Abstract
The author gives an overview of his discoveries along the lines of new laws and new phenomena. Included are the following sections: explanation of atmospheric phenomena, such as the occurrence of atmospheric electricity and the presence of precipitation at low supersaturation of water vapor in the atmosphere; development of classical laws of thermodynamics (Laplace, Young and Kelvin equations, phase rules, Gibbs adsorption equations and laws of Konovalov), consideration of nano-corrections to the Gibbs–Curie principle and the Gibbs phase equilibrium condition for a soluble solid particle. Section of new phenomena open surface properties of water and wetting anisotropy. A significant part of the review is the section “Mechanochemistry: laws and new phenomena.” Here the tensors of chemical potential and chemical affinity are characterized, the mechanochemical effects of dissolution and stress corrosion, mechanochemical effects in redox reactions involving iron and the mechanochemical effect sign of deformation in wetting phenomena are described. The theme of new phenomena is continued by the strong dependence of the contact angle on the pressure in the liquid and the temperature pinning of the contact angle. The final part tells about the discovery of a new thermodynamic potential, called the J-potential. The necessity of introducing such a potential is manifested in the thermodynamics of solid or mixed systems subjected to complex mechanical stresses. Three applications are demonstrated for J-potential: in the derivation of the classical Gibbs and Neumann equations, in the thermodynamics of thin films and in the theory of strength of materials.
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The author cordially thanks A.K. Shchekin for help in writing the article.
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The work was carried out with financial support of Russian Foundation for Basic Research (project no. 20-03-00641).
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Rusanov, A.I. My Discoveries (A Review). Russ J Gen Chem 92, 539–583 (2022). https://doi.org/10.1134/S1070363222040016
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DOI: https://doi.org/10.1134/S1070363222040016