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Ore Mineralization in Ultramafic and Metasomatic Rocks of the Ospin–Kitoi Massif, Eastern Sayan

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Abstract

In the Ospin–Kitoi ultramafic massif of the Eastern Sayan, accessory and ore Cr-spinel are mainly represented by alumochromite and chromite. Copper–nickel mineralization hosted in serpentinized ultramafic rocks occurs as separate grains of pentlandite and pyrrhotite, as well as assemblages of (i) hexagonal pyrrhotite + pentlandite + chalcopyrite and (ii) monoclinal pyrrhotite + pentlandite + chalcopyrite. Copper mineralization in rodingite is presented by bornite, chalcopyrite, and covellite. Talc–breunnerite–quartz and muscovite–breunnerite–quartz listvenite contains abundant sulfide and sulfoarsenide mineralization: pyrite, gersdorffite, sphalerite, Ag–Bi and Bi-galena, millerite, and kuestelite. Noble metal mineralization is represented by Ru–Ir–Os alloy, sulfides, and sulfoarsenides of these metals, Au–Cu–Ag alloys in chromitite, laurite intergrowth, an unnamed mineral with a composition of Cu3Pt, orcelite in carbonized serpentinite, and sperrylite and electrum in serpentinite. Sulfide mineralization formed at the late magmatic stage of the origination of intrusion and due to fluid–metamorphic and retrograde metasomatism of primary rocks.

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References

  • Ahmed, A.H. and Arai, S., Platinum-group minerals in podiform chromitites of the Oman ophiolite, Can. Mineral., 2003, vol. 41, pp. 597–616.

    Article  Google Scholar 

  • Antsiferova, T.N., Compositional peculiarities of oreforming and accessory minerals of hyperbasites of the Ospin Massif, East Sayan, Problemy geologii i osvoeniya nedr: Trudy Tret’ego Mezhdunar. nauch. simp. studentov, aspirantov i molodykh uchenykh im. akademika M.A. Usova (Problems of Geology and Interior Development. Proceedings of 3rd International Academician M.A. Usov Conference of Students, Post-Graduate Students, and Youth Scientists), Tomsk, 1999a, pp. 56–57.

    Google Scholar 

  • Antsiferova, T.N., Typomorphism of Cr-spinels of the Ospin–Kitoi massif, East Sayan, Geologiya i geodinamika Evrazii: Mater. XVIII Vseross. molodezhnoi konf. (Geology and Geodynamics of Euraisa. Proceedings of 18th All-Russian Youth Conference), Irkutsk, 1999b, p. 88.

    Google Scholar 

  • Antsiferova, T.N., Plastic deformations as factor determining the composition of accessory Cr-spinels of hyperbasites: evidence from the Ospin massif, in Petrologiya magmaticheskikh i metamorficheskikh kompleksov: Mater. nauch. konf., posvyashch. 80-letiyu so dnya rozhdeniya professora M.P. Kortusova (Petrology of Magmatic and Metamorphic Complexes. Proceedings of Conference Devoted to the 80th Anniversary of Professor M.P. Kortusov), Tomsk, 2001, pp. 282–287.

    Google Scholar 

  • Arai, S. and Akizawa, N., Precipitation and dissolution of chromite by hydrothermal solutions in the Oman ophiolite: new behavior of Cr and chromite, Am. Mineral., 2014, vol. 99, pp. 28–34.

    Article  Google Scholar 

  • Auge, T., Platinum-group minerals inclusions in chromitites from the Oman ophiolite, Bull. Mineral., 1986, vol. 109, pp. 301–304.

    Google Scholar 

  • Auge, T., Platinum-group minerals in the Tiebaghi and Vourinos ophiolitic complexes: genetic implication, Can. Mineral., 1988, vol. 26, pp. 177–192.

    Google Scholar 

  • Bai, W., Robinson, P.T., Fang, Q., et al. The PGE and base-metal alloys in the podiofirm chromitites of the Luobusa ophiolite, southern Tibet, Can. Mineral., 2000, vol. 38, pp. 585–598.

    Article  Google Scholar 

  • Constantinides, C.C., Kingston, G.A., and Fisher, P.C., The occurrence of platinum-group minerals in chromitites of the Kokkinorostos chrom main, Cyprus, in Ophiolites. Proc. Int. Ophiolite Symposium, Panayiotou, A., Eds., Cyprus, 1980, pp. 93–101.

