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Electrodeposition of Fe–W Coatings from a Citric Bath with Use of Divided Electrolytic Cell

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

The use of the separated anode and cathode spaces during electrodeposition of the Fe–W alloy from a citrate bath (separation was carried out using a membrane with an average pore diameter of 0.74 μm) made it possible to significantly (up to 2 times) increase the current efficiency and deposition rate when using a graphite anode and to increase the performance electrolyte (constancy of surface composition and surface microhardness up to 4 A h l–1). The dynamics of changes in the concentrations of the alloy-forming components of the electrolyte was studied and it was shown that it is defined not only by the electrodeposition of iron and tungsten into the alloy, but also by the absorption of tungstate by the anode.

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Authors and Affiliations

  1. Shevchenko Pridnestrovie State University, 3300, Tiraspol, Moldova

    V. V. Danil’chuk, A. I. Shul’man, A. V. Gotelyak, S. P. Yushchenko & A. I. Dikusar

  2. Institute of Applied Physics, 2028, Chisinau, Moldova

    S. P. Yushchenko, K. V. Kovalenko & A. I. Dikusar

Authors
  1. V. V. Danil’chuk
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  2. A. I. Shul’man
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  3. A. V. Gotelyak
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  4. S. P. Yushchenko
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  5. K. V. Kovalenko
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  6. A. I. Dikusar
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Corresponding author

Correspondence to A. I. Dikusar.

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FUNDING

The work was carried out in the framework of budgetary funding of the Institute of Applied Physics of Moldova (project no. 15.817.02.05.A) and the Shevchenko Transnistrian State University (Tiraspol), as well as the European project H2020 “Smartelectrodes” (no. 778357).

CONFLICT OF INTERESTS

The authors declare that they have no conflict of interest.

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Danil’chuk, V.V., Shul’man, A.I., Gotelyak, A.V. et al. Electrodeposition of Fe–W Coatings from a Citric Bath with Use of Divided Electrolytic Cell. Russ J Appl Chem 93, 375–379 (2020). https://doi.org/10.1134/S107042722003009X

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  • DOI: https://doi.org/10.1134/S107042722003009X

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