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Hydrolysis of 6-Aryl-2-amino-4-(dicyanomethylidene)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitriles

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Abstract

6-Aryl-2-(dicyanomethylidene)-4-oxo-3-azabicyclo[3.1.0]hexane-1,5-dicarbonitriles were synthesized by treatment of 2-amino-6-aryl-4-(dicyanomethylidene)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitriles with a solution of sulfuric acid in acetic acid. The reaction with aqueous sulfuric acid gave 1-(1-amino-2,2-dicyanovinyl)-3-arylcyclopropane-1,2-dicarbonitriles.

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Funding

The work was funded by the Ministry of Education and Science of the Russian Federation in the framework of the basic part of the State order for scientific research (project no. 4.6283.2017/8.9 (0849-2017-0001)).

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Authors and Affiliations

  1. Ul’yanov Chuvash State University, Moskovskii pr. 15, Cheboksary, 428015, Russia

    I. N. Bardasov, A. U. Alekseeva & O. V. Ershov

Authors
  1. I. N. Bardasov
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  2. A. U. Alekseeva
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  3. O. V. Ershov
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Correspondence to I. N. Bardasov.

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Conflict of Interest

The authors declare no conflict of interest.

Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 8, pp. 1163–1166.

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Bardasov, I.N., Alekseeva, A.U. & Ershov, O.V. Hydrolysis of 6-Aryl-2-amino-4-(dicyanomethylidene)-3-azabicyclo[3.1.0]hex-2-ene-1,5-dicarbonitriles. Russ J Org Chem 55, 1077–1080 (2019). https://doi.org/10.1134/S1070428019080025

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  • DOI: https://doi.org/10.1134/S1070428019080025

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