Skip to main content
SpringerLink
Log in

Salt stimulus response of a carboxyl betaine amphoteric hydrophobic associative polyacrylamide

  • Various Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

A carboxyl betaine amphoteric hydrophobic associative polyacrylamide (CBAHAPAM) was synthesized in water solution through radical polymerization, which was made of polyacrylamide, N,N′-dimethyl octadecyl allyl ammonium chloride (DOAC), 1-carboxy-N,N′-dimethyl-N-(3-methylacryl-amidopropyl) ethanaminium inner salt (CBMAA-1) and 2-acrylamide-2-methyl propanesulfonic acid (AMPS). Self-assembly associative properties in CBAHAPAM solution and the effects of salt and temperature on the associative behavior were investigated by the means of viscosimetry, rheological test, fluorescence spectroscopy, and environmental scanning electron microscope (ESEM). Results showed that the critical association concentration (CAC) of the CBAHAPAM was about 0.30–0.32 wt %. The addition of the calcium chloride made the apparent viscosity of CBAHAPAM solution improve drastically than NaCl. Meanwhile, CBAHAPAM solution with NaCl and CaCl2 showed up better heat and shearing resistance than CBAHAPAM solution itself. The network structures of CBAHAPAM aqueous or salt solution was observed by ESEM. NaCl and CaCl2 reinforced the network structures, which further indicated that CBAHAPAM solution had a excellent capacity of salt thickening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Sabhapondit, A., Borthakur, A., and Haque, I., J. Appl. Polym. Sci., 2003, vol. 87, no. 12, pp. 1869–1878.