    Google Scholar 

  • Damdinov, B.B., Noble metal metallogeny of Eastern Sayan ophiolite complex, in Ul’trabazit-bazitovye kompleksy skladchatykh oblastei i ikh minerageniya: Mater. IV mezhdunar. konf. i III molodezhnoi shkoly seminara (Ultrabasite–Basite Complexes of Fold Systems and their Metallogeny), Ulan-Ude, 2012, pp. 49–51.

    Google Scholar 

  • Damdinov, B.B., Zhmodik, S.M., Mironov, A.G., and Ochirov, Yu.Ch., No.ble metal mineralization in rodingites of the southeastern East Sayan, Russ. Geol. Geophys., 2004, vol. 45, no. 5, pp, 577–587.

    Google Scholar 

  • Distler, V.V., Kryachko, V.V., and Laputina, I.P., Evolution of PGM parageneses in Alpine-type hyperbasites, Geol. Rudn. Mestorozhd., 1986, no. 5, pp. 16–33.

    Google Scholar 

  • Distler, V.V., Volchenko, V.A., Kryachko, V.V., Elpyshev, G.A., and Merkulov, G.A., Platinum-group minerals in chromites of the Kempirsai massif, South Urals, Izv. Akad. Nauk SSSR, Ser. Geol., 1989, no. 11, pp. 113–117.

    Google Scholar 

  • Dobretsov, N.L., Model of the East Sayan nappe tectonics, Geotektonika, 1985, no. 1, pp. 39–50.

    Google Scholar 

  • Dobretsov, N.L., Konnikov, E.G., Medvedev, V.N., et al., Ophiolites and olistostromes of Eastern Sayan, Rifeisko-nizhnepaleozoiskie ofiolity Severnoi Evrazii (Riphean–Lower Paleozoic ophiolites of Northern Eurasia), Novosibirsk: Nauka, 1985, pp. 34–58.

    Google Scholar 

  • Galimov, E.M., Mironov, A.G., and Zhmodik, S.M., Nature of carbonization in the carbon-rich rocks of the Eastern Sayan, Geochem. Int., 2000, vol. 38, no. 4, pp. 317–322.

    Google Scholar 

  • Garutti, G. and Zaccarini, F., In situ alteration of platinum- group minerals at low temperature evidence from serpentinized and weathered cromitites of the Vourinos Complex, Greece, Can. Mineral., 1997, vol. 35, pp. 611–626.

    Google Scholar 

  • Garutti, G., Zaccarini, F., and Economou-Eliopoulos, M., Paragenesis and composition of laurite from chromitites of Othris (Greece): implications for Os-Ru fractionation in ophiolititc upper mantle of the Balkan Peninsula, Miner. Deposita, 1999, vol. 34, pp. 312–319.

    Article  Google Scholar 

  • Kiseleva, O.N., Chromitites and PGM Mineralization in the Ophiolites of Southeastern Eastern Sayan (Ospa–Kitoi and Khara-Nur Massifs), Extended Abstract of Candidate’s (Geol.-Min) Dissertation, Novosibirsk, 2014.

    Google Scholar 

  • Kiseleva, O.N., Zhmodik, S.M., and Agafonov, L.V., PGM mineralization in chromite ores of ophiolites of Eastern Sayan (Ospa–Kitoi and Khara–Nur districts), Sovremennye problemy geokhimii: Mater. Vseross. soveshch., posvyashch. 95-letiyu so dnya rozhdeniya akademika L.V. Tausona (Modern Problems of Geochemistry. Proceedings of All-Russian Conference Devoted to the 95th Anniversary of the Academician L.V. Tauson), Irkutsk, 2012, vol. 3, pp. 55–58.

    Google Scholar 

  • Kiseleva, O.N., Zhmodik, S.M., and Belyanin, D.K., Microtextural features of PGM as indicators of PGE remobilization in chromitites of the Eastern Sayan ophiolites, Geologiya i mineral’no-syr’evye resursy Sibiri (Geology and Mineral-Raw Resources of Siberia), 2014a, pp. 76–80.

    Google Scholar 

  • Kiseleva, O. N., Zhmodik, S. M., Damdinov, B. B., et al., Composition and evolution of PGE mienralization in chromite ores from the Il’chir ophiolite complex (Ospa–Kitoi and Khara-Nur areas, East Sayan), Russ. Geol. Geophys., 2014b, vol. 55, no. 2, pp. 259–272.

