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Delocalization energy of atoms in inorganic glass

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Abstract

For multicomponent sheet and lead glass, the delocalization energy of Δε e atoms is calculated from the experimental data on viscosity. It is shown that the value of Δε e remains constant in sufficiently broad temperature range in the glass transition region. The results are in good agreement with the calculation on the formula of the model of delocalized atoms, which includes the glass transition temperature and fraction of fluctuating volume frozen at this temperature.

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References

  1. Nemilov, S.V., Valence-configuration theory of viscous flow of supercooled glass-forming liquids and its experimental study, Fiz. Khim. Stekla, 1978, vol. 4, no. 2, pp. 129–148.

    Google Scholar 

  2. Nemilov, S.V., Thermodynamic and Kinetic Aspects of the Vitreous State, Boca Raton, FL: CRC Press, 1995.

    Google Scholar 

  3. Filippovich, V.N., Vacancy-diffusion theory of viscosity of glass and its application to silica glass, Fiz. Khim. Stekla, 1975, vol. 1, no. 3, pp. 256–263.

    Google Scholar 

  4. Filippovich, V.N. and Kalinina, A.M., On the nature and relationship of changes in the properties of glasses at the glass transition, in Stekloobraznoe sostoyanie (Glassy State), Leningrad: Nauka, 1971, pp. 28–34.

    Google Scholar 

  5. Sanditov, D.S. and Munkueva, S.B., Temperature dependence of the viscous flow of glass-forming melts in a broad temperature range, Glass Phys. Chem., 2016, vol. 42, no. 2, pp. 135–140.

    Article  Google Scholar 

  6. Sanditov, D.S., Munkueva, S.B., Mashanov, A.A., and Sanditov, B.D., Temperature behavior of the free activation energy of viscous flow of glass-forming melts in a wide temperature range, Glass Phys. Chem., 2012, vol. 38, no. 4, pp. 379–385.

    Article  Google Scholar 

  7. Sanditov, D.S., Deformation-activation model of viscous flow of glass-forming liquids, J. Non-Cryst. Solids, 2014, vol. 400, pp. 12–20.

    Article  Google Scholar 

  8. Sanditov, D.S., Model of delocalized atoms in the physics of the vitreous state, JETP, 2012, vol. 115, no. 1, pp. 112–124.

    Article  Google Scholar 

  9. Sanditov, D.S. and Badmaev, S.S., Delocalization of the atom in glass and its liquids, Glass Phys. Chem., 2015, vol. 41, no. 5, pp. 460–466.

    Article  Google Scholar 

  10. Bartenev, G.M. and Sanditov, D.S., Relaksatsionnye protsessy v stekloobraznykh sistemakh (Relaxation Processes in Glassy Systems), Novosibirsk: Nauka, 1986.

    Google Scholar 

  11. Damdinov, D.G., Stress relaxation in non-stabilized oxide glasses, Cand. Sci. (Chem.) Dissertation, Leningrad: Inst. Silicate Chem., Acad. Sci. USSR, 1986.

    Google Scholar 

  12. Sanditov, D.S. and Mashanov, A.A., Mathematical treatment of experimental data on the viscosity of glass melts in a wide temperature range, Glass Phys. Chem., 2010, vol. 36, no. 1, pp. 41–44.

    Article  Google Scholar 

  13. Ferry, J.D., Viscoelastic Properties of Polymers, New York: Wiley, 1970.

    Google Scholar 

  14. MDL® SciGlass-7.8. Institute of Theoretical Chemistry, Shrewsbury, MA, 2012. www.sciglass.info.

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Correspondence to D. S. Sanditov.

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Original Russian Text © D.S. Sanditov, M.V. Darmaev, A.A. Mashanov, 2016, published in Fizika i Khimiya Stekla.

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Sanditov, D.S., Darmaev, M.V. & Mashanov, A.A. Delocalization energy of atoms in inorganic glass. Glass Phys Chem 42, 445–448 (2016). https://doi.org/10.1134/S1087659616050138

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  • DOI: https://doi.org/10.1134/S1087659616050138

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