Abstract
Fluorozirconate glass, considered as the most stable heavy metal fluoride glass and excellent host for rare earth ions, has been extensively used for 2.7 μm laser materials due to its low intrinsic loss, wide transparency window, and small phonon energy. In this paper, a novel erbium ion doped fluorozirconate glass was prepared, 2.7 μm emission properties, thermal stability and Raman spectra were investigated and the spontaneous transition probability and branching ratio were calculated and analyzed. It was found that the thermal stability was greatly improved due to the ΔT increased from 59 to 89°C after introducing YF3 on the basis of ZBLA(ZrF4-BaF2-LaF3-AlF3). In addition, intensive 2.7 μm emission was observed and the present sample with the addition of Y3+ possessed larger 2.7 μm emission cross section (1.12 × 10−20 cm2) which indicated that this kind of fluoride glasses could potentially be used as an efficient gain media in the 2.7 μm fiber laser system.
Similar content being viewed by others
References
Yang, S., Wang, X., Guo, H., Dong, G., Peng, B., Qiu, J., Zhang, R., and Shi, Y., Broadband near-infrared emission in Tm3+Dy3+-codoped amorphous chalcohalide films fabricated by pulsed laser deposition, Opt. Express, 2011, vol. 19, no. 27, pp. 26529–26535.
Guoying Zhao, Ying Tian, Huiyan Fan, Junjjie Zhang, Lili Hu, Efficient 2.7 μm emission in Er3+-doped bismuth germanate glass pumped by 980 nm laser diode, Chin. Opt. Lett, 2012, vol. 10, no. 9, pp. 09160101–09160103.
Guo, Y., Li, M., Hu, L., and Zhang, J., Intense 2.7-μm emission and structural origin in Er3+-doped bismuthate (Bi2O3GeO2Ga2O3Na2O) glass, Opt. Lett., 2012, vol. 37, no. 2, pp. 268–270.
Xu, R., Tian, Y., Hu, L., and Zhang, J., Enhanced emission of 2.7-μm pumped by laser diode from Er3+/Pr3+-codoped germanate glasses, Opt. Lett., 2011, vol. 36, no. 7, pp. 1173–1175.
Haoyang Hu, Haipiang Xia, and Jianxu Hu, Intense 2.7 μm emission from Er3+/Tm3+/Pr3+ triply doped LiYF4 single crystal grown by Bridgman method, J. Alloys. Compd, 2013, vol. 573, no. 5, pp. 187–191.
Rousong Wang, Xiangwei Meng, Feixiang Yin, Yan Feng, Guanshi Qin, and Weiping Qin, Heavily erbiumdoped low-hydroxyl fluorotellurite glassses for 2.7 μm laser applications, Opt. Mater. Express, vol. 3, no. 8, pp. 1127–1136.
Zhong, H., Chen, Ch., Ren, G., Cheng, L., Yao, L., and Sun, J., 2.7-μm emission of Nd3+, Er3+-codoped tellurite glass, J. Appl. Phys., 2009, vol. 106, no. 8, pp. 083114–083114.
Chio, Y.G., Kim, K.H., Lee, B.J., Shin, Y.B., Kim, Y.S., and Heo, J., Emission properties of the Er3+ÅF4I11/2 4I13/2 transition in Er3+ and Er3+/Tm3+-doped Ge-Ga-As-S glasses, J. Non-Cryst. Solids, 2000, vol. 278, nos. 1–3, pp. 137–144.
Shigeki Tokita, Mayu Hirokane, Masanao Murakami, Seiji Shimizu, Masaki Hashida, and Shuji Sakabe, Stable 10 W Er: ZBLAN fiber laser operating at 2.71–2.88 μm, Opt. Lett., 2010, vol. 35, no. 23, pp. 3943–3945.
Zhu, X. and Peyghambarian, N., High-power ZBLAN glass fiber lasers: Review and prospect, Adv. OptoElectron., 2010, vol. 2010, pp. 1–23.
Trnovcová, V., Zakalyukin, R.M., Sorokin, N.I., Lezal, D., Fedorov, P.P., Illeková, E., Ozvoldová, M., Skubla, A., and Sobolev, B.P., Physical properties of multicomponent fluoride glasses for photonic and superionic applications, Ionics, 2001, vol. 7, nos. 4–6, pp. 456–462.
