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Synthesis of Tetrazoles from Amines Mediated by New Copper Nanocatalyst

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Abstract

New copper nanocatalyst was prepared by coating Fe3O4 magnetic nanoparticles with tetraethyl orthosilicate (TEOS), followed by functionalization with 3-chloropropyl(trimethoxy)silane and 4H-1,2,4-tri-azol-4-amine and complexation with copper(II) chloride. The new catalyst was characterized by various spectroscopic methods and was successfully used in the synthesis of 1-aryl-1H-tetrazoles by reaction of aromatic amines with sodium azide and triethyl orthoformate under solvent-free conditions at 100°C.

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Acknowledgments

The authors are grateful to the Bu-Ali Sina University, Hamedan, Iran, for the financial support of this work.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

    M. Ariannezhad, D. Habibi & S. Heydari

Authors
  1. M. Ariannezhad
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  2. D. Habibi
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  3. S. Heydari
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Correspondence to D. Habibi.

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Ariannezhad, M., Habibi, D. & Heydari, S. Synthesis of Tetrazoles from Amines Mediated by New Copper Nanocatalyst. Russ J Org Chem 55, 1591–1597 (2019). https://doi.org/10.1134/S1070428019100208

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  • DOI: https://doi.org/10.1134/S1070428019100208

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