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Micelle-Catalyzed Synthesis of Arylmethylidene Derivatives of Malononitrile Trimer and Study of Their Optical Properties

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Abstract

Potassium salts of arylmethylidene derivatives of malononitrile trimer were obtained by the reactions of aromatic aldehydes with malononitrile trimer in an aqueous medium under micellar catalysis. The optical properties of the synthesized salts were studied to show they absorb in the range of 313–436 nm, depending on the substituent. Exchange reactions with various metal salts showed that the synthesized derivatives of malononitrile trimer form difficultly soluble compounds with silver salts.

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Funding

The study was funded from a grant of the President of the Russian Federation for state support of young Russian scientists (grant no. MK-2166.2019.3, agreement no. 075-15-2019-383).

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Authors and Affiliations

  1. Ul’yanov Chuvash State University, 428015, Cheboksary, Russia

    A. U. Alekseeva, N. P. Dianov, N. N. Yashchenko, S. V. Zhitar’ & I. N. Bardasov

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  1. A. U. Alekseeva
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  2. N. P. Dianov
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  3. N. N. Yashchenko
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  4. S. V. Zhitar’
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  5. I. N. Bardasov
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Correspondence to I. N. Bardasov.

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Alekseeva, A.U., Dianov, N.P., Yashchenko, N.N. et al. Micelle-Catalyzed Synthesis of Arylmethylidene Derivatives of Malononitrile Trimer and Study of Their Optical Properties. Russ J Org Chem 56, 763–767 (2020). https://doi.org/10.1134/S1070428020050061

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  • DOI: https://doi.org/10.1134/S1070428020050061

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