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Synthesis, Characterization, and Catalytic Properties of Metal-Polymer Complexes Based on Copolymers of Polyethylene(propylene) Glycol Maleates with Acrylic Acid

  • Macromolecular Compounds and Polymeric Materials
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Abstract

New mono- and bimetallic polymer nanocomposites based on polyethylene(propylene) glycol maleates with acrylic acid and silver and nickel metals were prepared and studied. Metal particles were immobilized into copolymer supports by reduction of Ag+ and Ni2+ ions from solution of their nitrates to Ag0 and Ni0 in the presence of a catalyst, a solution of silver chloride in aqueous ammonia. The structure and composition of the complexes were determined by spectroscopy, calorimetry, microscopy, and chromatography. The catalytic activity was studied using pyridine hydrogenation as a model reaction.

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Acknowledgments

The study was performed at the Research Institute of Chemical Problems, Buketov State University, Karaganda, Kazakhstan and on the base of the Chair of Analytical and Inorganic Chemistry, Charles University, Prague, Czech Republic.

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Authors and Affiliations

  1. Buketov State University, Karaganda, 100028, Kazakhstan

    M. Zh. Burkeev, T. O. Khamitova, A. Zh. Sarsenbekova, S. Zh. Davrenbekov, E. M. Tazhbaev, G. E. Kozhabekova, Zh. K. Imanbekova & A. N. Bolatbai

  2. Charles University, Prague, Czech Republic

    D. Havliček

Authors
  1. M. Zh. Burkeev
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  2. T. O. Khamitova
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  3. D. Havliček
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  4. A. Zh. Sarsenbekova
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  5. S. Zh. Davrenbekov
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  6. E. M. Tazhbaev
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  7. G. E. Kozhabekova
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  8. Zh. K. Imanbekova
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  9. A. N. Bolatbai
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Corresponding author

Correspondence to T. O. Khamitova.

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Burkeev, M.Z., Khamitova, T.O., Havliček, D. et al. Synthesis, Characterization, and Catalytic Properties of Metal-Polymer Complexes Based on Copolymers of Polyethylene(propylene) Glycol Maleates with Acrylic Acid. Russ J Appl Chem 92, 1–8 (2019). https://doi.org/10.1134/S1070427219010014

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  • DOI: https://doi.org/10.1134/S1070427219010014

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