Abstract
Formal kinetic model is suggested on the basis of experimental studies of the heat-release kinetics in decomposition of an anion-exchange resin, copolymer of N-methyl-4-vinylpyridinium chloride and divinylbenzene. The model makes it possible to determine the service life of the resin in the temperature range 100–170°C in optimization of the process in which monosilane is synthesized from trichlorosilane with the resin used as a catalyst.
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Original Russian Text © I.A. Blinov, V.M. Belokhvostov, A.A. Kossoy, D.A. Mukhortov, M.P. Kambur, O.V. Lantratova, E.S. Kurapova, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 4, pp. 437−441.
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Blinov, I.A., Belokhvostov, V.M., Kossoy, A.A. et al. Thermal decomposition of anion-exchange resin based on copolymer of 4-vinylpyridine. Russ J Appl Chem 89, 554–558 (2016). https://doi.org/10.1134/S1070427216040054
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DOI: https://doi.org/10.1134/S1070427216040054