Abstract
Data on the phase diagram of the lithium–antimony system and on the thermodynamic properties of lithium–antimony alloys and their electrochemical behavior in molten and nonaqueous electrolytes are summarized and analyzed. The possibility of using antimony and its alloys with various metals as anode material in lithium–ion batteries is discussed.
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Skundin, A.M. and Voronkov, G.Ya., Khimicheskie istochniki toka: 210 let (Chemical Current Sources: 210 Years), Moscow: Pokolenie, 2010.
Winter, M., Besenhard, J.O., Spahr, M.E., and Novak, P., Adv. Mater., 1998, vol. 10, no. 10, pp. 725–763.
Skundin, A.M., Efimov, O.N., and Yarmolenko, O.V., Russ. Chem. Rev., 2002, vol. 71, no. 4, p. 329–346.
Scrosati, B. and Garche, J., J. Power Sources, 2010, vol. 195, pp. 2419–2430.
Song, M.-K., Park, S., Alamgir, F.M., et al., Mater. Sci. Eng. R, 2011, vol. 72, pp. 203–252.
Goodenough, J.B. and Park, K.-S., J. Am. Chem. Soc., 2013, vol. 135, pp. 1167–1176.
Kulova, T.L., Russ. J. Electrochem., 2013, vol. 49, no. 1, pp. 1–25.
Yaroslavtsev, A.B., Kulova, T.L., and Skundin, A.M., Russ. Chem. Rev., 2015, vol. 84, no. 8, pp. 826–852.
Barsukov, V.Z., Il’in, E.A., and Jaskula, M., Elektrokhim. Energet., 2002, vol. 2, no. 4, pp. 153–164.
Thackeray, M.M., Vaughey, J.T., and Fransson, L.M.L., J. Met., 2002, vol. 54, pp. 20–23.
Benedek, R. and Thackeray, M.M., J. Power Sources, 2002, vol. 110, pp. 406–411.
Hassoun, J., Panero, S., and Scrosati, B., Fuel Cells, 2009, no. 3, pp. 277–283.
Zhang, W.-J., J. Power Sources, 2011, vol. 196, pp. 13–24.
Kamali, A.R. and Fray, D.J., Rev. Adv. Mater., 2011, vol. 27, pp. 14–24.
Morachevskii, A.G. and Demidov, A.I., Russ. J. Appl. Chem., 2015, vol. 88, no. 4, pp. 547–566.
Morachevskii, A.G., Russ. J. Appl. Chem., 2015, vol. 88, no. 7, pp. 1087–1105.
Park, C.-M., Yoon, S., Lee, S., and Kim, J.H., J. Electrochem. Soc., 2007, vol. 154, no. 10, pp. A917–A920.
Kim, H., Boysen, D.A., Newhouse, J.M., et al., Chem. Rev., 2013, vol. 113, pp. 2075–2099.
Wang, K., Jiang, K., Chung, B., et al., Nature, 2014, vol. 514, pp. 348–350.
Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik (Phase Diagrams of Binary Metal Systems: Handbook), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1999, vol. 3, book 1.
Drits, M.E. and Zusman, L.L., Splavy shchelochnykh i shchelochnozemel’nykh metallov: Spravochnik (Alloys of Alkali and Alkaline Earth Metals: Handbook), Moscow: Metallurgiya, 1986.
Sangster, J. and Pelton, A.D., J. Phase Equilib., 1993, vol. 14, no. 4, pp. 514–517.
Fedorov, P.I., Russ. J. Inorg. Chem., 1995, vol. 40, no. 5, pp. 815–817.
Weppner, W. and Huggins, R.A., J. Electrochem. Soc., 1978, vol. 125, no. 1, pp. 7–14.
Nikitin, A.V., Demidov, A.I., and Morachevskii, A.G., Zh. Prikl. Khim., 1980, vol. 53, no. 7, pp. 1641–1644.
