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Crystal Structure of the Organonickel Sigma Complex [NiBr(Tcpp)(bpy)]

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Abstract

The low-stable organonickel sigma-complex (2,2'-bipyridyl)bromo(2,4,6-tricyclopentylphenyl)nickel(II) [NiBr(Tcpp)(bpy)] was obtained by a modified procedure of preparative electrochemical synthesis and isolation. The crystal structure of the resulting organonickel complex was determined by the X-ray diffraction method. Its structure was compared with that of its more stable analogue [NiBr(Tchp)(bpy)], where Tchp is 2,4,6-tricyclohexylphenyl. It was found that a more efficient network of intermolecular interactions is formed in the [NiBr(Tchp)(bpy)] crystal, which is responsible for its higher stability, whereas [NiBr(Tcpp)(bpy)] is more likely to enter into an equilibrium Schlenk reaction, leading to its decomposition.

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ACKNOWLEDGMENTS

Mass spectrometric studies and elemental analysis were performed on the equipment of the Spectro-Analytical Center of the Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences.”

Funding

The work was carried out with the financial support of the Russian Science Foundation (project no. 21-73-00136).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”, 420088, Kazan, Russia

    A. A. Kagilev, Z. N. Gafurov, I. F. Sakhapov, A. O. Kantyukov, I. K. Mikhailov & D. G. Yakhvarov

  2. A.M. Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University, 420008, Kazan, Russia

    A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov & D. G. Yakhvarov

  3. Laboratory for Structural Studies of Biomacromolecules, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”, 420111, Kazan, Russia

    D. R. Islamov

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  1. A. A. Kagilev
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  2. Z. N. Gafurov
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Correspondence to D. G. Yakhvarov.

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To the 145th anniversary of A.E. Arbuzov

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Kagilev, A.A., Gafurov, Z.N., Sakhapov, I.F. et al. Crystal Structure of the Organonickel Sigma Complex [NiBr(Tcpp)(bpy)]. Russ J Gen Chem 92, 2659–2665 (2022). https://doi.org/10.1134/S1070363222120155

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