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Lithium–antimony alloys: Phase diagram, thermodynamic properties, electrochemical behavior in molten and nonaqueous electrolytes, and use in lithium–ion batteries

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Abstract

Data on the phase diagram of the lithium–antimony system and on the thermodynamic properties of lithium–antimony alloys and their electrochemical behavior in molten and nonaqueous electrolytes are summarized and analyzed. The possibility of using antimony and its alloys with various metals as anode material in lithium–ion batteries is discussed.

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References

  1. Skundin, A.M. and Voronkov, G.Ya., Khimicheskie istochniki toka: 210 let (Chemical Current Sources: 210 Years), Moscow: Pokolenie, 2010.

    Google Scholar 

  2. Winter, M., Besenhard, J.O., Spahr, M.E., and Novak, P., Adv. Mater., 1998, vol. 10, no. 10, pp. 725–763.

    Article  CAS  Google Scholar 

  3. Skundin, A.M., Efimov, O.N., and Yarmolenko, O.V., Russ. Chem. Rev., 2002, vol. 71, no. 4, p. 329–346.

    Article  CAS  Google Scholar 

  4. Scrosati, B. and Garche, J., J. Power Sources, 2010, vol. 195, pp. 2419–2430.

    Article  CAS  Google Scholar 

  5. Song, M.-K., Park, S., Alamgir, F.M., et al., Mater. Sci. Eng. R, 2011, vol. 72, pp. 203–252.

    Article  CAS  Google Scholar 

  6. Goodenough, J.B. and Park, K.-S., J. Am. Chem. Soc., 2013, vol. 135, pp. 1167–1176.

    Article  CAS  Google Scholar 

  7. Kulova, T.L., Russ. J. Electrochem., 2013, vol. 49, no. 1, pp. 1–25.

    Article  CAS  Google Scholar 

  8. Yaroslavtsev, A.B., Kulova, T.L., and Skundin, A.M., Russ. Chem. Rev., 2015, vol. 84, no. 8, pp. 826–852.

    Article  CAS  Google Scholar 

  9. Barsukov, V.Z., Il’in, E.A., and Jaskula, M., Elektrokhim. Energet., 2002, vol. 2, no. 4, pp. 153–164.

    Google Scholar 

  10. Thackeray, M.M., Vaughey, J.T., and Fransson, L.M.L., J. Met., 2002, vol. 54, pp. 20–23.

    CAS  Google Scholar 

  11. Benedek, R. and Thackeray, M.M., J. Power Sources, 2002, vol. 110, pp. 406–411.

    Article  CAS  Google Scholar 

  12. Hassoun, J., Panero, S., and Scrosati, B., Fuel Cells, 2009, no. 3, pp. 277–283.

    Article  CAS  Google Scholar 

  13. Zhang, W.-J., J. Power Sources, 2011, vol. 196, pp. 13–24.

    Article  CAS  Google Scholar 

  14. Kamali, A.R. and Fray, D.J., Rev. Adv. Mater., 2011, vol. 27, pp. 14–24.

    CAS  Google Scholar 

  15. Morachevskii, A.G. and Demidov, A.I., Russ. J. Appl. Chem., 2015, vol. 88, no. 4, pp. 547–566.

    Article  CAS  Google Scholar 

  16. Morachevskii, A.G., Russ. J. Appl. Chem., 2015, vol. 88, no. 7, pp. 1087–1105.

    Article  CAS  Google Scholar 

  17. Park, C.-M., Yoon, S., Lee, S., and Kim, J.H., J. Electrochem. Soc., 2007, vol. 154, no. 10, pp. A917–A920.

    Article  CAS  Google Scholar 

  18. Kim, H., Boysen, D.A., Newhouse, J.M., et al., Chem. Rev., 2013, vol. 113, pp. 2075–2099.

    Article  CAS  Google Scholar 

  19. Wang, K., Jiang, K., Chung, B., et al., Nature, 2014, vol. 514, pp. 348–350.

    Article  CAS  Google Scholar 

  20. Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik (Phase Diagrams of Binary Metal Systems: Handbook), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1999, vol. 3, book 1.

