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Sorption recovery of transition metals with dithiooxamidated polysiloxane

  • Sorption and Ion Exchange Processes
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Abstract

Effect of the acidity of the sorption solution on the recovery of Cu(II), Ni(II), Co(II), Ag(I), and Pd(II) ions was studied for dithiooxamidated polysiloxanes with degrees of modification of 0.10 and 0.21. The constant acidity of the solution was maintained with ammonia, acetate, and ammonia-acetate buffer solutions. The optimal sorption conditions of metal ions from individual solutions were found. The distribution coefficients and pairwise selectivity coefficients were calculated for all the ions studied. It was fund on the basis of the selectivity coefficients that introduction of dithiooxamide groups into the structure of polysiloxane yields an effective sorbent for recovery of Pd(II) and Ag(I).

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Authors and Affiliations

  1. Ural Federal University, ul. Mira 19, Yekaterinburg, 620002, Russia

    A. S. Kholmogorova & L. K. Neudachina

  2. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. Kovalevskoi 22, Yekaterinburg, 620137, Russia

    I. S. Puzyrev & A. V. Pestov

Authors
  1. A. S. Kholmogorova
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  2. L. K. Neudachina
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  3. I. S. Puzyrev
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  4. A. V. Pestov
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Correspondence to A. S. Kholmogorova.

Additional information

Original Russian Text © A.S. Kholmogorova, L.K. Neudachina, I.S. Puzyrev, A.V. Pestov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1449–1456.

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Kholmogorova, A.S., Neudachina, L.K., Puzyrev, I.S. et al. Sorption recovery of transition metals with dithiooxamidated polysiloxane. Russ J Appl Chem 87, 1450–1455 (2014). https://doi.org/10.1134/S1070427214100103

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  • DOI: https://doi.org/10.1134/S1070427214100103

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