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Synthesis, Structure, and Luminescent Properties of Copper(I) Iodide Clusters Bearing Dialkylcyanamide Ligands

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Abstract

The reaction of CuI with dialkylcyanamides yielded copper(I) cluster complexes [Cu4I4(NCNR2)4] (R2 = Me2, Et2, C4H8, C5H10, C4H8O), as well as coordination polymer catena-[CuI(NCNMe2)]n. The structures of the obtained compounds were determined by single-crystal X-ray diffraction analysis, atomic emission spectroscopy (Cu), CHN elemental analysis, X-ray phase analysis, and IR spectroscopy. The prepared clusters luminesce at room temperature in the solid state with an emission maximum in the range of 554–600 nm upon irradiation at 365 nm.

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ACKNOWLEDGMENTS

Physicochemical measurements were carried out in the Center for X-ray Diffraction Studies, Center for Chemical Analysis and Materials Research, Optical and Laser Materials Research Center, and Thermogravimetric and Calorimetric Research Center, St. Petersburg State University.

Funding

This study was supported by the Russian Science Foundation (project no. 22-13-00078: structural and photophysical studies) and by the Russian Foundation for Basic Research (project no. 20-33-90240: synthetic studies).

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    Y. N. Toikka, Yu. N. Toikka, A. S. Mereshchenko, G. L. Starova & N. A. Bokach

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  1. Y. N. Toikka
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  2. Yu. N. Toikka
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  3. A. S. Mereshchenko
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  4. G. L. Starova
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  5. N. A. Bokach
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Correspondence to N. A. Bokach.

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Toikka, Y.N., Toikka, Y.N., Mereshchenko, A.S. et al. Synthesis, Structure, and Luminescent Properties of Copper(I) Iodide Clusters Bearing Dialkylcyanamide Ligands. Russ J Gen Chem 92, 1467–1474 (2022). https://doi.org/10.1134/S107036322208014X

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