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Adsorption properties of new Silochrome-based chelate-containing gas chromatographic materials

  • Sorption and Ion Exchange Processes
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Abstract

Adsorbents were obtained on the basis of Silochrome S80 modified with complex compounds of copper(II) and nickel(II) with bidentate nitrogen-containing organic ligands. The gas-chromatographic method was used to study the thermodynamic characteristics of the adsorption of organic compounds belonging to various classes on Silochrome S80 before and after its modification. It was found that supported metal complexes strongly affect the chromatographic polarity and favor a more selective separation of mixtures of close-boiling carbonyl compounds and saturated and unsaturated light hydrocarbons.

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Authors and Affiliations

  1. Tomsk State University, Kievskaya ul. 60A, Tomsk, 634061, Russia

    A. I. Makarycheva & Yu. G. Slizhov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrentʼeva 3, Novosibirsk, 630090, Russia

    V. P. Kirin

Authors
  1. A. I. Makarycheva
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  2. Yu. G. Slizhov
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  3. V. P. Kirin
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Correspondence to A. I. Makarycheva.

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Original Russian Text © A.I. Makarycheva, Yu.G. Slizhov, V.P. Kirin, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 4, pp. 434−442.

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Makarycheva, A.I., Slizhov, Y.G. & Kirin, V.P. Adsorption properties of new Silochrome-based chelate-containing gas chromatographic materials. Russ J Appl Chem 90, 533–540 (2017). https://doi.org/10.1134/S1070427217040073

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  • DOI: https://doi.org/10.1134/S1070427217040073

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