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Electrochemical Synthesis and Characterization of Copper(II) and Zinc(II) Coordination Compounds with Nicotinic and Picolinic Acids

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Abstract

New methods for the electrochemical synthesis of copper(II) and zinc(II) coordination compounds with pyridinecarboxylic acids (nicotinic and picolinic) have been developed. The resulting compounds were characterized by quantitative analysis and IR spectroscopy. The vibrational frequencies of the synthesized compounds were calculated by a DFT quantum-chemical method, and the experimental IR spectra were interpreted on this basis. It was found that pyridinecarboxylate ions in all cases are coordinated both at the nitrogen atom and at the carboxylate group, however, in the case of nicotinic acid, this leads to the formation of coordination polymers, whereas for picolinic acid, the formation of mononuclear complexes is typical.

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Funding

The work was carried out using the equipment of the Ecoanalytical and Analytical Center for System Research, Mathematical Modeling, and Environmental Safety of the South of Russia, of Kuban State University and the Scientific and Educational Center “Diagnostics of the Structure and Properties of Nanomaterials” of the Kuban State University.

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    E. O. Andriychenko, V. I. Zelenov, A. V. Bespalov, V. E. Bovyka & N. N. Bukov

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  1. E. O. Andriychenko
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  2. V. I. Zelenov
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  3. A. V. Bespalov
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  4. V. E. Bovyka
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  5. N. N. Bukov
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Correspondence to E. O. Andriychenko.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 9, pp. 1416–1425 https://doi.org/10.31857/S0044460X21090134.

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Andriychenko, E.O., Zelenov, V.I., Bespalov, A.V. et al. Electrochemical Synthesis and Characterization of Copper(II) and Zinc(II) Coordination Compounds with Nicotinic and Picolinic Acids. Russ J Gen Chem 91, 1697–1705 (2021). https://doi.org/10.1134/S1070363221090139

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