  21. Drits, M.E. and Zusman, L.L., Splavy shchelochnykh i shchelochnozemel’nykh metallov: Spravochnik (Alloys of Alkali and Alkaline Earth Metals: Handbook), Moscow: Metallurgiya, 1986.

    Google Scholar 

  22. Sangster, J. and Pelton, A.D., J. Phase Equilib., 1993, vol. 14, no. 4, pp. 514–517.

    Article  CAS  Google Scholar 

  23. Fedorov, P.I., Russ. J. Inorg. Chem., 1995, vol. 40, no. 5, pp. 815–817.

    Google Scholar 

  24. Weppner, W. and Huggins, R.A., J. Electrochem. Soc., 1978, vol. 125, no. 1, pp. 7–14.

    Article  CAS  Google Scholar 

  25. Nikitin, A.V., Demidov, A.I., and Morachevskii, A.G., Zh. Prikl. Khim., 1980, vol. 53, no. 7, pp. 1641–1644.

    CAS  Google Scholar 

  26. Nikitin, A.V., Demidov, A.I., and Morachevskii, A.G., Zh. Prikl. Khim., 1982, vol. 55, no. 4, pp. 915–916.

    CAS  Google Scholar 

  27. Demidov, A.I., Dukhanin, G.P., and Morachevskii, A.G., Elektrokhimiya, 1983, vol. 19, no. 12, pp. 1695–1699.

    CAS  Google Scholar 

  28. Okamoto, H., J. Phase Equilib., 1996, vol. 17, no. 3, p. 271.

    Article  CAS  Google Scholar 

  29. Okamoto, H. and Massalski, T.B., J. Phase Equilib., 1991, vol. 12, no. 2, pp. 148–168.

    Article  CAS  Google Scholar 

  30. Kane, M.M., Newhouse, J.M., and Sadoway, D.R., J. Electrochem. Soc., 2015, vol. 162, no. 3, pp. A421–A425.

    Article  CAS  Google Scholar 

  31. Guminski, C. and Borgstedt, H.U., Arch. Metall. Mater., 2004, vol. 49, no. 3, pp. 529–534.

    CAS  Google Scholar 

  32. Seefurth, R.N. and Sharma, R.A., J. Electrochem. Soc., 1975, vol. 122, no. 8, pp. 1049–1053.

    Article  CAS  Google Scholar 

  33. Morachevskii, A.G., Demidov, A.I., Bulatova, V.F., and Klebanov, E.B., in Issledovaniya v oblasti khimii rasplavov i tverdykh elektrolitov (Studies in the Field of Chemistry of Melts and Solid Electrolytes), Kiev: Naukova Dumka, 1985, pp. 100–105.

    Google Scholar 

  34. Morachevskii, A.G., Voronin, G.F., Geiderikh, V.A., and Kutsenok, I.B., Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (Electrochemical Methods of Investigation in Thermodynamics of Metal Systems), Moscow: Akademkniga, 2003.

    Google Scholar 

  35. Shchukarev, S.A., Volf, E., and Morozova, M.P., J. Gen. Chem. USSR, 1954, vol. 24, no. 11, pp. 1887–1888.

    CAS  Google Scholar 

  36. Morachevskii, A.G., Russ. J. Appl. Chem., 2002, vol. 75, no. 3, pp. 367–369.

    Article  CAS  Google Scholar 

  37. Schlesinger, M.E., Chem. Rev., 2013, vol. 113, pp. 8066–8092.

    Article  CAS  Google Scholar 

  38. Robie, A. and Hemingway, B.C., Thermodynamic Properties of Minerals and Related Substances at 298.15 K and 1 bar (105 pascals) Pressure and at Higher Temperatures: US Geological Survey Bull. 2131. Washington: US Government, 1995.

    Google Scholar 

  39. Demidov, A.I., Klebanov, E.B., Morachevskii, A.G., and Nikitin, A.V., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1982, no. 6, pp. 63–65.

    Google Scholar 

  40. Temnogorova, N.V., Demidov, A.I., and Morachevskii, A.G., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1980, no. 1, pp. 121–122.

