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Synthesis of NiW/Al2O3 hydrotreating catalysts from ammonium paratungstate using chelating agents

  • Applied Electrochemistry and Corrosion Protection of Metals
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Abstract

Procedures are suggested for preparing NiW/Al2O3 catalysts using ammonium paratungstate as a tungsten source and citric acid and D(+)-sorbitol as chelating agents. The catalysts prepared using the suggested reagents are characterized by increased dispersity of the sulfide component compared to the NiW/Al2O3 catalyst prepared by the traditional procedure using ammonium metatungstate and nickel(II) nitrate. In transformations of dibenzothiophene, quinoline, and naphthalene, the NiW/Al2O3 catalysts prepared using ammonium paratungstate and citric acid or D(+)-sorbitol considerably surpass in the activity the NiW/Al2O3 catalyst prepared by the traditional procedure.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, ul. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    V. Yu. Pereyma, E. Yu. Gerasimov, O. V. Klimov & A. S. Noskov

Authors
  1. V. Yu. Pereyma
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  2. E. Yu. Gerasimov
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  3. O. V. Klimov
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  4. A. S. Noskov
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Corresponding author

Correspondence to V. Yu. Pereyma.

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Original Russian Text © V.Yu. Pereyma, E.Yu. Gerasimov, O.V. Klimov, A.S. Noskov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 9, pp. 1313-1319.

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Pereyma, V.Y., Gerasimov, E.Y., Klimov, O.V. et al. Synthesis of NiW/Al2O3 hydrotreating catalysts from ammonium paratungstate using chelating agents. Russ J Appl Chem 88, 1458–1463 (2015). https://doi.org/10.1134/S1070427215090128

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  • DOI: https://doi.org/10.1134/S1070427215090128

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