Abstract
The radical copolymerization of norbornene with norbornenyl acrylate or bornyl acrylate has been studied. New copolymers containing norbornane moieties in the side chain were produced. The influence of the reaction conditions on the composition, molecular weight characteristics, and glass transition temperature of the copolymers was studied. It was established that copolymers of norbornene with norbornenyl acrylate or bornyl acrylate have high transparency (95–97%) in the visible region (400–800 nm) and glass transition temperature. They effectively stabilize semiconductor nanoparticles, which allows these new copolymers to be considered as promising materials for optoelectronics.
Similar content being viewed by others
References
Makovetskii, K.L., Polym. Sci. Ser. C, 2008, vol. 50, no. 1, pp. 22–38.
Tritto, I., Boggioni, L., and Ferro, D.R., Coord. Chem. Rev., 2006, vol. 250, nos. 1–2, pp. 212–241.
Kaminsky, W., Sperber, O., and Werner, R., Coord. Chem. Rev., 2006, vol. 250, no. 1–2, pp. 110–117.
US Patent US 2799668, 1957. Novel Polymers of Ethylene and Bicyclo(2.2.1)-2-heptene.
Brauer, E., Wiegleb, H., and Helmsted, M., Polym. Bull., 1986, vol. 15, pp. 551–557.
Brauer, E., Wild, C., and Wlegleb, H., Polym. Bull., 1987, vol. 18, pp. 73–80.
Kaminsky, W., Arndt, M., and Bark, A., Polym. Prepr., 1991, vol. 32, no. 1, pp. 467–471.
US Patent 5929181, 1999. Method for Preparation of Copolymers Ethylene/Norbornene—Type Monomers with Nickel Catalysts.
Makovetskii, K.L., Bykov, V.I., and Finkelshtein, E.Sh., Kinet. Catal., 2006, vol. 47, no. 2, pp. 241–244.
RF Patent 2456304, 2012.
Bykov, V.I., Makovetskii, K.L., and Popov, D.S., Polym. Sci. Ser. B, 2012, vol. 54, nos. 1–2, pp. 99–105.
Author information
Authors and Affiliations
Corresponding author
Additional information
Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 5, pp. 634–638.
Rights and permissions
About this article
Cite this article
Bykov, V.I., Butenko, T.A. Norbornene Copolymers with Acrylates Bearing Norbornane Moieties: Promising Materials for Optoelectronics. Russ J Appl Chem 92, 667–671 (2019). https://doi.org/10.1134/S1070427219050136
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427219050136