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Mechanically Activated Solid-State Synthesis of Nanocrystalline Yb4Zr3O12

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Abstract

Nanocrystalline ytterbium zirconate Yb4Zr3O12 (δ-phase) was synthesized by the solid-state method with preliminary mechanical activation of a stoichiometric mixture of the corresponding oxides. The processes occurring in the course of the synthesis were studied by X-ray powder diffraction, IR spectroscopy, and thermal analysis. The average size of Yb4Zr3O12 crystallites obtained by annealing a mechanically activated oxide mixture at 900, 1000, 1100, and 1200°C was calculated by the Scherrer formula and was 12, 17, 27, and 41 nm, respectively.

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Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Kola Scientific Center of the Russian Academy of Sciences”, 184209, Apatity, Russia

    A. M. Kalinkin, O. A. Kuz’menkov, E. V. Kalinkina & V. V. Semushin

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  1. A. M. Kalinkin
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  2. O. A. Kuz’menkov
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  3. E. V. Kalinkina
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Correspondence to A. M. Kalinkin.

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A.M. Kalinkin is a member of the Editorial Board of the Zhurnal Obshchei Khimii. The other authors declare the absence of conflict of interest.

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Kalinkin, A.M., Kuz’menkov, O.A., Kalinkina, E.V. et al. Mechanically Activated Solid-State Synthesis of Nanocrystalline Yb4Zr3O12. Russ J Gen Chem 92, 1056–1061 (2022). https://doi.org/10.1134/S1070363222060172

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