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One-pot amination of cage hydrocarbons

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Abstract

A one-pot procedure has been proposed for the synthesis of amines directly from cage hydrocarbons. A number of cage amines have been synthesized by treatment of adamantane, its homologs, and structurally related cage hydrocarbons with nitric acid in acetic acid and subsequent addition of urea and heating.

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Authors and Affiliations

  1. Samara State Technical University, ul. Molodogvardeiskaya 244, Samara, 443100, Russia

    M. V. Leonova, M. Yu. Skomorokhov, I. K. Moiseev & Yu. N. Klimochkin

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  1. M. V. Leonova
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  2. M. Yu. Skomorokhov
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  3. I. K. Moiseev
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  4. Yu. N. Klimochkin
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Correspondence to M. V. Leonova.

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Original Russian Text © M.V. Leonova, M.Yu. Skomorokhov, I.K. Moiseev, Yu.N. Klimochkin, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 12, pp. 1737–1743.

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Leonova, M.V., Skomorokhov, M.Y., Moiseev, I.K. et al. One-pot amination of cage hydrocarbons. Russ J Org Chem 51, 1703–1709 (2015). https://doi.org/10.1134/S1070428015120064

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