    Google Scholar 

  41. Smith, J.F. and Moser, Z., J. Nucl. Mater., 1976, vol. 59, no. 2, pp. 158–174.

    Article  CAS  Google Scholar 

  42. Morachevskii, A.G. and Demidov, A.I., Zh. Fiz. Khim., 1983, vol. 57, no. 9, pp. 2113–2128.

    CAS  Google Scholar 

  43. Morachevskii, A.G., Shesterkin, I.A., Busse-Machukas, V.B., et al., Natrii. Svoistva, proizvodstvo i primenenie (Sodium. Properties, Production, and Use), St. Petersburg: Khimiya, 1992.

    Google Scholar 

  44. Morachevskii, A.G., Beloglazov, I.N., and Kasymbekov, B.A., Kalii. Svoistva, proizvodstvo, primenenie (Potassium. Properties, Production, and Use), Moscow: Ruda i Metally, 2000.

    Google Scholar 

  45. Morachevskii, A.G., Zh. Prikl. Khim., 1994, vol. 67, no. 12, pp. 1937–1950.

    Google Scholar 

  46. Morachevskii, A.G., Russ. J. Appl. Chem., 1997, vol. 70, no. 7, pp. 1001–1015.

    Google Scholar 

  47. Morachevskii, A.G., Zh. Prikl. Khim., 1992, vol. 62, no. 6, pp. 1201–1218.

    Google Scholar 

  48. Morachevskii, A.G. and Demidov, A.I., Itogi Nauki Tekh., Ser.: Rastv., Raspl., 1975, vol. 2, pp. 242–270.

    CAS  Google Scholar 

  49. Wang, J., Raistrick, I.D., and Huggins, R.A., J. Electrochem. Soc., 1986, vol. 133, no. 3, pp. 457–460.

    Article  CAS  Google Scholar 

  50. Kedrinskii, I.A., Dmitrenko, V.E., and Grudyanov, I.I., Litievye istochniki toka (Lithium Current Sources), Moscow: Energoatomizdat, 1992.

    Google Scholar 

  51. Demakhin, A.G., Ovsyannikov, V.M., and Ponomarenko, S.M., Elektrolitnye sistemy litievykh KhIT (Electrolyte Systems for Lithium Chemical Current Sources), Saratov: Saratovsk. Univ., 1993.

    Google Scholar 

  52. Zingel’, E.M., Timofeev, N.V., and Kedrinskii, I.A., Nevodnye elektrolity dlya litievykh istochnikov toka (Nonaqueous Electrolytes for Lithium Current Sources), Krasnoyarsk: Sib. Gos. Tekh. Univ., 2001.

    Google Scholar 

  53. Kedrinskii, I.A. and Yakovlev, V.G., Litii-ionnye akkumulyatory (Lithium–Ion Batteries), Krasnoyarsk: Platina, 2002.

    Google Scholar 

  54. Scrosati, B., J. Electrochem. Soc., 1992, vol. 139, no. 10, pp. 2776–2781.

    Article  CAS  Google Scholar 

  55. Huggins, R.A., Solid State Ionics, 1998, vols. 113–115, pp. 57–67.

    Article  Google Scholar 

  56. Winter, M. and Besenhard, J.O., Electrochim. Acta, 1999, vol. 45, no. 1, pp. 31–50.

    Article  CAS  Google Scholar 

  57. Larcher, D., Beaulieu, L.Y., Mao, O., et al., J. Electrochem. Soc., 2000, vol. 147, no. 5, pp. 1703–1708.

    Article  CAS  Google Scholar 

  58. Skundin, A.M., Elektrokhim. Energet., 2001, vol. 1, no. 1, pp. 5–15.

    Google Scholar 

  59. Thackeray, M.M., Vaughey, J.T., Johnson, C.S., et al., J. Power Sources, 2003, vol. 113, pp. 124–130.

    Article  CAS  Google Scholar 

  60. Dubasova, V.S. and Kanevskii, L.S., Elektrokhim. Energet., 2005, vol. 5, no. 2, pp. 109–119.

    CAS  Google Scholar 

  61. Yang, J., Winter, M., and Besenhard, J.O., Solid State Ionics, 1996, vol. 90, pp. 281–287.

    Article  CAS  Google Scholar 

  62. Besenhard, J.O., Yang, J., and Winter, M., J. Power Sources, 1997, vol. 68, no. 1, pp. 87–90.

    Article  CAS  Google Scholar 

  63. Yang, J., Wachtler, M., Winter, M., and Besenhard, J.O., Electrochem. Solid-State Lett., 1999, vol. 2, no. 4, pp. 161–163.

