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Combined neutralization of nitrogen(I), (II), and (IV) oxides in production of adipic acid

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Compositions of a catalyst and a chemisorbent for effective purification of oxygen-containing effluent gases in production of adipic acid to remove N2O, NO, and NO2 were developed. Their use enables catalytic decomposition of N2O as the prevalent component at temperatures of up to 500°C and chemisorption purification to remove microimpurities of NO and NO2 at 20°C and in excess amount of oxygen. The optimization of the catalyst and chemisorbent compositions made it possible to diminish the content of the expensive ruthenium and cerium to 4.5 and 4.2 wt %, respectively, with the developed service characteristics preserved.

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References

  1. Furman, M.S., Badrian, A.S., Gol’dman, A.M., et al., Proizvodstvo tsiklogeksanona i adipinovoi kisloty okisleniem tsiklogeksana (Production of Cyclohexanone and Adipic Acid via Oxidation of Cyclohexane), Furman, M.S. and Gol’dman, A.M., Eds., Moscow: Khimiya, 1967.

  2. Volk, C.M., Elkins, J.W., Fahey, D.W., et al., J. Geophys. Res., 1997, vol. 102, pp. 25543–25564.

    Article  CAS  Google Scholar 

  3. Trimm, D.L., and Stanislaus, A., Appl. Catal., 1986, vol. 21, pp. 215–238.

    Article  CAS  Google Scholar 

  4. Spetsow, E.A., Nefedova, L.A., and Lavrishcheva, S.A., Russ. J. Appl. Chem., 2014, vol. 87, no. 4, pp. 434–438.

    Article  CAS  Google Scholar 

  5. Li, K., Wang, X.F., and Zeng, H.C., Trans. IChemE. B, 1997, vol. 75, pp. 807–812.

    Article  CAS  Google Scholar 

  6. Pekridis, G., Athanasiou, C., Konsolakis, M., et al., Top. Catal., 2009, vol. 52, pp. 1880–1887.

    Article  CAS  Google Scholar 

  7. Krylov, O.V. and Kiselev, V.F., Adsorbtsiya i kataliz na perekhodnykh metallakh i ikh oksidakh (Adsorption and Catalysis on Transition Metals and Their Oxides), Moscow: Khimiya, 1981.

    Google Scholar 

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Correspondence to E. A. Spetsow.

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Original Russian Text © E.A. Spetsow, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 9, pp. 1233-1239.

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Spetsow, E.A. Combined neutralization of nitrogen(I), (II), and (IV) oxides in production of adipic acid. Russ J Appl Chem 88, 1381–1387 (2015). https://doi.org/10.1134/S1070427215090013

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  • DOI: https://doi.org/10.1134/S1070427215090013

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