Nikitin, A.V., Demidov, A.I., and Morachevskii, A.G., Zh. Prikl. Khim., 1982, vol. 55, no. 4, pp. 915–916.
Demidov, A.I., Dukhanin, G.P., and Morachevskii, A.G., Elektrokhimiya, 1983, vol. 19, no. 12, pp. 1695–1699.
Okamoto, H., J. Phase Equilib., 1996, vol. 17, no. 3, p. 271.
Okamoto, H. and Massalski, T.B., J. Phase Equilib., 1991, vol. 12, no. 2, pp. 148–168.
Kane, M.M., Newhouse, J.M., and Sadoway, D.R., J. Electrochem. Soc., 2015, vol. 162, no. 3, pp. A421–A425.
Guminski, C. and Borgstedt, H.U., Arch. Metall. Mater., 2004, vol. 49, no. 3, pp. 529–534.
Seefurth, R.N. and Sharma, R.A., J. Electrochem. Soc., 1975, vol. 122, no. 8, pp. 1049–1053.
Morachevskii, A.G., Demidov, A.I., Bulatova, V.F., and Klebanov, E.B., in Issledovaniya v oblasti khimii rasplavov i tverdykh elektrolitov (Studies in the Field of Chemistry of Melts and Solid Electrolytes), Kiev: Naukova Dumka, 1985, pp. 100–105.
Morachevskii, A.G., Voronin, G.F., Geiderikh, V.A., and Kutsenok, I.B., Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (Electrochemical Methods of Investigation in Thermodynamics of Metal Systems), Moscow: Akademkniga, 2003.
Shchukarev, S.A., Volf, E., and Morozova, M.P., J. Gen. Chem. USSR, 1954, vol. 24, no. 11, pp. 1887–1888.
Morachevskii, A.G., Russ. J. Appl. Chem., 2002, vol. 75, no. 3, pp. 367–369.
Schlesinger, M.E., Chem. Rev., 2013, vol. 113, pp. 8066–8092.
Robie, A. and Hemingway, B.C., Thermodynamic Properties of Minerals and Related Substances at 298.15 K and 1 bar (105 pascals) Pressure and at Higher Temperatures: US Geological Survey Bull. 2131. Washington: US Government, 1995.
Demidov, A.I., Klebanov, E.B., Morachevskii, A.G., and Nikitin, A.V., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1982, no. 6, pp. 63–65.
Temnogorova, N.V., Demidov, A.I., and Morachevskii, A.G., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1980, no. 1, pp. 121–122.
Smith, J.F. and Moser, Z., J. Nucl. Mater., 1976, vol. 59, no. 2, pp. 158–174.
Morachevskii, A.G. and Demidov, A.I., Zh. Fiz. Khim., 1983, vol. 57, no. 9, pp. 2113–2128.
Morachevskii, A.G., Shesterkin, I.A., Busse-Machukas, V.B., et al., Natrii. Svoistva, proizvodstvo i primenenie (Sodium. Properties, Production, and Use), St. Petersburg: Khimiya, 1992.
Morachevskii, A.G., Beloglazov, I.N., and Kasymbekov, B.A., Kalii. Svoistva, proizvodstvo, primenenie (Potassium. Properties, Production, and Use), Moscow: Ruda i Metally, 2000.
Morachevskii, A.G., Zh. Prikl. Khim., 1994, vol. 67, no. 12, pp. 1937–1950.
Morachevskii, A.G., Russ. J. Appl. Chem., 1997, vol. 70, no. 7, pp. 1001–1015.
Morachevskii, A.G., Zh. Prikl. Khim., 1992, vol. 62, no. 6, pp. 1201–1218.
Morachevskii, A.G. and Demidov, A.I., Itogi Nauki Tekh., Ser.: Rastv., Raspl., 1975, vol. 2, pp. 242–270.
Wang, J., Raistrick, I.D., and Huggins, R.A., J. Electrochem. Soc., 1986, vol. 133, no. 3, pp. 457–460.