    Article  CAS  Google Scholar 

  64. Besenhard, J.O., Wachtler, M., Winter, M., et al., J. Power Sources, 1999, vols. 81–83, pp. 268–275.

    Article  Google Scholar 

  65. Wachtler, M., Besenhard, J.O., Winter, M., et al., J. Power Sources, 2001, vol. 94, pp. 189–193.

    Article  CAS  Google Scholar 

  66. Rom, I., Wachtler, M., Papst, I., et al., Solid State Ionics, 2001, vol. 143, nos. 3–4, pp. 329–336.

    Article  CAS  Google Scholar 

  67. Wachtler, M., Winter, M., and Besenhard, J.O., J. Power Sources, 2002, vol. 105, pp. 151–160.

    Article  CAS  Google Scholar 

  68. Yang, J., Takeda, Y., Imanishi, N., and Yamamoto, O., J. Electrochem. Soc., 1999, vol. 146, no. 11, pp. 4009–4013.

    Article  CAS  Google Scholar 

  69. Yang, J., Takeda, Y., Imanishi, N., and Yamamoto, O., J. Electrochem. Soc., 2000, vol. 147, no. 5, pp. 1671–1676.

    Article  CAS  Google Scholar 

  70. Yang, J., Takeda, Y., Imanishi, N., et al., Solid State Ionics, 2000, vol. 133, pp. 189–194.

    Article  CAS  Google Scholar 

  71. Yang, J., Takeda, Y., Imanishi, N., et al., Solid State Ionics, 2000, vol. 135, pp. 175–180.

    Article  CAS  Google Scholar 

  72. Yang, J., Takeda, Y., Capiglia, C., et al., J. Power Sources, 2003, vols. 119–121, pp. 56–59.

    Article  CAS  Google Scholar 

  73. Li, H., Zhu, G., Huang, X., and Chen, L., J. Mater. Chem., 2000, vol. 10, pp. 693–696.

    Article  Google Scholar 

  74. Li, H., Shi, L., Lu, W., et al., J. Electrochem. Soc., 2001, vol. 148, no. 8, pp. A915–A922.

    Article  CAS  Google Scholar 

  75. Li, H., Shi, L., Wang, Q., et al., Solid State Ionics, 2002, vol. 148, pp. 247–258.

    Article  CAS  Google Scholar 

  76. Fernandez-Madrigal, F.J., Lavela, P., Vicente, C.P., and Tirado, J.L., Chem. Mater., 2002, vol. 14, pp. 2962–2968.

    Article  CAS  Google Scholar 

  77. Mukaibo, H., Osaka, T., Reale, P., et al., J. Power Sources, 2004, vol. 132, pp. 225–228.

    Article  CAS  Google Scholar 

  78. Trifonova, A., Wachtler, M., Wagner, M.R., et al., Solid State Ionics, 2004, vol. 168, pp. 51–59.

    Article  CAS  Google Scholar 

  79. Zhao, H., Yin, C., Guo, H., and Qiu, W., Electrochem. Solid-State Lett., 2006, vol. 9, no. 6, pp. A281–A284.

    Article  CAS  Google Scholar 

  80. Zhao, H., Yin, C., Guo, H., et al., J. Power Sources, 2007, vol. 174, pp. 916–920.

    Article  CAS  Google Scholar 

  81. Zhao, H., Zhu, Z., Yin, C., et al., Mater. Chem. Phys., 2008, vol. 110, pp. 201–205.

    Article  CAS  Google Scholar 

  82. Simonin, L., Lafont, U., and Kelder, E.M., J. Power Sources, 2008, vol. 180, pp. 859–863.

    Article  CAS  Google Scholar 

  83. Zhao, H., Jiang, C., He, X., and Ren, J., J. Power Sources, 2008, vol. 184, pp. 532–537.

    Article  CAS  Google Scholar 

  84. Diagrammy sostoyaniya metallicheskikh sistem (Phase Diagrams of Metal Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 2000, vol. 3, book 2.

