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Products of ozone oxidation of some saturated cyclic hydrocarbons

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Abstract

Low-temperature ozone oxidation of a series of saturated carbocyclic hydrocarbons afforded the corresponding alcohols and/or ketones in high yield through intermediate trioxidanes. exo,endo-Tetracyclo-[6.2.1.03,5]undecane-2,7-dione and exo,endo,endo-hexacyclo[9.3.1.03,8.04,6.05,9.012,14]pentadecane-2,10-dione were isolated, and exo,endo,exo-pentacyclo[6.3.1.02,7.03,5.09,11]dodecyl-, exo,exo,exo-heptacyclo-[9.3.1.02,10.03,8.04,6.05,9.012,14]pentadecyl, and 1-methylcyclohexyltrioxidanes were identified and characterized for the first time.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    L. R. Khalitova, S. A. Grabovskiy, A. V. Antipin, L. V. Spirikhin & N. N. Kabal’nova

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  1. L. R. Khalitova
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  2. S. A. Grabovskiy
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  3. A. V. Antipin
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  4. L. V. Spirikhin
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  5. N. N. Kabal’nova
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Correspondence to L. R. Khalitova.

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Original Russian Text © L.R. Khalitova, S.A. Grabovskiy, A.V. Antipin, L.V. Spirikhin, N.N. Kabal’nova, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 12, pp. 1744–1750.

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Khalitova, L.R., Grabovskiy, S.A., Antipin, A.V. et al. Products of ozone oxidation of some saturated cyclic hydrocarbons. Russ J Org Chem 51, 1710–1716 (2015). https://doi.org/10.1134/S1070428015120076

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  • DOI: https://doi.org/10.1134/S1070428015120076

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