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Effect of Gaseous Products on the Kinetics of Thermal Decomposition of Chloride-Containing Complex Ammonium Nitrate-Based Fertilizers

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The results of studying the effect of gaseous products on the kinetics of thermal decomposition of chloride-containing complex ammonium nitrate-based fertilizers using the methods of thermogravimetry and differential scanning calorimetry are presented. The experimental data were analyzed with the Sestak–Berggren model fitting method and the isoconversion differential Friedman method. Based on the results of the studies, the dependences of the decomposition rate on the degree of decomposition are determined and a conclusion is drawn on the reasons of the influence of the self-generated atmosphere on the kinetics of exothermic decomposition.

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Authors and Affiliations

  1. The Research Institute for Fertilizers and Insecto-Fungicides Named after Professor Y. Samoilov, 162622, Cherepovets, Russia

    K. G. Gorbovskiy & A. M. Norov

  2. Institute of Problems of Chemical Physics of Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. I. Kazakov

  3. Dmitry Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    A. I. Mikhaylichenko

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  1. K. G. Gorbovskiy
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  2. A. I. Kazakov
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Correspondence to K. G. Gorbovskiy.

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A.I. Kazakov used financing on the topic 0089-2019-0005 of the state assignment (state registration no. AAAA-A19-119101500098-3) “Fundamental and problem-oriented studies in the field of creating energy condensed systems (ECS) for various purposes (mixed solid rocket fuels, gunpowder , high-energy materials, pyrotechnic compositions) with a high level of efficiency and operational properties.”

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Gorbovskiy, K.G., Kazakov, A.I., Norov, A.M. et al. Effect of Gaseous Products on the Kinetics of Thermal Decomposition of Chloride-Containing Complex Ammonium Nitrate-Based Fertilizers. Russ J Appl Chem 93, 352–361 (2020). https://doi.org/10.1134/S1070427220030064

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