  85. Allen, W.P. and Perepezko, J.H., Scr. Metall., 1990, vol. 24, no. 11, pp. 2215–2220.

    Article  CAS  Google Scholar 

  86. Vaughey, J.T., O’Hara, J., and Thackeray, M.M., Electrochem. Solid-State Lett., 2000, vol. 3, no. 1, pp. 13–16.

    Article  CAS  Google Scholar 

  87. Johnson, C.S., Vaughey, J.T., Thackeray, M.M., et al., Electrochem. Commun., 2000, vol. 2, pp. 595–600.

    Article  CAS  Google Scholar 

  88. Hewitt, K.C., Beaulieu, L.Y., and Dahn, J.R., J. Electrochem. Soc., 2001, vol. 148, no. 5, pp. A402–A410.

    Article  CAS  Google Scholar 

  89. Vaughey, J.T., Johnson, C.S., Kropf, A.J., et al., J. Power Sources, 2001, vols. 97–98, pp. 194–197.

    Article  Google Scholar 

  90. Tostmann, H., Kropf, A.J., Johnson, C.S., et al., Phys. Rev. B, 2002, vol. 66, pp. 014106-1-014106-12.

  91. Sarakonsri, T., Jonson, C.S., Hackney, S.A., and Thackeray, M.M., J. Power Sources, 2006, vol. 153, pp. 319–327.

    Article  CAS  Google Scholar 

  92. Stjerndahl, M., Bryngelsson, H., Gustafsson, T., et al., Electrochim. Acta, 2007, vol. 52, pp. 4947–4955.

    Article  CAS  Google Scholar 

  93. Fransson, L.M.L., Vayghey, J.T., Benedek, R., et al., Electrochem. Commun., 2001, vol. 3, pp. 317–323.

    Article  CAS  Google Scholar 

  94. Morcrette, M.M., Larcher, D., Tarascon, J.M., et al., Electrochim. Acta, 2007, vol. 52, pp. 5339–5345.

    Article  CAS  Google Scholar 

  95. Matsuno, S., Noji, M., Nakayama, M., et al., J. Electrochem. Soc., 2008, vol. 155, no. 2, pp. A151–A157.

    Article  CAS  Google Scholar 

  96. Nakayama, M., Matsuno, S., Shirakawa, J., and Wakihara, M.J., Electrochem. Soc., 2008, vol. 155, no. 7, pp. A505–A511.

    Article  CAS  Google Scholar 

  97. Zhao, X.B. and Cao, G.S., Electrochim. Acta, 2001, vol. 46, pp. 891–896.

    Article  CAS  Google Scholar 

  98. Honda, H., Sakaguchi, H., Tanaka, I., and Esaka, T., J. Power Sources, 2003, vol. 123, pp. 216–221.

    Article  CAS  Google Scholar 

  99. Vaughey, J.T., Fransson, L., Swinger, H.A., et al., J. Power Sources, 2003, vols. 119–121, pp. 64–68.

    Article  CAS  Google Scholar 

  100. Xie, J., Zhao, X.B., Cao, G.S., et al., Mater. Lett., 2003, vol. 57, pp. 4673–4677.

    Article  CAS  Google Scholar 

  101. Xie, J., Zhao, X.B., Cao, G.S., et al., J. Alloys Compd., 2005, vol. 393, pp. 283–286.

    Article  CAS  Google Scholar 

  102. Villevieille, C., Ionica-Bousquet, C.-M., Ducourant, B., et al., J. Power Sources, 2007, vol. 172, pp. 388–394.

    Article  CAS  Google Scholar 

  103. Alcantara, R., Fernandez-Madrigal, F.J., Lavela, P., et al., J. Mater. Chem., 1999, vol. 9, pp. 2517–2521.

    Article  CAS  Google Scholar 

  104. Fernandez-Madrigal, F.J., Lavela, P., Perez-Vicente, C., and Tirado, J.L., J. Electroanal. Chem., 2001, vol. 501, pp. 205–209.

