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Nanocrystalline Lanthanum Cobaltite as a Material for Gas Sensors

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Nanocrystalline LaCoO3 was prepared by the sol–gel method using microwave radiation, was characterized by X-ray diffraction, scanning electron microscopy, low-temperature nitrogen adsorption, and temperature-programmed reduction with hydrogen, and was tested as a sensitive material for detecting СО and NH3. The dependence of the phase composition and microstructural parameters of LaCoO3 on the annealing temperature and time was revealed. The LaCoO3 prepared exhibits high sensor response in detecting СО and NH3.

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REFERENCES

  1. GN (Hygienic Norms) 2.2.5.3532–18: Maximum Permissible Concentrations (MPC) of Harmful Substances in Air of the Working Zone; GN 2.1.6.3492–17: Maximum Permissible Concentrations (MPC) of Pollutants in Air of Urban and Rural Settlements.

  2. Enhessari, M. and Salehabadi, A., in Progress in Chemical Sensor, Wang, W., Ed., IntechOpen Book Ser., 2016. https://doi.org/10.5772/62559

  3. Choopun, S., Hongsith, N., and Wongrat, S., in Nanowires–Recent Advances, Peng, X., Ed., IntechOpen Book Ser., 2012. https://doi.org/10.5772/54385

  4. Saburi, O., J. Am. Ceram. Soc., 1961, vol. 44, no. 2, pp. 54–63. https://doi.org/10.1111/j.1151-2916.1961.tb15350.x

    Article  Google Scholar 

  5. Zhou, Z.-G., Tang, Z.-L., Zhang, Z.-T., and Wlodarski, W., Sens. Actuators B, 2001, vol. 77, pp. 22–26. https://doi.org/10.1016/S0925-4005(01)00667-0

    Article  CAS  Google Scholar 

  6. Granger, P., Parvulescu, V., Kaliaguine, S., and Prellier, W., Perovskites and Related Mixed Oxides: Concepts and Applications, Wiley, 2016, pp. 367–377.

    Google Scholar 

  7. Leontiou, A., Ladavos, A., Giannakas, A., and Bakas, T., J. Catal., 2007, vol. 251, pp. 103–112. https://doi.org/10.1016/j.jcat.2007.07.012

    Article  CAS  Google Scholar 

  8. Singh, S. and Pandey, S., Philos. Mag., 2017, vol. 97, pp. 451–463. https://doi.org/10.1080/14786435.2016.1263404

    Article  CAS  Google Scholar 

  9. Rahnamaye Aliabad, H., Hesam, V., Ahmad, I., and Khan, I., Physica B: Cond. Matter, 2013, vol. 410, pp. 112–119. https://doi.org/10.1016/j.physb.2012.11.002

    Article  CAS  Google Scholar 

  10. Radovic, M., Speakman, S., Allard, L., and Payzant, E., J. Power Sources, 2008, vol. 184, pp. 77–83. https://doi.org/10.1016/j.jpowsour.2008.05.063

    Article  CAS  Google Scholar 

  11. Mukhopadhyay, S., Finnis, M.W., and Harrison, N.M., Phys. Rev. B, 2013, vol. 87, ID 125132. https://doi.org/10.1103/PhysRevB.87.125132

    Article  CAS  Google Scholar 

  12. Aswin, V., Dogra, A., Gupta, A., and Pulikkotil, J.J., RSC Adv., 2016, vol. 6, pp. 1403–1407. https://doi.org/10.1039/C5RA23244A

    Article  CAS  Google Scholar 

  13. Zhuang, M., Zhang, W., and Ming, N., Phys. Rev. B, 1998, vol. 57, pp. 10705–10709. https://doi.org/10.1103/PhysRevB.57.10705

    Article  CAS  Google Scholar 

  14. Cieniek, L., Kopia, A., Kusinski, J., Kowalski, K., Moskalewicz, T., Cyza, A., and Maziarz, W., Int. J. Mater. Res., 2018, vol. 109, pp. E1–E10. https://doi.org/10.3139/146.111618

    Article  CAS  Google Scholar 

  15. Jedrusik, M., Microstructure and sensing properties of LaMO3 (M = Co, Fe) thin films, Thesis, HAL Id: tel-02498329, version 1, 2020. https://tel.archives-ouvertes.fr/tel-02498329.

