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Synthesis and Catalytic Activity of Quaternary Ammonium Salts Containing gem-Dichlorocyclopropane and 1,3-Dioxolane Fragments

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Abstract

Quaternary ammonium salts containing gem-dichlorocyclopropane and 1,3-dioxolane groups were synthesized in high yield. The reactions of dichlorocarbonation of styrene and O-alkylation of 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane in the presence of quaternary ammonium salts were studied. It was established that in the O-alkylation reaction, compounds containing cycloacetal and allyl moieties have the maximum efficiency in the series of catalysts studied. The structures of the isolated salts were proved by 1H and 13C NMR spectroscopy.

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ACKNOWLEDGMENTS

The authors are grateful to L.V. Spirikhin, head of the laboratory of the Federal Institute of Physics and Chemistry of the UFIC RAS for their assistance in identifying the structure of the compounds.

Funding

The studies were supported by the RFBR contest mol_ev_a (Eureka! Idea) under the contract no. 19-33-80002/19 of 12/07/2018.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, 450062, Ufa, Russia

    G. N. Sakhabutdinova, E. A. Yakovenko, G. Z. Raskil’dina & S. S. Zlotskii

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  1. G. N. Sakhabutdinova
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  2. E. A. Yakovenko
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  3. G. Z. Raskil’dina
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  4. S. S. Zlotskii
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Correspondence to G. Z. Raskil’dina.

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Sakhabutdinova, G.N., Yakovenko, E.A., Raskil’dina, G.Z. et al. Synthesis and Catalytic Activity of Quaternary Ammonium Salts Containing gem-Dichlorocyclopropane and 1,3-Dioxolane Fragments. Russ J Appl Chem 93, 967–972 (2020). https://doi.org/10.1134/S1070427220070046

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  • DOI: https://doi.org/10.1134/S1070427220070046

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