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Synthesis and Herbicidal and Antioxidant Activity of a Series of Hetero- and Carbocyclic Derivatives of Monochloroacetic Acid

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Monochloroacetic acid esters and amides containing carbo- and heterocycles and heterocyclic esters and amides derived from commercial aryloxyacetyl chlorides were synthesized. The structures of the compounds were confirmed by 1Н and 13С spectroscopy. The herbicidal activity of the substances was studied with respect to mono- and dicotyledonous plants. The relative antioxidant activity of the compounds was studied by recording the luminol-dependent chemiluminescence. The experimental data, on the whole, confirm that the development of herbicides containing acetal and gem-dichlorocyclopropane fragments is appropriate and promising.

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ACKNOWLEDGMENTS

The authors are sincerely grateful to L.V. Spirikhin, head of Laboratory of Physicochemical Methods of Analysis, Ufa Federal Research Center, Russian Academy of Sciences, for the assistance in identification of the structures of the compounds.

Funding

The studies were supported by the Russian Foundation for Basic Research, mol_ev_a competition (Eureca! Idea), contract no. 19-33-80002\19 of December 7, 2018.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, 450064, Ufa, Russia

    E. A. Yakovenko, G. Z. Raskil’dina & S. S. Zlotskii

  2. Bashkir State Medical University, 450000, Ufa, Russia

    Yu. L. Baimurzina

Authors
  1. E. A. Yakovenko
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  2. Yu. L. Baimurzina
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  3. G. Z. Raskil’dina
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  4. S. S. Zlotskii
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Corresponding author

Correspondence to G. Z. Raskil’dina.

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Yakovenko, E.A., Baimurzina, Y.L., Raskil’dina, G.Z. et al. Synthesis and Herbicidal and Antioxidant Activity of a Series of Hetero- and Carbocyclic Derivatives of Monochloroacetic Acid. Russ J Appl Chem 93, 712–720 (2020). https://doi.org/10.1134/S1070427220050122

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  • DOI: https://doi.org/10.1134/S1070427220050122

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