    Article  Google Scholar 

  • Kuz’michev, A.B., Riphean ophiolites of the Kitoi range: structural position and age of obduction, Izv. Vyssh. Uchebn. Zaved., Geol. Razvedka, 1996, no. 3, pp. 11–25.

    Google Scholar 

  • Kuz’michev, A.B., Tektonicheskaya istoriya Tuvino-Mongol’skogo massiva: rannebaikal’skii, pozdnebaikal’skii i rannekaledonskii etapy (Tectonic History of the Tuva–Mongolian Massif: Early Baikalian and Early Caledonian Stages), Moscow, 2004.

    Google Scholar 

  • Lodochnikov, V.N., Il’cjir and other serpentines and serpepentinites, Trudy TsNIGRI, 1936, vol. 38.

  • Makeev, A.B., PGE Speciation in the Alpine-Type Ultrabasites of the Urals, Geologiya i genezis mestorozhdenii platinovykh metallov (Geology and Genesis of PGM Deposits), Moscow: Nauka, 1994, pp. 175–1893.

    Google Scholar 

  • Makeev, A.B., Shcherbakova, A.V., and Mel’nikov, F.P., Copper minerals in the ores and ore-bearing dunites of the Tsentral’noe chromitite deposit, Rai-iz massif, Polar Urals, Geologiya i mineral’nye resursy Evropeiskogo Severo-Vostoka Rossii. Novye rezul’taty i novye perspektivy (Geology and Mineral Resources of European Northeastern Russia. New Results and Prospects), Moscow, 1999, vol. 4, pp. 67–70.

    Google Scholar 

  • Mochalov, A.G. and Dmitrenko, G.G., PGM mineralogy of alpine-type ultramafites, Petrologiya giperbazitov i bazitov (Petrology of Hyperbasites and Basites), Novosibirsk: Sibirsk. Otd. Ross. Akad. Nauk, 1990, pp. 144–167.

    Google Scholar 

  • Moloshag, V.P., Alimov, V.Yu., Anikina, E.V., et al., Accessory mineralization of chromitites of the Alpine-type hyperbasites of the Urals, Zap. Vsesoyuz. Mineral. O-va, 1999, no. 2, pp. 71–83.

    Google Scholar 

  • Ohnenstetter, M., Johan, Z., Cocherie, A., et al., New exploration methods for platinum and rhodium deposits poor in base-metal sulfides–NEXTRIM, Trans. Inst. Mining Metall (Appl. Earth Sci.), 1999, vol. 108, pp. 119–150.

    Google Scholar 

  • Orsoev, D.A., Tolstykh, N.D., and Kislov, E.V., Mineral of Pt-Cu3 composition from chromitites of the Ospa–Kitoi hyperbasite massif, East Saya, Zap. Ross. Mineral. O-va, 2001, vol. 130, no. 4, pp. 61–71.

    Google Scholar 

  • Pavlov, N. V., Kravchenko, G. G., and Chuprinina, I. I., Khromity Kempirsaiskogo Plutona (Chromitites of the Kempirsai Pluton), Moscow: Nauka, 1968.

    Google Scholar 

  • Pedersen, R.B. and Johannesen, G.M., Stratiform platinum-group element mineralizations in the ultramafic cumulates of the Leka ophiolite complex, central Norway, Econ. Geol., 1993, vol. 88, pp. 782–803.

    Google Scholar 

  • Prichard, H.M., Economou-Eliopoulos, M., and Fisher, P.C., Contrasting platinum-group mineral assemblages from two different podiform chromotite localities in the Pindos ophiolite complex, Greece, Can. Mineral., 2008, vol. 46, pp. 329–341.

    Article  Google Scholar 

  • Prichard, H.M., Ixer, R.I., Maynard, J., et al., Assemblages of platinum-group minerals and sulfides in silicate lithologies and chromite-rich rocks within the Shetland ophiolite, Can. Mineral., 1994, vol. 32, pp. 291–294.

    Google Scholar 

  • Prichard, H.M., Haroldo, J., and Fisher, P.C., Platinumgroup mineral assemblages and chromite composition in the altered and deformed Bacuri Complex, Amapa, northeastern Brazil, Can. Mineral., 2001, vol. 39, pp. 377–396.

