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Sorption Selectivity of Palladium(II) by Poly(N-2-Sulfoethylallylamine) under Static and Dynamic Conditions

  • Sorption and Ion Exchange Processes
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Abstract

The process of Pd(II) sorption from hydrochloric acid solutions was studied in the pH range of 0.5–5.0 in the presence of Pt(IV) and a number of non-noble metal ions by poly(N-2-sulfoethylallylamine) (degrees of modification by sulfoethyl groups of 0.5 and 1.0) crosslinked with epichlorohydrin. It is shown that the degree of extraction of Pd(II) from multicomponent solutions containing transition metal ions Cu(II), Ni(II), Co(II), Zn(II), Cd(II), Mg(II), Pt( IV) is the largest. The selectivity coefficients of KPd(II)/Pt(IV) increase with an increase in the content of sulfoethyl groups in the aminopolymer and an increase in pH, which indicates that the Pd(II) sorption proceeds predominantly via the complex formation mechanism. It was found that the sorption equilibrium in the systems metal salt solution–sorbent is achieved within 240 and 120 min of phase contact for poly(N-2-sulfoethylallylamines) with modification degrees of 0.5 and 1.0, respectively. Under dynamic conditions, the studied sorbent, along with Pd(II), to a large extent extracts accompanying metal ions, which indicates a significant contribution of ion exchange to the mechanism of the sorption process.

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REFERENCES

  1. Pestov, A.V., Privar, Yu.O., Mekhaev, A.V., Fedorets, A.N., Ezhikova, M.A., Kodess, M.I., and Bratskaya, S.Yu., Eur. Polym.J., 2019, vol. 115, pp. 356–363. https://doi.org/10.1016/j.eurpolymj.2019.03.049

    Article  CAS  Google Scholar 

  2. Bratskaya, S., Privar Yu., Ustinov, A., Azarova Yu., and Pestov, A., Ind. Eng. Chem. Res., 2016, vol. 55, no. 39, pp. 10377–10385. https://doi.org/10.1021/acs.iecr.6b01376

    Article  CAS  Google Scholar 

  3. Lee, J., Kurniawan, Hong, H., Chung, K.W., and Sookyung, K., Sep. Purif. Technol., 2020, vol. 246, ID 116896. https://doi.org/10.1016/j.seppur.2020.116896

    Article  CAS  Google Scholar 

  4. Alifkhanova, L.M.k., Kuznetsova K.Ya., Marchuk, A.A., Petrova Yu.S., Pestov, A.V., and Neudachina, L.K.., Russ. J. Inorg. Chem., 2021, vol. 66, no. 6. P. 909–915. https://doi.org/10.31857/S0044457X21060027 

    Article  Google Scholar 

  5. Alifkhanova, L.M.k., Lopunova K.Ya., Pestov, A.V., Zemlyakova, E.O., Kondratovich, O.V., Petrova, Yu.S., and Neudachina, L.K., Sep. Sci. Technol., 2021, vol. 56, no. 8, pp. 1303–1311. https://doi.org/10.1080/01496395.2020.1781175

    Article  CAS  Google Scholar 

  6. Marhol, M., Ion Exchangers in Analytical Chemistry, Prague, 1982.

    Google Scholar 

  7. Gandhi, M.R., Yamada, M., Kondo, Y., Shibayama, A., and Hamada, F., J. Ind. Eng. Chem., 2015, vol. 30, pp. 20–28. https://doi.org/10.1016/j.jiec.2015.04.024

    Article  CAS  Google Scholar 

  8. Nikoloski, A.N., Ang, K.L., and Li, D., Hydrometallurgy, 2015, vol. 152, pp. 20–32. https://doi.org/10.1016/j.hydromet.2014.12.006

    Article  CAS  Google Scholar 

  9. Miroshnichenko, A.A., Procedia Eng., 2016, vol. 152, pp. 8–12. https://doi.org/10.1016/j.proeng.2016.07.607

    Article  CAS  Google Scholar 

  10. Kononova, O.N., Duba, E.V., Shnaider, N.I., and Pozdnyakov, I.A., Russ. J. Appl. Chem., 2017, vol. 90, no. 8, pp. 1239–1245. https://doi.org/10.1134/S1070427217080080 

    Article  CAS  Google Scholar 

  11. Pinto, J., Lopes, C.B., Henriques, B., Couto, A.F., Ferreira, N., Carvalho, L., Costa, M., Torres, J.M.P., Vale, C., and Pereira, E., J. Environ. Chem. Eng., 2021, vol. 9. ID 105100. https://doi.org/10.1016/j.jece.2021.105100

    Article  Google Scholar 

  12. Ramakul, P., Yanachawakul, Y., Leepipatpiboon, N., and Sunsandee, N., Chem. Eng.J., 2012, vol. 193–194, pp. 102–111. https://doi.org/10.1016/j.cej.2012.04.035

    Article  CAS  Google Scholar 

  13. Petrova, Yu.S., Pestov, A.V., Usoltseva, M.K., Kapitanova, E.I., and Neudachina, L.K., Sep. Sci. Technol., 2019, vol. 54. N 1, pp. 42–50. https://doi.org/10.1080/01496395.2018.1505912

