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Fluorescent and Acid-Base Indicator Properties of Complexes Based on Sn(IV) Octaethylporphyrinate and Molecules of Dye: Phenolphthalein and 1,3,5,7-Tetramethyl-8-(4-hydroxyphenyl) (BODIPY)

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Abstract

Triads L–SNP–L, containing two ligands, phenolphthalein or 1,3,5,7-tetramethyl-8-(4-hydroxyphenyl)-4,4-difluoro-4-boron-3a,4a-diazaindacene (BODIPY), axially bound to Sn(IV)octaethylporphyrinate, were synthesized. The sensitivity of the obtained triads to changes in the acidity of the medium has been studied. Photoexcitation of the BODIPY-SnP-BODIPY triad leads to photoinduced energy transfer from the BODIPY donor fragments to the porphyrinate acceptor. When the triad is excited at the wavelength λexc = 490 nm, in addition to BODIPY fluorescence, fluorescence sensitized by the porphyrin fragment is recorded, and when the triad is excited at a wavelength λexc = 400 nm, porphyrinate fluorescence flares up compared to initial SnP. In the triad with phenolphthalein molecules, the fluorescent properties of both the ligand and porphyrinate are quenched, however, sensitivity to changes in the solution pH increases.

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Funding

The work was supported by a grant of the Russian Science Foundation (project no. 22-23-00018) with the use of equipment from the Upper Volga Regional Center for Physical and Chemical Research.

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Authors and Affiliations

  1. G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045, Ivanovo, Russia

    A. E. Likhonina & N. Zh. Mamardashvili

  2. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    D. A. Bryksina

Authors
  1. A. E. Likhonina
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Correspondence to A. E. Likhonina.

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Likhonina, A.E., Bryksina, D.A. & Mamardashvili, N.Z. Fluorescent and Acid-Base Indicator Properties of Complexes Based on Sn(IV) Octaethylporphyrinate and Molecules of Dye: Phenolphthalein and 1,3,5,7-Tetramethyl-8-(4-hydroxyphenyl) (BODIPY). Russ J Gen Chem 92, 2786–2795 (2022). https://doi.org/10.1134/S1070363222120295

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