Abstract
The study discusses the results of investigations of a natural gas hydtrate formation of Srednevilyuiskoe field in various model systems based on distilled water by DSC. Based on the calculated data conditions for synthesis of natural gas hydrates in a calorimeter cell were selected and thermobaric conditions of formation and decomposition of hydrates under study were found. It was shown that in the presence of surfactants the process of the natural gas hydrate formation led predominantly to the formation of methane hydrates. An influence of mechanical admixtures and surfactants on supercooling was determined, which in turn affects the crystallization temperatures of systems under study.
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Istomin, V.A. and Derevyagin, A.M., Sovremennoe sostoyanie gazogidratnykh issledovanii v mire i prakticheskie rezul’taty dlya gazovoi promyshdennosti (Current State of Gas Hydrate Research in the World, and the Practical Results for the Gas Promyshdennosti). Moscow: OOO “IRTs Gazprom,” 2004.
Yakushev, V.S., Kvon, V.G., Gerasimov, Yu.A., and Istomin, V.A., Sovremennoe sostoyanie gazogidratnykh tekhnologii: Obzor inform. (Current State of Gas Hydrate Technology: Overview Inf.), Moscow: OOO “IRTs Gazprom,” 2008.
Dalmazzone, D., Hamed, N., and Dalmazzone, C., Chem. Eng. Sci., 2009, vol. 64, no. 9, pp. 2020–2026.
Davies, S.R., Hester, K.C., Lachance, J.W., et al., Chem. Eng. Sci., 2009, vol. 64, pp. 370–375.
Gupta, A., Lachance, J., Sloan, E.D., and Koh, C.A., Chem. Eng. Sci., 2008, vol. 63, pp. 5848–5853.
Lachance, J.W., Sloan, E.D., and Koh, C.A., Chem. Eng. Sci., 2008, vol. 63, pp. 3942–3947.
Lachance, J.W., Sloan, E.D., and Koh, C.A., Chem. Eng. Sci., 2009, vol. 64, pp. 180–184.
Le Parlouer, P., Dalmazzone, C., Herzhaft, B. et al., J. Therm. Anal. Calorim., 2004, vol. 78, pp. 165–172.
Zhang, Y., Debenedetti, P.G., Prud’homme, R.K., and Pethica, B.A., J. Phys. Chem. B, 2004, vol. 108, pp. 16717–16722.
Dalmazzone, D., Hamed, N., Dalmazzone, C., and Rosseau, L., J. Therm. Anal. Calorim., 2006, vol. 85, pp. 361–368.
Zhang, J. and Lee, J.W., Energy Fuels, 2009, vol. 23, pp. 3045–3047.
GOST 23781-87. Gazy goryuchie prirodnye. Khromatograficheskii metod opredeleniya komponentnogo sostava (Natural Gases. Chromatographic Method of Determination of Composition), Moscow: IPK Izd. Standartov, 1997.
Gayet, P., Dicharry, C., Marion, G., et al., Chem. Eng. Sci., 2005, vol. 60, pp. 5751–5758.
Zhong, Y. and Rogers, R.E., Chem. Eng. Sci., 2000, vol. 55, pp. 4175–4187.
Karaaslan, U. and Parlaktuna, M., Energy a. Fuels, 2000, vol. 14, pp. 1103–1107.
Vysniaukas, A. and Bishnoy, P.R., Chem. Eng. Sci., 1983, vol. 38, pp. 1061–1072.
Sloan, E.D., Clathrate hydrates of natural gases, 2nd ed. New York: Marcel Dekker, 1978.
Istomin, V.A. and Yakushev, V.S., Gazovye gidraty v prirodnykh usloviyakh (Gas Hydrates in Natural Conditions), Moscow: Nedra, 1992.
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Original Russian Text © I.K. Ivanova, M.E. Semenov, I.I. Rozhin, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 8, pp. 1111–1116.
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Ivanova, I.K., Semenov, M.E. & Rozhin, I.I. Synthesis and phase transformations of natural gas hydrates of Srednevilyuiskoe field. Russ J Appl Chem 87, 1094–1098 (2014). https://doi.org/10.1134/S107042721408014X
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DOI: https://doi.org/10.1134/S107042721408014X