    Article  CAS  Google Scholar 

  2. Volpert, E., Selb, J., Candau, F., et al., Langmuir, 1998, vol. 14, no.7, pp. 1870–1879.

    Article  CAS  Google Scholar 

  3. Wever, DAZ, Picchioni, F, and Broekhuis, A.A., Prog. Polym. Sci., 2011, vol. 36, no. 11, pp. 1558–1628.

    Article  CAS  Google Scholar 

  4. Gao, B.J., Jiang, L.D., and Liu, K.K., Eur. Polym. J., 2007, vol. 43, no. 10, pp. 4530–4540.

    Article  CAS  Google Scholar 

  5. Song, H., Zhang, S.F., Ma, X.C., Wang, D.Z., and Yang, J.Z., Carbohydr. Polym., 2007, vol. 69, no. 1, pp. 189–195.

    Article  CAS  Google Scholar 

  6. Yang, X., Liu, J., Li, P., and Liu, C., J. Polym. Res., 2015, vol. 22, no. 6, pp. 1–7.

    Article  Google Scholar 

  7. Huang, Z., Lu, H., and He, Y., Colloid & Polym. Sci., 2006, vol. 285, no. 285, pp. 365–370.

    Article  CAS  Google Scholar 

  8. Gou, S., Luo, S., Liu, T., et al., New J. Chem., 2015, vol. 39, no. 10, pp. 7805–7814.

    Article  CAS  Google Scholar 

  9. Shashkina, Y.A., Zaroslov, Y.D., Smirnov, V.A., et al., Polymer, 2003, vol. 44, no. 8, pp. 2289–2293.

    Article  CAS  Google Scholar 

  10. Jiang, G., Huang, L., Li, B., et al., J. Appl. Polym. Sci., 2012, vol. 123, no. 1, pp. 66–76.

    Article  CAS  Google Scholar 

  11. Bonte, N., Laschewsky, A., Mayer, B., and Vermylen, V., Macromol. Symp., 1996, vol. 102, no. 1, pp. 273–280.

    Article  CAS  Google Scholar 

  12. Johnson, K.M., Fevola, M.J., and McCormick, C.L., J. Appl. Polym. Sci., 2004, vol. 92, no. 1, pp. 647–657.

    Article  CAS  Google Scholar 

  13. Miyazawa, K. and Winnik, F.M., Macromol., 2002, vol. 35, no. 7, pp. 2440–2444.

    Article  CAS  Google Scholar 

  14. Miyazawa, K. and Winnik, F.M., Macromol., 2002, vol. 35, no. 25, pp. 9536–9544.

    Article  CAS  Google Scholar 

  15. Miyazawa, K. and Winnik, F.M., J. Phys. Chem. B, 2003, vol. 107, no. 38, pp. 10677–10682.

    Article  CAS  Google Scholar 

  16. Grassl, B., Mathis, A., Rawiso, M., and Galin, J.C., Macromol., 1997, vol. 30, no. 7, pp. 2075–2084.

    Article  CAS  Google Scholar 

  17. Rodriguez, M., Xue, J., Gouveia, L.M., et al., Colliod Surf. A: Physicochem. Eng. Aspects, 2011, vol. 373, no. 1, pp. 66–73.

    Article  CAS  Google Scholar 

  18. Fevola, M.J., Bridges, J.K., Kellum, M.G., et al., J. Appl. Polym. Sci., 2004, vol. 94, no. 1, pp. 24–39.

    Article  CAS  Google Scholar 

  19. Georgiev, G.S., Kamenska, E.B., Vassileva, E.D., et al., Biomacromol., 2006, vol. 7, no. 4, pp. 1329–1334.

    Article  CAS  Google Scholar 

  20. Liu, C, Hong, B, Xu, K, et al., Polymer Bull., 2014, vol. 71, no. 12, pp. 3051–3065.

    Article  CAS  Google Scholar 

  21. Wyatt, N.B., Gunther, C.M., and Liberatore, M.W., Polymer, 2011, vol. 52, no. 11, pp. 2437–2444.

    Article  CAS  Google Scholar 

  22. Gohy, J.F., Creutz, S., Garcia, M., et al., Macromol., 2000, vol. 33, no. 17, pp. 6378–6387.

    Article  CAS  Google Scholar 

  23. Pu, W., Liu, R., Li, B., et al., Rsc. Advances, 2015, vol. 5, no. 107, pp. 88002–88013.

    Article  CAS  Google Scholar 

  24. Chen, H., Wang, Z., Ye, Z., and Han, L., J Appl. Polym. Sci., 2014, vol. 131, no. 1, pp. 1–15.

    Article  Google Scholar 

  25. Eckelt, J., Knopf, A., and Wolf, B.A., Macromol., 2008, vol. 41, no. 41, pp. 912–918.

    Article  CAS  Google Scholar 

  26. Kudaibergenov, S.E., Didukh, A.G., Zhumadilova, G.T., et al., Macromol. Symp., 2004, vol. 207, no. 1, pp. 153–172.

    Article  CAS  Google Scholar 

  27. Sitnikova, T.A., Rakhnyanskaya, A.A., Yaroslavova, E.G., et al., Polym. Sci. Ser. A, 2009, vol. 51, no. 6, pp. 630–637.

    Article  Google Scholar 

  28. Coronel, V.J.G., and Jiménez-Regalado E.J., Polymer Bulletin, 2011, vol. 67, no. 2, pp. 251–262.

    Article  Google Scholar 

  29. Doyaguez, Elisa, G., Parra, F, Corrales, G., et al, Polymer, 2009, val. 50, no.l9, pp. 4438–4446.

    Article  CAS  Google Scholar 

  30. Johnson, K.M., Fevola, M.J, and McCormick, C.L., J Appl. Polym. Sci., 2004, val. 92, no. 1, pp. 647–657.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Chengdu, 610500, PR China

    Hongping Quan, Haiyang Tian & Zhiyu Huang

  2. College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, 610500, PR China

    Hongping Quan, Haiyang Tian & Zhiyu Huang

  3. College of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400715, PR China

    Yuwei Long

Authors
  1. Hongping Quan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Haiyang Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhiyu Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yuwei Long
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hongping Quan.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Quan, H., Tian, H., Huang, Z. et al. Salt stimulus response of a carboxyl betaine amphoteric hydrophobic associative polyacrylamide. Russ J Appl Chem 90, 1193–1201 (2017). https://doi.org/10.1134/S1070427217070266

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427217070266

Search

Navigation