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Synthesis of basic bismuth(III) oxalate by precipitation from nitrate solutions

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Conditions were determined in which basic bismuth oxalate of composition BiC2O4(OH) can be obtained by direct precipitation upon addition of oxalic acid from nitrate solutions used in production of bismuth compounds. The composition of the compound was confirmed by X-ray phase and chemical analyses, IR and Raman spectroscopy, and thermogravimetry. Electron microscopy was used to examine the effect of the composition of the reaction medium and temperature on the morphology of the product being obtained. It was shown that β-Bi2O3 can be obtained in oxidative thermolysis of basic bismuth oxalate, depending on its morphology.

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Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    E. V. Timakova, L. I. Afonina, N. V. Bulina, S. S. Shatskaya & Yu. M. Yukhin

  2. Novosibirsk State Technical University, pr. Karla Marksa 20, Novosibirsk, 630073, Russia

    E. V. Timakova & L. I. Afonina

  3. Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 13, Novosibirsk, 630090, Russia

    V. A. Volodin

  4. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    V. A. Volodin

Authors
  1. E. V. Timakova
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  2. L. I. Afonina
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  3. N. V. Bulina
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  4. S. S. Shatskaya
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  5. Yu. M. Yukhin
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  6. V. A. Volodin
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Corresponding author

Correspondence to E. V. Timakova.

Additional information

Original Russian Text © E.V. Timakova, L.I. Afonina, N.V. Bulina, S.S. Shatskaya, Yu.M. Yukhin, V.A. Volodin, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 7, pp. 826−832.

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Timakova, E.V., Afonina, L.I., Bulina, N.V. et al. Synthesis of basic bismuth(III) oxalate by precipitation from nitrate solutions. Russ J Appl Chem 90, 1040–1046 (2017). https://doi.org/10.1134/S1070427217070035

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  • DOI: https://doi.org/10.1134/S1070427217070035

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