Abstract
This paper presents the results of the synthesis and investigation of the thermal behavior of borate Ba3Eu2(BO3)4 according to the powder high temperature X-ray data. The coefficients of thermal expansion are calculated. The relationship between expansion and the crystalline structure is described.
Similar content being viewed by others
REFERENCES
Khamaganova, T.N., Structural specific features and properties of alkaline-earth and rare-earth metal borates, Russ. Chem. Bull., 2017, no. 2, pp. 187–200.
Huang, X., Solid-state lighting: Red phosphor converts white LEDs, Nat. Photon., 2014, no. 8, p. 748.
Mondal, K., Singh, D.K., and Manam, J., Spectroscopic behavior, thermal stability and temperature sensitivity of Ca2SiO4:Eu3+ red emitting phosphor for solid state lighting application, J. Alloys Compd., 2018, vol. 761, pp. 41–51.
Blistanov, A.A., Kristally kvantovoi i nelineinoi optiki (Crystals of Quantum and Nonlinear Optics), Moscow: Mosk. Inst. Stali Splavov, 2000.
Filatov, S.K., Biryukov, Y.P., Bubnova, R.S., and Shablinskii, A.P., The novel borate Lu5Ba6B9O27 with a new structure type: Synthesis, disordered crystal structure and negative linear thermal expansion, Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 2019, vol. 75, pp. 697–703.
Biryukov, Y.P., Bubnova, R.S., Krzhizhanovskaya, M.G., and Filatov, S.K., Structure refinement and thermal properties of novel cubic borate Lu2Ba3B6O15, Mater. Chem. Phys., 2019, vol. 229, pp. 355–361.
Kolesnikov, I.E., Bubnova, R.S., Povolotskiy, A.V., Biryukov, Y.P., and Povolotckaia, A.V., Shorets, O.Yu., and Filatov, S.K., Europium-activated phosphor Ba3Lu2B6O15: Influence of isomorphic substitution on photoluminescence properties, Ceram. Int., 2021, vol. 47, no. 6, pp. 8030–8034.
Chen, X., Zhao, L., Chang, X., and Xiao, W., Syntheses, crystal structures, vibrational spectra, and luminescent properties of M3Eu2(BO3)4 (M = Ba, Sr), J. Solid State Chem., 2020, vol. 283, p. 121163.
Cong, R., Zhou, Z., Li, Q., Sun, J., Lin, J., and Yang, T., Approaching the structure of REBaB9O16 (RE = rare earth) by characterizations of its new analogue Ba6Bi9B79O138, J. Mater. Chem., 2015, pp. 1–7.
Pan, J., Lin, Z., Hu, Z., Zhang, L., and Wang, G., Crystal growth and spectral properties of Yb3+: Sr3La2(BO3)4 crystal, Opt. Mater., 2006, vol. 12, pp. 250–254.
Zhang, Y., Lin, Z., Hu, Z., and Wanga, G., Growth and spectroscopic properties of Nd3+-doped Sr3Y2(BO3)4 crystal, J. Solid State Chem., 2004, vol. 177, pp. 3183–3186.
He, L. and Wang, Y., Synthesis of Sr3Y2(BO3)4:Eu3+ and its photoluminescence under UV and VUV excitation, J. Alloys Compd., 2007, vol. 431, pp. 226–229.
Mill, B.V., Tkachuk, A.M., Belokoneva, E.L., Ershova, G.I., Mironov, D.I., and Razumova, I.K., Spectroscopic studies of Ln2Ca3B4O12 (Ln =Y, La, Gd) crystals, J. Alloys Compd., 1998, pp. 291–294.
Tu, C., Wang, Y., You, Z., Li, J., Zhu, Z., and Wu, B., The growth and spectroscopic characteristics of Ca3Y2(BO3)4:Er3+ laser crystal, J. Cryst. Growth, 2004, vol. 260, pp. 410–413.
Bubnova, R.S., Firsova, V.A., Volkov, S.N., and Filatov, S.K., Rietveldtotensor: Program for processing powder X-ray diffraction data under variable conditions, Glass Phys. Chem., 2018, vol. 44, no. 1, pp. 33–40.
Momma, K. and Izumi, F., VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data, J. Appl. Crystallogr., 2011, vol. 44, pp. 1272–1276.
Volkov, S.N., Bubnova, R.S., and Filatov, S.K., Synthesis, crystal structure and thermal expansion of a novel borate, Ba3Bi2(BO3)4, Z. Kristallogr., 2013, vol. 228, pp. 436–443.
Reuther, C., Doctoral Dissertation, Freiberg: Tech. Univ. Bergakademie, 2013.
Shablinskii, A.P., Bubnova, R.S., and Kolesnikov, I.E., Novel Sr3Bi2(BO3)4:Eu3+ red phosphor: Synthesis, crystal structure, luminescent and thermal properties, Solid State Sci., 2017, pp. 1–22.
Kosyl, K.M., Paszkowicz, W., Shekhovtsov, A.N., Kosmyna, M.B., Antonowicz, J., Olczak, A., and Fitch, A.N., Variation of cation distribution with temperature and its consequences on thermal expansion for Ca3Eu2(BO3)4, Acta Crystallogr., 2020, vol. 76, pp. 554–562.
Bubnova, R.S. and Filatov, S.K., Vysokotemperaturnaya kristallokhimiya boratov i borosilikatov (High-Temperature Crystal Chemistry of Borates and Borosilicates), St. Petersburg: Nauka, 2008.
ACKNOWLEDGMENTS
The authors are grateful to Associate Professor M.G. Krzhizhanovskaya, Cand. Sci. (Geol. Mineral.), for high temperature X-ray powder diffraction measurements. The X-ray studies were carried out at the resource center “X-Ray Diffraction Research Methods” of the St. Petersburg State University.
Funding
This study was carried out as part of a state assignment (no. 0097-2019-0013, Institute of Silicate Chemistry, Russian Academy of Sciences) of the Ministry of Science and Higher Education and the Russian Foundation for Basic Research (project no. 18-29-12106).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Rights and permissions
About this article
Cite this article
Demina, S.V., Shablinskii, A.P., Bubnova, R.S. et al. Thermal Expansion of Borate Ba3Eu2(BO3)4. Glass Phys Chem 47, 722–725 (2021). https://doi.org/10.1134/S1087659621060055
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1087659621060055