Skip to main content
Log in

New “Green” Polysaccharidal Inhibitor of Gas Hydrate Formation on the Basis of Carboxymethylcellulose Sodium Salt

  • Various Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Thermobaric conditions of gas hydrate formation in the presence of the carboxymethylcellulose sodium salt were studied under conditions of a quasi-equilibrium thermodynamic experiment. It is established that this polysaccharide slows down the rate and changes the conditions of gas hydrate formation, showing the properties of the thermodynamic and kinetic inhibitor with an efficiency exceeding 300 times the methanol when used in the same dosages.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Birchwood, R., Dai, J., Shelander, D., et al., Oilfield Rev., 2010, vol. 22, no. 1, pp. 18–33.

    Google Scholar 

  2. Carroll, J., Natural Gas Hydrates, Gulf Professional Publishing. 2014.

    Google Scholar 

  3. Kuznetsov, F.A., Istomin, V.A., and Rodionova, T.V., Ros. Khim. Zh., 2003, vol. 47, no. 3, pp. 5–18.

    CAS  Google Scholar 

  4. Kelland, M.A., Energy Fuels, 2006, vol. 20, no. 3, pp. 825–847.

    Article  CAS  Google Scholar 

  5. Kelland, M.A., Energy Fuels, 2017, vol. 31, no. 5, pp. 5046–5054.

    Article  CAS  Google Scholar 

  6. Tariq, M., Rooney, D., Othman, E., et al., Ind. Eng. Chem. Res., 2014, vol. 53, no. 46, pp. 17855–17868.

    Article  CAS  Google Scholar 

  7. Grunval’d, A.V., Neftegazovoe Delo, 2007, no. 2, pp. 1–25.

    Google Scholar 

  8. Fraser-Reid, B.O., Tatsuta, K., Thiem, J., et al., Glycoscience. Chemistry and Chemical Biology, In vol. 3, Berlin, Heidelberg: Springer-Verlag, 2008.

    Google Scholar 

  9. Arias, J.L. and Fernandez, M.S., Chem. Rev., 2008, vol. 108, no. 11, pp. 4475–4482.

    Article  CAS  Google Scholar 

  10. Kontrec, J., Kralj, D., Brecevic, L., and Falini, G., J. Cryst. Growth, 2008, vol. 310, no. 21, pp. 4554–4560.

    Article  CAS  Google Scholar 

  11. Rao, A., Berg, J.K., Kellermeier, M., and Gebauer, D., Eur. J. Mineral., 2014, vol. 26, pp. 537–552.

    Article  CAS  Google Scholar 

  12. Hasson, D., Shemer, H., and Sher, A., Ind. Eng. Chem. Res., 2011, vol. 50, pp. 7601–7607.

    Article  CAS  Google Scholar 

  13. Derakhshanian, V. and Banerjee, S., Ind. Eng. Chem. Res., 2012, vol. 51, pp. 4463–4465.

    Article  CAS  Google Scholar 

  14. Kirboga, S. and Oner, M., Colloids Surf. B, 2012, vol. 91, pp. 18–25.

    Article  CAS  Google Scholar 

  15. Ishmuratov, F.G., Koptyaeva, E.I., Voloshin, A., et al., Russ. J. Appl. Chem., 2015, vol. 88, no. 12, pp. 1920–1922.

    Article  CAS  Google Scholar 

  16. Dokichev, V.A., Koptyaeva, E.I., Ishmuratov, F.G., et al., Neft. Khoz-vo, 2016, no. 5, pp. 92–94.

    Google Scholar 

  17. Klemm, D., Schmauder, H., and Heinze, Th., Biopolymers: Biology, Chemistry, Biotechnology, Applications, Polysaccharide II, vol. 6, De, S., Baets, E.J., and Vandamme, A., Steinbüchel, Eds., Weinheim: Wiley-VCH, 2002, pp. 275–319.

  18. Batelaan, J.G., Van Ginkel, C.G., and Balk, F., Carboxymethylcellulose (CMC), The Handbook of Enviromental Chemistry, vol. 3, part F, Hutzinger, O., Ed., Berlin-Heidelberg: Springer-Verlag, 1992, pp. 329–336.

  19. Altamash, T., Qureshi, M.F., Aparicio, S., et al., J. Nat. Gas Sci. Eng., 2017, vol. 46, pp. 873–883.

    Article  CAS  Google Scholar 

  20. Haghighi, H., Chapoy, A., Burgess, R., et al., Fluid Phase Equilib., 2009, vol. 278, nos. 1–2, pp. 109–116.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Dokichev.

Additional information

Original Russian Text © F.G. Ishmuratov, N.T. Rakhimova, E.R. Ishmiyarov, A.I. Voloshin, V.N. Gusakov, Yu.V. Tomilov, N.E. Nifant’yev, V.A. Dokichev, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 4, pp. 584−587.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ishmuratov, F.G., Rakhimova, N.T., Ishmiyarov, E.R. et al. New “Green” Polysaccharidal Inhibitor of Gas Hydrate Formation on the Basis of Carboxymethylcellulose Sodium Salt. Russ J Appl Chem 91, 653–656 (2018). https://doi.org/10.1134/S1070427218040183

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427218040183

Navigation