul. 1, St. Petersburg, 198035, Russia

    V. V. Elfimov

  2. St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    A. V. Markov & Yu. P. Yulenets

Authors
  1. V. V. Elfimov
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  2. A. V. Markov
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  3. Yu. P. Yulenets
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Corresponding author

Correspondence to A. V. Markov.

Additional information

Original Russian Text © V.V. Elfimov, A.V. Markov, Yu.P. Yulenets, 2016, published in Vysokomolekulyarnye Soedineniya. Ser. B, 2016, Vol. 58, No. 3, pp. 238–245.

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Elfimov, V.V., Markov, A.V. & Yulenets, Y.P. Bulk polymerization of isoprene in apparatuses with a fixed bed of the reaction mixture. Polym. Sci. Ser. B 58, 284–291 (2016). https://doi.org/10.1134/S1560090416030052

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  • DOI: https://doi.org/10.1134/S1560090416030052

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