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Efficient Catalytic Synthesis of α,ω-Di(spiro[adamantane2,3′-[1,2,4,5,7]tetroxazocan]-7′-yl)alkanes

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Abstract

An efficient method has been developed for the synthesis of α,ω-di(spiro[adamantane-2,3′[1,2, 4,5,7]tetroxazocan]-7′-yl)alkanes by recyclization of spiro[adamantane-2,3′-[1,2,4,5,7]pentoxocane] with α,ω-diaminoalkanes in THF in the presence of Sm(NO3)3 · 6 H2O as catalyst.

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Funding

This study was performed under financial support by the Russian Science Foundation (project no. 18-73-00 014).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia

    N. N. Makhmudiyarova, E. S. Meshcheryakova & A. G. Ibragimov

  2. Bashkir State University, 450076, Ufa, Russia

    L. S. Koroleva

Authors
  1. N. N. Makhmudiyarova
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  2. L. S. Koroleva
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  3. E. S. Meshcheryakova
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  4. A. G. Ibragimov
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Correspondence to N. N. Makhmudiyarova.

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Makhmudiyarova, N.N., Koroleva, L.S., Meshcheryakova, E.S. et al. Efficient Catalytic Synthesis of α,ω-Di(spiro[adamantane2,3′-[1,2,4,5,7]tetroxazocan]-7′-yl)alkanes. Russ J Org Chem 56, 378–384 (2020). https://doi.org/10.1134/S1070428020030021

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