    Article  CAS  Google Scholar 

  105. Park, C.-M. and Sohn, H.-J., J. Electrochem. Soc., 2010, vol. 157, no. 1, pp. A46–A49.

    Article  CAS  Google Scholar 

  106. Gomes-Camer, J.L., Villeveille, C., and Novak, P., Mater. Chem. A, 2013, vol. 1, no. 41, pp. 13011–13016.

    Article  CAS  Google Scholar 

  107. Yin, J., Wada, M., Tanase, S., and Sakai, T., J. Electrochem. Soc., 2004, vol. 151, no. 6, pp. A867–A872.

    Article  CAS  Google Scholar 

  108. Rönnebro, E., Yin, J., Kitano, A., et al., J. Electrochem. Soc., 2005, vol. 152, no. 1, pp. A152–A157.

    Article  CAS  Google Scholar 

  109. Matsuno, S., Nakayama, M., and Wakihara, M., J. Electrochem. Soc., 2008, vol. 155, no. 1, pp. A61–A65.

    Article  CAS  Google Scholar 

  110. Guo, H., Zhao, H., Jia, X., et al., J. Power Sources, 2007, vol. 174, pp. 921–926.

    Article  CAS  Google Scholar 

  111. Tabuchi, T., Hochgatterer, N., Ogumi, Z., and Winter, M., J. Power Sources, 2009, vol. 188, pp. 552–557.

    Article  CAS  Google Scholar 

  112. Wang, F., Zhao, M., and Song, X., J. Power Sources, 2008, vol. 175, pp. 558–563.

    Article  CAS  Google Scholar 

  113. Zhao, X.B., Cao, G.S., Lv, C.P., et al., J. Alloys Compd., 2001, vol. 315, pp. 265–269.

    Article  CAS  Google Scholar 

  114. Hassoun, J., Derrien, G., Panero, S., and Scrosati, B., J. Power Sources, 2008, vol. 183, pp. 339–343.

    Article  CAS  Google Scholar 

  115. Hassoun, J., Derrien, G., Panero, S., and Scrosati, B., Electrochim. Acta, 2009, vol. 54, pp. 4441–4444.

    Article  CAS  Google Scholar 

  116. Park, C.-M. and Sohn, H.-J., Electrochim. Acta, 2009, vol. 54, pp. 6367–6373.

    Article  CAS  Google Scholar 

  117. Li, H., Huang, X., and Chen, L., Solid State Ionics, 1999, vol. 123, pp. 189–197.

    Article  CAS  Google Scholar 

  118. Yoon, S. and Manthiram, A., Chem. Mater., 2009, vol. 21, pp. 3898–3904.

    Article  CAS  Google Scholar 

  119. Bryngelsson, H., Eskhult, J., Nyholm, L., et al., Chem. Mater., 2007, vol. 19, pp. 1170–1180.

    Article  CAS  Google Scholar 

  120. Bryngelsson, H., Eskhult, J., Edström, K., and Nyholm, L., Electrochim. Acta, 2007, vol. 53, pp. 1062–1073.

    Article  CAS  Google Scholar 

  121. Larcher, D., Prakash, A.S., Laffont, L., et al., J. Electrochem. Soc., 2006, vol. 153, no. 9, pp. A1778–A1787.

    Article  CAS  Google Scholar 

  122. Xue, M.Z. and Fu, Z.W., Electrochem. Commun., 2006, vol. 8, pp. 1250–1256.

    Article  CAS  Google Scholar 

  123. Pridatko, K.I. and Churikov, A.I., Elektrokhim. Energet., 2005, vol. 5, no. 1, pp. 16–29.

    CAS  Google Scholar 

  124. Ehrich, G.M., Durand, C., Chen, X., et al., J. Electrochem. Soc., 2000, vol. 147, no. 3, pp. 886–891.

    Article  Google Scholar 

  125. Simonin, L., Laffont, U., Tabrizi, N., et al., J. Power Sources, 2007, vol. 174, pp. 805–810.

    Article  CAS  Google Scholar 

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Correspondence to A. G. Morachevskii.

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Original Russian Text © A.G. Morachevskii, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 11, pp. 1521−1533.

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Morachevskii, A.G. Lithium–antimony alloys: Phase diagram, thermodynamic properties, electrochemical behavior in molten and nonaqueous electrolytes, and use in lithium–ion batteries. Russ J Appl Chem 88, 1737–1749 (2015). https://doi.org/10.1134/S10704272150110014

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