    Article  CAS  Google Scholar 

  14. Asere, T.G., Mincke, S., Folens, K., Bussche, F.V., Lapeire, L., Verbeken, K., Voort, P.V.D., Tessema, D.A., Laing, G.D., and Stevens, C.V., React. Funct. Polym., 2019, vol. 141, pp. 145–154. https://doi.org/10.1016/j.reactfunctpolym.2019.05.008

    Article  CAS  Google Scholar 

  15. Chassary, P., Thierry, V., Marcano, J.S., Macaskie, L.E., and Guibal, E., Hydrometallurgy, 2005, vol. 76, pp. 131–147. https://doi.org/10.1016/j.hydromet.2004.10.004

    Article  CAS  Google Scholar 

  16. Guibal, E., Sweeney, N.V.O., Zikan, M.C., Vincent, T., and Tobin, J.M., Int. J. Biol. Macromol., 2001, vol. 28, pp. 401–408. https://doi.org/10.1016/s0141-8130(01)00130-1

    Article  CAS  PubMed  Google Scholar 

  17. Ricoux, Q., Bocokic, V., Mericq, J.P., Bouyer, D., Zutphen, S.V., and Faur, C., Chem. Eng.J., 2015, vol. 264, pp. 772–779. https://doi.org/10.1016/j.cej.2014.11.139

    Article  CAS  Google Scholar 

  18. Prozorova, G., Kuznetsova, N., Shaulina, L., Bolgova, Yu., Trofimova, O., Emel’yanov, A., and Pozdnyakov, A., J. Organomet. Chem., 2020, vol. 916. ID 121273. https://doi.org/10.1016/j.jorganchem.2020.121273

    Article  Google Scholar 

  19. Rasoulzadeh, H., Sheikhmohammadi, A., Abtah, M., Roshan, B., and Jokar, R., J. Environ. Chem. Eng., 2021, vol. 9, ID 105954. https://doi.org/10.1016/j.jece.2021.105954

    Article  CAS  Google Scholar 

  20. Wang, Z., Kang, S.B., and Won, S.W., J. Environ. Chem. Eng., 2021, vol. 9. ID 105058. https://doi.org/10.1016/j.jece.2021.105058

    Article  PubMed  PubMed Central  Google Scholar 

  21. Ruiz, M., Sastre, A.M., and Guibal, E., React. Funct. Polym., 2000, vol. 45, pp. 155–173. https://doi.org/10.1016/S1381-5148(00)00019-5

    Article  CAS  Google Scholar 

  22. Ho, Y.S. and McKay, G., Process Biochem., 1999, vol. 34, no. 5, pp. 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5

    Article  CAS  Google Scholar 

  23. Ho, Y.S., Ng, J.C.Y., and McKay, G., Sep. Purific. Methods, 2000, vol. 29, no. 2, pp. 189–232. https://doi.org/10.1081/SPM-100100009

    Article  CAS  Google Scholar 

  24. Ozacar, M. and Sengil, I.A., Process Biochem., 2005, vol. 40, no. 2, pp. 565–572. https://doi.org/10.1016/j.procbio.2004.01.032

    Article  CAS  Google Scholar 

  25. Petrukhin, O.M., Myasoedova, G.V., and Malofeeva, G.I., Khimicheskie metody razdeleniya i kontsentrirovaniya (Chemical Methods of Separation and Concentration), Moscow: KomKniga, 2005.

    Google Scholar 

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Funding

The study was supported by the grant of the Russian Science Foundation (Russian Science Foundation) no. 21-73-00052, https://rscf.ru/project/21-73-00052/.

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Authors and Affiliations

  1. Ural Federal University named after the first President of Russia B.N. Yeltsin, 620002, Ekaterinburg, Russia

    L. M. k. Alifkhanova, Yu. S. Petrova, K. Ya. Kuznetsova, A. V. Pestov & L. K. Neudachina

  2. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620137, Ekaterinburg, Russia

    E. O. Zemlyakova & A. V. Pestov

Authors
  1. L. M. k. Alifkhanova
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  2. Yu. S. Petrova
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  3. K. Ya. Kuznetsova
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  4. E. O. Zemlyakova
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  5. A. V. Pestov
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  6. L. K. Neudachina
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Contributions

L.M.k. Alifkhanova: a study of the sorption selectivity of noble metal ions by sulfoethylated polyallyamine under static conditions; K.Ya. Kuznetsova: a study of the sorption selectivity of noble metal ions by sulfoethylated polyallyamine under dynamic conditions; L.K. Neudachina and Yu.S. Petrova: researching the sorption kinetics of metal ions by the studied sorbents and carrying out mathematical processing of kinetic curves; E.O. Zemlyakova and A.V. Pestov: synthesis of the studied sorbents.

Corresponding author

Correspondence to L. M. k. Alifkhanova.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 3, pp. 399–408, March, 2022 https://doi.org/10.31857/S0044461822030136

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Alifkhanova, L.M.k., Petrova, Y.S., Kuznetsova, K.Y. et al. Sorption Selectivity of Palladium(II) by Poly(N-2-Sulfoethylallylamine) under Static and Dynamic Conditions. Russ J Appl Chem 95, 451–459 (2022). https://doi.org/10.1134/S1070427222030168

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