  16. Ding, J.-C., Li, H.-Y., Cai, Z.-X., Zhang, X.-D., and Guo, X., RSC Adv., 2015, vol. 5, pp. 65668–65673. https://doi.org/10.1039/C5RA10521H

    Article  CAS  Google Scholar 

  17. Ghasdi, M. and Alamdari, H., Sens. Actuators B, 2010, vol. 148, pp. 478–485. https://doi.org/10.1016/j.snb.2010.05.056

    Article  CAS  Google Scholar 

  18. Ortiz, L., Bonilla, H., Salazar, J., Olvera, M., Karthik, T., Gonzalez, E., and Gomes, J., J. Nanomater., 2014, vol. 2014, pp. 1–8. https://doi.org/10.1155/2014/164380

    Article  CAS  Google Scholar 

  19. Ding, J.-C., Li, H.-Y., Cai, Z.-X., Wang, X.-X., and Guo, X., Sens. Actuators B, 2016, vol. 222, pp. 517–524. https://doi.org/10.1016/j.snb.2015.08.099

    Article  CAS  Google Scholar 

  20. Ding, J.-C., Li, H.-Y., and Guo, X., Solid State Ionics, 2015, vol. 272, pp. 155–159. https://doi.org/10.1016/j.ssi.2015.01.015

    Article  CAS  Google Scholar 

  21. Liu, H., Sun, H., Xie, R., Zhang, X., Zheng, K., Peng, T., Wu, X., and Zhang, Y., Appl. Surf. Sci., 2018, vol. 442, pp. 742–749. https://doi.org/10.1016/j.apsusc.2018.02.221

    Article  CAS  Google Scholar 

  22. Chaudhary, G. and Pawar, M., Sens. Tranducers, 2008, vol. 88, no. 2, pp. 74–78. https://www.sensorsportal.com/HTML/DIGEST/february_08/P_241.pdf.

    CAS  Google Scholar 

  23. Ding, J.-C., Li, H.-Y., Cao, T.-C., Cai, Z.-X., Wang, X.-X., and Guo, X., Solid State Ionics, 2017, vol. 303, pp. 97–102. https://doi.org/10.1016/j.ssi.2017.02.021

    Article  CAS  Google Scholar 

  24. Zhu, Y., Tan, R., Yi, T., Ji, S., Ye, X., and Cao, L., J. Mater. Sci., 2000, vol. 35, pp. 5415–5420. https://doi.org/10.1023/A:1004863332704

    Article  CAS  Google Scholar 

  25. Malyshev, V.V. and Pislyakov, A.V., Sens. Actuators B, 2007, vol. 123, no. 1, pp. 71–81. https://doi.org/10.1016/j.snb.2006.07.026

    Article  CAS  Google Scholar 

  26. Touahra, H., Chebout, R., Lerari, D., Halliche, D., and Bachari, K., Energy, 2019, vol. 171, pp. 465–474. https://doi.org/10.1016/j.energy.2019.01.085

    Article  CAS  Google Scholar 

  27. Erdenee, N., Enkhnaran, U., Galsan, S., and Pagvajav, A., J. Nanomater., 2017, vol. 2017, ID 9120586. https://doi.org/10.1155/2017/9120586

    Article  CAS  Google Scholar 

  28. Harizanova, S., Senyshyn, A., Zhecheva, E., and Tenchev, K., J. Alloys Compd., 2009, vol. 480, pp. 279–285. https://doi.org/10.1016/j.jallcom.2009.02.096

    Article  CAS  Google Scholar 

  29. Chen, H., Wei, G., Liang, X., Liu, P., Xi, Y., and Zhu, J., Catal. Sci. Technol., 2020, vol. 10, pp. 5829–5839. https://doi.org/10.1039/D0CY01150A

    Article  CAS  Google Scholar 

  30. Raccah, P.M. and Goodenough, J.B., Phys. Rev., 1967, vol. 155, no. 3, pp. 932–943. https://doi.org/10.1103/PhysRev.155.932

    Article  CAS  Google Scholar 

  31. Kobayashi, Y., Mitsunaga, T., Fujinawa, G., Arii, T., Suetake, M., Asai, K., and Harada, J., J. Phys. Soc. Jpn., 2000, vol. 69, no. 10, pp. 3468–3469. https://doi.org/10.1143/JPSJ.69.3468

    Article  CAS  Google Scholar 

  32. Krivetskiy, V.V.,, Rumyantseva, M.N., and Gaskov, A.M., Russ. Chem. Rev., 2013, vol. 82, no. 10, pp. 917–941.

    Article  Google Scholar 

  33. Yamazoe, N. and Shimanoe, K., Sens. Actuators B, 2008, vol. 128, no. 2, pp. 566–573. https://doi.org/10.1016/j.snb.2007.07.036

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to Prof. D. Fasquelle (Université du Littoral Côte d’Opale, Calais, France) for examining the samples by scanning electron microscopy.

Funding

The study was performed within the framework of the government assignment, theme АААА-А21-121011590082-2.

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Correspondence to M. N. Rumyantseva.

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The authors declare that they have no conflict of interest.

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Translated from Zhurnal Prikladnoi Khimii, No. 12, pp. 1390–1398, December, 2021 https://doi.org/10.31857/S0044461821120057

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Chumakova, V.T., Marikutsa, A.V. & Rumyantseva, M.N. Nanocrystalline Lanthanum Cobaltite as a Material for Gas Sensors. Russ J Appl Chem 94, 1651–1658 (2021). https://doi.org/10.1134/S1070427221120119

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