Kedrinskii, I.A., Dmitrenko, V.E., and Grudyanov, I.I., Litievye istochniki toka (Lithium Current Sources), Moscow: Energoatomizdat, 1992.
Demakhin, A.G., Ovsyannikov, V.M., and Ponomarenko, S.M., Elektrolitnye sistemy litievykh KhIT (Electrolyte Systems for Lithium Chemical Current Sources), Saratov: Saratovsk. Univ., 1993.
Zingel’, E.M., Timofeev, N.V., and Kedrinskii, I.A., Nevodnye elektrolity dlya litievykh istochnikov toka (Nonaqueous Electrolytes for Lithium Current Sources), Krasnoyarsk: Sib. Gos. Tekh. Univ., 2001.
Kedrinskii, I.A. and Yakovlev, V.G., Litii-ionnye akkumulyatory (Lithium–Ion Batteries), Krasnoyarsk: Platina, 2002.
Scrosati, B., J. Electrochem. Soc., 1992, vol. 139, no. 10, pp. 2776–2781.
Huggins, R.A., Solid State Ionics, 1998, vols. 113–115, pp. 57–67.
Winter, M. and Besenhard, J.O., Electrochim. Acta, 1999, vol. 45, no. 1, pp. 31–50.
Larcher, D., Beaulieu, L.Y., Mao, O., et al., J. Electrochem. Soc., 2000, vol. 147, no. 5, pp. 1703–1708.
Skundin, A.M., Elektrokhim. Energet., 2001, vol. 1, no. 1, pp. 5–15.
Thackeray, M.M., Vaughey, J.T., Johnson, C.S., et al., J. Power Sources, 2003, vol. 113, pp. 124–130.
Dubasova, V.S. and Kanevskii, L.S., Elektrokhim. Energet., 2005, vol. 5, no. 2, pp. 109–119.
Yang, J., Winter, M., and Besenhard, J.O., Solid State Ionics, 1996, vol. 90, pp. 281–287.
Besenhard, J.O., Yang, J., and Winter, M., J. Power Sources, 1997, vol. 68, no. 1, pp. 87–90.
Yang, J., Wachtler, M., Winter, M., and Besenhard, J.O., Electrochem. Solid-State Lett., 1999, vol. 2, no. 4, pp. 161–163.
Besenhard, J.O., Wachtler, M., Winter, M., et al., J. Power Sources, 1999, vols. 81–83, pp. 268–275.
Wachtler, M., Besenhard, J.O., Winter, M., et al., J. Power Sources, 2001, vol. 94, pp. 189–193.
Rom, I., Wachtler, M., Papst, I., et al., Solid State Ionics, 2001, vol. 143, nos. 3–4, pp. 329–336.
Wachtler, M., Winter, M., and Besenhard, J.O., J. Power Sources, 2002, vol. 105, pp. 151–160.
Yang, J., Takeda, Y., Imanishi, N., and Yamamoto, O., J. Electrochem. Soc., 1999, vol. 146, no. 11, pp. 4009–4013.
Yang, J., Takeda, Y., Imanishi, N., and Yamamoto, O., J. Electrochem. Soc., 2000, vol. 147, no. 5, pp. 1671–1676.
Yang, J., Takeda, Y., Imanishi, N., et al., Solid State Ionics, 2000, vol. 133, pp. 189–194.
Yang, J., Takeda, Y., Imanishi, N., et al., Solid State Ionics, 2000, vol. 135, pp. 175–180.
Yang, J., Takeda, Y., Capiglia, C., et al., J. Power Sources, 2003, vols. 119–121, pp. 56–59.
Li, H., Zhu, G., Huang, X., and Chen, L., J. Mater. Chem., 2000, vol. 10, pp. 693–696.
Li, H., Shi, L., Lu, W., et al., J. Electrochem. Soc., 2001, vol. 148, no. 8, pp. A915–A922.
Li, H., Shi, L., Wang, Q., et al., Solid State Ionics, 2002, vol. 148, pp. 247–258.
