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Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides

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Abstract

Efficient and selective methods have been developed for the synthesis of previously unknown organyl [3-(trimethylsilyl)prop-2-yn-1-yl] selenides, organyl prop-2-yn-1-yl selenides, and bis[3-(trimethylsilyl) prop-2-yn-1-yl] selenide by reactions of 3-bromo-1-(trimethylsilyl)prop-1-yne with the corresponding organylselenolates and sodium selenide generated from diorganyl diselenides or elemental selenium by the action of sodium tetrahydridoborate.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. V. Musalov, M. V. Andreev, S. V. Amosova, L. I. Larina & V. A. Potapov

Authors
  1. M. V. Musalov
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  2. M. V. Andreev
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  3. S. V. Amosova
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  4. L. I. Larina
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  5. V. A. Potapov
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © M.V. Musalov, M.V. Andreev, S.V. Amosova, L.I. Larina, V.A. Potapov, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 10, pp. 1483–1486.

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Musalov, M.V., Andreev, M.V., Amosova, S.V. et al. Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides. Russ J Org Chem 53, 1510–1513 (2017). https://doi.org/10.1134/S1070428017100049

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  • DOI: https://doi.org/10.1134/S1070428017100049

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