Abstract
Methyl N-alkyl-, N-cycloalkyl-, and N-arylcarbamates were synthesized by reaction of the corresponding amines with dimethyl carbonate in the presence of binder-free FeHY zeolite. The optimal conditions (reactant ratio, amount of the catalyst, temperature, reaction time) were found to afford the target products with high yields.
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ACKNOWLEDGMENTS
This study was performed using the equipment of Agidel joint center, Ufa Federal Research Center, Russian Academy of Sciences.
Funding
This study was performed under financial support by the Ministry of Science and Higher Education of the Russian Federation (project no. 2019-05-595-000-058).
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Khusnutdinov, R.I., Shchadneva, N.A., Mayakova, Y.Y. et al. Methoxycarbonylation of Alkyl-, Cycloalkyl-, and Arylamines with Dimethyl Carbonate in the Presence of Binder-Free Zeolite. Russ J Org Chem 56, 1228–1235 (2020). https://doi.org/10.1134/S1070428020070179
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DOI: https://doi.org/10.1134/S1070428020070179