Fernandez-Madrigal, F.J., Lavela, P., Vicente, C.P., and Tirado, J.L., Chem. Mater., 2002, vol. 14, pp. 2962–2968.
Mukaibo, H., Osaka, T., Reale, P., et al., J. Power Sources, 2004, vol. 132, pp. 225–228.
Trifonova, A., Wachtler, M., Wagner, M.R., et al., Solid State Ionics, 2004, vol. 168, pp. 51–59.
Zhao, H., Yin, C., Guo, H., and Qiu, W., Electrochem. Solid-State Lett., 2006, vol. 9, no. 6, pp. A281–A284.
Zhao, H., Yin, C., Guo, H., et al., J. Power Sources, 2007, vol. 174, pp. 916–920.
Zhao, H., Zhu, Z., Yin, C., et al., Mater. Chem. Phys., 2008, vol. 110, pp. 201–205.
Simonin, L., Lafont, U., and Kelder, E.M., J. Power Sources, 2008, vol. 180, pp. 859–863.
Zhao, H., Jiang, C., He, X., and Ren, J., J. Power Sources, 2008, vol. 184, pp. 532–537.
Diagrammy sostoyaniya metallicheskikh sistem (Phase Diagrams of Metal Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 2000, vol. 3, book 2.
Allen, W.P. and Perepezko, J.H., Scr. Metall., 1990, vol. 24, no. 11, pp. 2215–2220.
Vaughey, J.T., O’Hara, J., and Thackeray, M.M., Electrochem. Solid-State Lett., 2000, vol. 3, no. 1, pp. 13–16.
Johnson, C.S., Vaughey, J.T., Thackeray, M.M., et al., Electrochem. Commun., 2000, vol. 2, pp. 595–600.
Hewitt, K.C., Beaulieu, L.Y., and Dahn, J.R., J. Electrochem. Soc., 2001, vol. 148, no. 5, pp. A402–A410.
Vaughey, J.T., Johnson, C.S., Kropf, A.J., et al., J. Power Sources, 2001, vols. 97–98, pp. 194–197.
Tostmann, H., Kropf, A.J., Johnson, C.S., et al., Phys. Rev. B, 2002, vol. 66, pp. 014106-1-014106-12.
Sarakonsri, T., Jonson, C.S., Hackney, S.A., and Thackeray, M.M., J. Power Sources, 2006, vol. 153, pp. 319–327.
Stjerndahl, M., Bryngelsson, H., Gustafsson, T., et al., Electrochim. Acta, 2007, vol. 52, pp. 4947–4955.
Fransson, L.M.L., Vayghey, J.T., Benedek, R., et al., Electrochem. Commun., 2001, vol. 3, pp. 317–323.
Morcrette, M.M., Larcher, D., Tarascon, J.M., et al., Electrochim. Acta, 2007, vol. 52, pp. 5339–5345.
Matsuno, S., Noji, M., Nakayama, M., et al., J. Electrochem. Soc., 2008, vol. 155, no. 2, pp. A151–A157.
Nakayama, M., Matsuno, S., Shirakawa, J., and Wakihara, M.J., Electrochem. Soc., 2008, vol. 155, no. 7, pp. A505–A511.
Zhao, X.B. and Cao, G.S., Electrochim. Acta, 2001, vol. 46, pp. 891–896.
Honda, H., Sakaguchi, H., Tanaka, I., and Esaka, T., J. Power Sources, 2003, vol. 123, pp. 216–221.
Vaughey, J.T., Fransson, L., Swinger, H.A., et al., J. Power Sources, 2003, vols. 119–121, pp. 64–68.
Xie, J., Zhao, X.B., Cao, G.S., et al., Mater. Lett., 2003, vol. 57, pp. 4673–4677.
Xie, J., Zhao, X.B., Cao, G.S., et al., J. Alloys Compd., 2005, vol. 393, pp. 283–286.
