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Reactions of Compounds Containing Benzoquinonе-1,4-diimine Groups with Sulfuric Acid

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Abstract

The reactions of poly(benzoquinone-1,4-diimine-N,N′-diyl-1,4-phenylene) and N,N′-di-(4-aminophenyl)benzoquinone-1,4-diimine with sulfuric acid proceeded as 1,4-addition of sulfuric acid and water to quinonediimine groups. Relative rates of these reactions depend on concentration of sulfuric acid. Electrical conductivities of both synthesized and doped with acids compounds were determined. Maximum value of conductivity 10–7 S/cm for doped polymers was achieved in case of doping level approximately 30%.

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Funding

This study was financially supported by the Enterprise Incubator Foundation (EIF) and PMI Science.

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Authors and Affiliations

  1. Yerevan State University, 375025 Republic of, Yerevan, Armenia

    N. A. Durgaryan, A. A. Durgaryan, R. H. Arakelyan & N. A. Miraqyan

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  1. N. A. Durgaryan
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  2. A. A. Durgaryan
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  3. R. H. Arakelyan
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  4. N. A. Miraqyan
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Correspondence to N. A. Durgaryan.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 9, pp. 1397–1403 https://doi.org/10.31857/S0044460X21090110.

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Durgaryan, N.A., Durgaryan, A.A., Arakelyan, R.H. et al. Reactions of Compounds Containing Benzoquinonе-1,4-diimine Groups with Sulfuric Acid. Russ J Gen Chem 91, 1680–1686 (2021). https://doi.org/10.1134/S1070363221090115

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