    Article  Google Scholar 

  • Rajabzadeh, M.A. and Moosavinasab, Z., Mineralogy and distribution of platinum-group minerals (PGM) and other solid inclusions in the Neyriz ophiolitic chromitites, southern Iran, Can. Mineral., 2012, vol. 50, pp. 643–665.

    Article  Google Scholar 

  • Tarkian, M. and Prichard, H.M., Irarsite-hollogworthite solid solution series and other associated Ru-, Os-, Ir- and Rh-bearing PGM’s from the Shetland ophiolite complex, Miner. Deposita, 1987, vol. 22, no. 3, pp. 178–184.

    Article  Google Scholar 

  • Uysal, I., Sadiklar, M.B., Tarkian, M., Karsli, O., and Aydin, F., Mineralogy and composition of the chromitites and their platinum-group minerals from Ortaca (Mugla–SW Turkey): evidence for ophiolitic chromitite genesis, Mineral. Petrol., 2005, vol. 83, pp. 219–242.

    Article  Google Scholar 

  • Uysal, I., Tarkian, M., Sadiklar, M.B., and Guneyt, S., Platinum-group-element geochemistry and mineralogy of ophiolitic chromitites from the Kop mountains, northeastern Turkey, Can. Mineral., 2007, vol. 45, pp. 355–377.

    Article  Google Scholar 

  • Watenphul, A., Schmidt, C., and Jahn, S., Cr(III) solubility in aqueous fluids at high pressures and temperatures, Geochim. Cosmochim. Acta, 2014, vol. 126, pp. 212–227.

    Article  Google Scholar 

  • Weiser, T.W., Kojonen, K.K., and Lodziak, J., New data of eskolaite, Zn-bearing chromite, willyamite and ullmannite from the Outokumpu mine, eastern Finland, Bull. Geol. Soc. Finland, 2008, vol. 80, pp. 5–18.

    Article  Google Scholar 

  • Wood, S.A., The aqueous geochemistry of the platinum-group elements with applications to ore deposits, The Geology, Geochemistry, Mineralogy, and Mineral Beneficiation of Platinum- Group Elements, Cabri, L.J., Ed. Can. Inst. Min. Metall., 2002, vol. 54, pp. 211–249.

    Google Scholar 

  • Wylie, Ann, G., Candela, P. A., and Burke, T. M., Compositional zoning in unusual Zn-rich chromite from the Sykesville District of, Maryland: and its bearing on the origin of “ferritchromite”, Am. Mineral., 1987, vol. 72, pp. 413–422.

    Google Scholar 

  • Zhmodik, S.M., Agafonov, L.V., Mironov, A.G., et al., A unique PGE–Ni mineralization in ophiolites from the Ospin–Kitoi District, Eastern Sayan, Dokl. Earth Sci., 2000, vol. 373, pp. 806–810.

    Google Scholar 

  • Zhmodik, S.M., Mironov, A.G., Agafonov, L.V., Zhmodik, A.S., et al., Carbonatization of East Sayan ultrabasic rocks and Au–Pd–Pt mineralization, Russ. Geol. Geophys., 2004, vol. 45, no. 2, pp. 210–225.

    Google Scholar 

  • Zhmodik, S.M., Mironov, A.G., Zhmodik, A.S., Zolotokontsentriruyushchie sistemy ofiolitovykh poyasov (na primere Sayano-Baikalo-Muiskogo poyasa (Gold-Concentrating Systems of Ophiolite Belts by the Example of the Sayan–Baikal-Muya belt), Novosibirsk: GEO, 2008, pp. 154–211.

    Google Scholar 

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Correspondence to A. V. Grigor’eva.

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Original Russian Text © A.V. Grigor’eva, B.B. Damdinov, S.F. Sluzhenikin, 2018, published in Geologiya Rudnykh Mestorozhdenii, 2018, Vol. 60, No. 2, pp. 141–163.

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Grigor’eva, A.V., Damdinov, B.B. & Sluzhenikin, S.F. Ore Mineralization in Ultramafic and Metasomatic Rocks of the Ospin–Kitoi Massif, Eastern Sayan. Geol. Ore Deposits 60, 121–141 (2018). https://doi.org/10.1134/S1075701518020022

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