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Nitrilation of carboxylic acids with acetonitrile catalyzed by molybdenum and vanadium complexes

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Abstract

Various carbonitriles were synthesized by reaction of the corresponding carboxylic acids with acetonitrile in carbon tetrachloride in the presence of VO(acac)2 and Mo(CO)6 in 6 h at 150–170°C.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    R. I. Khusnutdinov, N. A. Shchadneva, A. R. Bayguzina & Yu. Yu. Mayakova

Authors
  1. R. I. Khusnutdinov
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  2. N. A. Shchadneva
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  3. A. R. Bayguzina
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  4. Yu. Yu. Mayakova
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Corresponding author

Correspondence to R. I. Khusnutdinov.

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Original Russian Text © R.I. Khusnutdinov, N.A. Shchadneva, A.R. Bayguzina, Yu.Yu. Mayakova, 2016, published in Zhurnal Organicheskoi Khimii, 2016, Vol. 52, No. 9, pp. 1295–1299.

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Khusnutdinov, R.I., Shchadneva, N.A., Bayguzina, A.R. et al. Nitrilation of carboxylic acids with acetonitrile catalyzed by molybdenum and vanadium complexes. Russ J Org Chem 52, 1282–1286 (2016). https://doi.org/10.1134/S1070428016090050

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  • DOI: https://doi.org/10.1134/S1070428016090050

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