Villevieille, C., Ionica-Bousquet, C.-M., Ducourant, B., et al., J. Power Sources, 2007, vol. 172, pp. 388–394.
Alcantara, R., Fernandez-Madrigal, F.J., Lavela, P., et al., J. Mater. Chem., 1999, vol. 9, pp. 2517–2521.
Fernandez-Madrigal, F.J., Lavela, P., Perez-Vicente, C., and Tirado, J.L., J. Electroanal. Chem., 2001, vol. 501, pp. 205–209.
Park, C.-M. and Sohn, H.-J., J. Electrochem. Soc., 2010, vol. 157, no. 1, pp. A46–A49.
Gomes-Camer, J.L., Villeveille, C., and Novak, P., Mater. Chem. A, 2013, vol. 1, no. 41, pp. 13011–13016.
Yin, J., Wada, M., Tanase, S., and Sakai, T., J. Electrochem. Soc., 2004, vol. 151, no. 6, pp. A867–A872.
Rönnebro, E., Yin, J., Kitano, A., et al., J. Electrochem. Soc., 2005, vol. 152, no. 1, pp. A152–A157.
Matsuno, S., Nakayama, M., and Wakihara, M., J. Electrochem. Soc., 2008, vol. 155, no. 1, pp. A61–A65.
Guo, H., Zhao, H., Jia, X., et al., J. Power Sources, 2007, vol. 174, pp. 921–926.
Tabuchi, T., Hochgatterer, N., Ogumi, Z., and Winter, M., J. Power Sources, 2009, vol. 188, pp. 552–557.
Wang, F., Zhao, M., and Song, X., J. Power Sources, 2008, vol. 175, pp. 558–563.
Zhao, X.B., Cao, G.S., Lv, C.P., et al., J. Alloys Compd., 2001, vol. 315, pp. 265–269.
Hassoun, J., Derrien, G., Panero, S., and Scrosati, B., J. Power Sources, 2008, vol. 183, pp. 339–343.
Hassoun, J., Derrien, G., Panero, S., and Scrosati, B., Electrochim. Acta, 2009, vol. 54, pp. 4441–4444.
Park, C.-M. and Sohn, H.-J., Electrochim. Acta, 2009, vol. 54, pp. 6367–6373.
Li, H., Huang, X., and Chen, L., Solid State Ionics, 1999, vol. 123, pp. 189–197.
Yoon, S. and Manthiram, A., Chem. Mater., 2009, vol. 21, pp. 3898–3904.
Bryngelsson, H., Eskhult, J., Nyholm, L., et al., Chem. Mater., 2007, vol. 19, pp. 1170–1180.
Bryngelsson, H., Eskhult, J., Edström, K., and Nyholm, L., Electrochim. Acta, 2007, vol. 53, pp. 1062–1073.
Larcher, D., Prakash, A.S., Laffont, L., et al., J. Electrochem. Soc., 2006, vol. 153, no. 9, pp. A1778–A1787.
Xue, M.Z. and Fu, Z.W., Electrochem. Commun., 2006, vol. 8, pp. 1250–1256.
Pridatko, K.I. and Churikov, A.I., Elektrokhim. Energet., 2005, vol. 5, no. 1, pp. 16–29.
Ehrich, G.M., Durand, C., Chen, X., et al., J. Electrochem. Soc., 2000, vol. 147, no. 3, pp. 886–891.
Simonin, L., Laffont, U., Tabrizi, N., et al., J. Power Sources, 2007, vol. 174, pp. 805–810.
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Original Russian Text © A.G. Morachevskii, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 11, pp. 1521−1533.
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Morachevskii, A.G. Lithium–antimony alloys: Phase diagram, thermodynamic properties, electrochemical behavior in molten and nonaqueous electrolytes, and use in lithium–ion batteries. Russ J Appl Chem 88, 1737–1749 (2015). https://doi.org/10.1134/S10704272150110014
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DOI: https://doi.org/10.1134/S10704272150110014