Rongrong Xu, Ying Tian, Meng Wang, Lili Hu, and Junjie Zhang, Investigation on broadband near-infrared emission and energy transfer in Er3+-Tm3+-codoped germanate glasses, Opt. Mater., 2011, vol. 33, no. 3, pp. 299–302.
Lebullenger, R., Benjaballah, S., Le Deit, C., and Poulain, M., Systematic substitutions in ZBLA and ZBLAN glasses, J. Non-Cryst. Solids, 1993, vol. 161, pp. 217–221.
Rigout, N., Adam, J.L., and Lucas, J., Chemical and physical compatibilities of fluoride and fluorophosphate glasses, J. Non-Cryst. Soilds, 1995, vol. 184, pp. 319–323.
Yan, Y., Faber, A.J., and de Waal, H., Luminescence quenching by OH groups in highly Er-doped phosphate glasses, J. Non-Cryst. Solids, 1995, vol. 181, no. 3, pp. 283–290.
Ying Tian, Rongrong Xu, Lili Hu, and Junjie Zhang, 2.7-μm fluorescence radiative dynamics and energy transfer between Er3+ and Tm3+ ions in fluoride glass under 800 nm and 980 nm excitation, J. Quant. Spectrosc. Radiat. Transfer, 2012, vol. 113, no. 1, pp. 87–95.
Shan Guan, Ying Tian, Yanyan Guo, Lili Hu, and Junjie Zhang, Spectroscopic properties and energy transfer processes in Er3+/Nd3+ co-doped tellurite glass for 2.7-μm laser materials, Chin. Opt. Lett., 2012, vol. 10, no. 7, pp. 071603–071607.
Almeida, R.M. and Mackenzie, J.D., Vibrational spectra and structure of fluorozirconate glasses, J. Chem. Phys., 1981, vol. 74, no. 11, pp. 5954–5961.
Almeida, R.M. and Mackenzie, J.D., A Structural interpretation of the vibrational spectra of binary fluorohafnate glasses, J. Chem. Phys., 1983, vol. 78, no. 11, pp. 6502–6513.
Aimeida, R.M., Vibrational spectroscopy of glasses, J. Non-Cryst. Soilds, 1988, vol. 106. no. 1–3, pp. 347–358.
Xin Wang, Lili Hu, Kefeng Li, Ying Tian, and Sijun Fan, Spectroscopic properties of thulium ions in bismuth silicate glass, Chin. Opt. Lett., 2012, vol. 10, no. 10, pp. 10160101–10160105.
Schweizer, T., Hewak, D.W., Samson, B.N., and Payne, D.N., Spectroscopic data of the 1.8-, 2.9-, and 4.3-μm transitions in dysprosium-doped gallium lanthanum sulfide glass, Opt. Lett., 1996, vol. 21, no. 19, pp. 1594–1596.
Xiangtan Li, and Xueqiang Liu, Emission enhancement in Er3+/Pr3+-codoped germanate glasses and their use as a 2.7 μm laser material, Chin. Opt. Lett., 2013, vol. 11, no. 12, pp. 12160101–12160103.
Koetke, J. and Huber, G., Infrared excited-state absorption and stimulated-emission cross sections of Er3+-doped crystals, Appl. Phys. B, 1995, vol. 61, no. 2, pp. 151–158.
Louis, M., Hubert, S., Simoni, E., and Gesland, J.Y., Energy transfer between lanthanide and actinide ions in LiYF4, Opt. Mater., 1996, vol. 6, no. 3, pp. 121–127.
Lin, H., Chen, D., Yu, Y., Yang, A., and Wang, Y., Enhance mid-infrared emissions of Er3+ at 2.7 μm via Nd3+ sensitization in chalcohalide glass, Opt. Lett., 2011, vol. 36, no. 10, pp. 1815–1817.
Ivanova, S. and Pelle, F., Strong 1.53 to NIR-VIS-UV upconversion in Er-doped uoride glass for high-efficiency solar cells, J. Opt. Soc. Am. B, 2009, vol. 26, no. 10, pp. 1930–1938.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Huang, F., Guo, Y., Ma, Y. et al. 2.7 μm Emission properties of Er3+ doped fluorozirconate glass. Glass Phys Chem 40, 277–282 (2014). https://doi.org/10.1134/S1087659614030067
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1087659614030067