Skip to main content
Log in

Synthesis of a Li2FeSiO4/C nanocrystalline cathode material for lithium-ion batteries

  • Applied Electrochemistry and Corrosion Protection of Metals
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

An Erratum to this article was published on 01 November 2014

Abstract

Nanocrystalline cathode material Li2FeSiO4/C was synthesized by the solid-state synthesis method, with amorphous Li2SiO3 produced by fusion of SiO2 and Li2CO3 as the starting component. The resulting powders were studied by X-ray diffraction analysis, scanning electron microscopy, high-resolution transmission electron microscopy, and energy-dispersive X-ray spectrometry. The electrochemical characteristics of the material were obtained by galvanostatic cycling in the range 1.5–4.6 V.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yan, Z., Cai, S., Miao, L., et al., J. Alloys Compounds, 2012, vol. 511, pp. 101–106.

    Article  CAS  Google Scholar 

  2. Kosova, N.V. and Devyatkina, E.T., Russ. J. Electrochem., 2012, vol. 48, no. 3, pp. 320–329.

    Article  CAS  Google Scholar 

  3. Delacourt, C., Laffont, L., Bouchet, R., et al., J. Electrochem. Soc., 2005, vol. 152, pp. 913–921.

    Article  Google Scholar 

  4. Huang, H., Yin, S.C., and Nazar, L.F., Solid-State Lett., 2001, vol. 4, pp. 170–172.

    Article  Google Scholar 

  5. Gong, Z. and Yang, Y., Energy Environ. Sci, 2011, vol. 4, pp. 3223–3242.

    Article  CAS  Google Scholar 

  6. Dominko, R., Conte, D.E., Hanzel, D., et al., J. Power Sources, 2008, vol. 178, pp. 842–847.

    Article  CAS  Google Scholar 

  7. Kudryavtsev, E.N., Sibiryakov, R.V., Agafonov, D.V., and Naraev, V.N., Sovr. Problemy Nauki Obrazovaniya, 2012, no. 5.

    Google Scholar 

  8. Nyten, A. et al., Electrochem. Commun., 2005, vol. 7, pp. 156–160.

    Article  CAS  Google Scholar 

  9. Sun, S. and Wu, Z., J. Chem. & Pharm. Res., 2014, vol. 6, no. 4. pp. 221–225.

    Google Scholar 

  10. Dominko, R., J. Power Sources, 2008, vol. 184, pp. 462–468.

    Article  CAS  Google Scholar 

  11. Huang, X., Chen, H., Zhou, S., et al., Electrochimica Acta, 2012, vol. 60, pp. 239–243.

    Article  CAS  Google Scholar 

  12. Wu, X., Wang X., and Zhang, Y., ACS Appl. Mater. Interfaces, 2013, vol. 5, no. 7, pp. 2510–2516.

    Article  CAS  Google Scholar 

  13. Malik, R., Burch, D., Bazant, M., and Ceder, G., Nano Lett., 2010, vol. 10, no. 10, pp. 4123–4127.

    Article  CAS  Google Scholar 

  14. Fan, X.Y., Li, Y., Wang, J.J., et al., J. Alloys Compounds, 2010, vol. 493, pp. 77–80.

    Article  CAS  Google Scholar 

  15. Kong, X., Mei, T., Xing, Z., et al., Int. J. Electrochem. Sci., 2012, vol. 7, pp. 5565–5573.

    CAS  Google Scholar 

  16. Guo, H.J., Xiang K.X., Cao X., et al.. Trans. Nonferrous Met. Soc. China, 2009, vol. 19, pp. 166–169.

    Article  CAS  Google Scholar 

  17. Huang, B., Zheng, X., Lu, M., J. Alloys Compounds, 2012, vol. 525, pp. 110–113.

    Article  CAS  Google Scholar 

  18. Yang, J., Kang, X., Hu, L., et al., J. Alloys Compounds, 2013, vol. 572, pp. 158–162.

    Article  CAS  Google Scholar 

  19. Deng, C., Zhang, S., Yang, S.Y., et al., J. of Power Sources, 2011, vol. 196, pp. 386–392.

    Article  CAS  Google Scholar 

  20. Hao Hao, Junbo Wang, Jiali Liu, et al., J. Power Sourc es, 2012, vol. 210, pp. 397–401.

    Article  CAS  Google Scholar 

  21. Bai, J., Gong, Zh., Lv, D., et al., J. Mater. Chem., 2012, vol. 22, pp. 12128–12132.

    Article  CAS  Google Scholar 

  22. Gong, Z.L., Li, Y.X., and Yang, Y., Electrochem. Solid-State Lett., 2006, vol. 9, no. 12, pp. 542–544.

    Article  Google Scholar 

  23. Jung, Y.S., Cavanagh, A.S., Dillon, A.C., et al., J. Electrochem. Soc., 2010, vol. 157, no. 1, pp. 75–81.

    Article  Google Scholar 

  24. Knoops, H.C.M., Donders, M.E., van de Sanden, M.C.M., et al., J. Vac. Sci. Technol., 2012, vol. 30, no. 1, pp. 010801.01–010801.10.

    Google Scholar 

  25. Diagrammy sostoyaniya silikatnykh sistem (The Phase Diagram of Silicate Systems), Toropov, N.A. et al., Eds., Leningrad: Nauka, Leningr. Otd., 1969.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. A. Novikov.

Additional information

Original Russian Text © A.A. Popovich, P.A. Novikov, A.O. Silina, N.G. Razumov, Wang Quing Sheng, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 9, pp. 1274–1279.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Popovich, A.A., Novikov, P.A., Silin, A.O. et al. Synthesis of a Li2FeSiO4/C nanocrystalline cathode material for lithium-ion batteries. Russ J Appl Chem 87, 1268–1273 (2014). https://doi.org/10.1134/S1070427214090134

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214090134

Keywords

Navigation