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Use of a Graft Copolymer of Low Molecular Weight Polyethylene and Acrylic Acid in Carbon Black-Filled Polyethylene Compouns

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Composites based on carbon black/high-density polyethylene composites and, as well as linear low-density polyethylene containing graft copolymers of low molecular weight polyethylene and acrylic acid, have been produced. The introduction of graft copolymers into the polyethylene matrix helps to reduce the average size of carbon black particles in the composition, reduce the melt viscosity and improve the thermal stability of carbon black-filled compositions, which is important for the production of pipe products based on polyethylene.

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Authors and Affiliations

  1. Institute of Chemistry and Physics of Polymers, Academy of Sciences of the Republic of Uzbekistan, 100128, Tashkent, Uzbekistan

    V. O. Kudyshkin, N. I. Bozorov, N. Sh. Ashurov, N. R. Ashurov & S. Sh. Rashidova

  2. JSC “Shurtan Gas Chemical Complex,” pos. Shurtan, 131300, Kashkadarya oblast, Uzbekistan

    R. Kh. Madiev

Authors
  1. V. O. Kudyshkin
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  2. N. I. Bozorov
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  3. R. Kh. Madiev
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  4. N. Sh. Ashurov
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  5. N. R. Ashurov
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  6. S. Sh. Rashidova
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Contributions

V.O. Kudyshkin: choice of the research objects, substantiation of the possibility of using a graft copolymer of low-molecular-weight polyethylene and acrylic acid as a compatibilizer in polyethylene blends with carbon black; development a detailed research plan and analysis of the results obtained; N.I. Bozorov: synthesis of graft copolymers of a given composition and preparation of blends of polyethylene, graft copolymers and carbon black; R.Kh. Madiev: studying the composites for thermal stability, determination of the melt flow indices; N.Sh. Ashurov: studying the compositions of polyethylene, carbon black and graft copolymers by atomic force microscopy; N.R. Ashurov: substantiation of the use of compatibilizers for the formation of a uniform distribution of particles of the dispersed phase in the blends of polyethylene and carbon black, as well as the blend compositions and the conditions for their preparation, described the relationship between the physico-mechanical parameters of the composites and the particle sizes of the dispersed phase; S.Sh. Rashidova: formulation the idea of ​​improving the thermal stability of linear polyethylene compositions by introduction of graft copolymers, critical analysis of the conclusion drawn based on the experimental results and literature data.

Corresponding authors

Correspondence to V. O. Kudyshkin or R. Kh. Madiev.

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The authors declare no conflict of interest requiring disclosure in this article.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 5, pp. 589–595, May, 2022 https://doi.org/10.31857/S0044461822050048

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Kudyshkin, V.O., Bozorov, N.I., Madiev, R.K. et al. Use of a Graft Copolymer of Low Molecular Weight Polyethylene and Acrylic Acid in Carbon Black-Filled Polyethylene Compouns. Russ J Appl Chem 95, 655–660 (2022). https://doi.org/10.1134/S1070427222050044

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  • DOI: https://doi.org/10.1134/S1070427222050044

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