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Synthesis of Bromochloropolyfluorobiphenyls Containing Bromine and Chlorine Atoms in the 4 and 4,4′ Positions

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Abstract

A new method for the synthesis of 4-chlorononafluoro- and 4-bromononafluorobiphenyl by the reactions of nonafluorobiphenyl-4-thiol with Cl2, PCl5, and Br2, as well as of 4,4′-dichlorooctafluorobiphenyl from octafluorobiphenyl-4,4′-dithiol, 4′-chlorooctafluorobiphenyl-4-thiol, Cl2, and PCl5 was developed. 4-Bromo-4′-chlorooctafluorobiphenyl was synthesized for the first time from 4′-chlorooctafluorobiphenyl-4-thiol and Br2. 4,4′-Dichlorooctafluorobiphenyl was obtained as the main product in the reaction of 4′-bromooctafluorobiphenyl-4-thiol with PCl5.

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ACKNOWLEDGMENTS

The authors are grateful to the Chemical Research Center for Collective Use, Siberian Branch, Russian Academy of Sciences, for spectral and analytical measurements.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    P. V. Nikul’shin, A. M. Maksimov & V. E. Platonov

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  1. P. V. Nikul’shin
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  2. A. M. Maksimov
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  3. V. E. Platonov
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Correspondence to V. E. Platonov.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 7, pp. 1049–1058 https://doi.org/10.31857/S0044460X2107009X.

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Nikul’shin, P.V., Maksimov, A.M. & Platonov, V.E. Synthesis of Bromochloropolyfluorobiphenyls Containing Bromine and Chlorine Atoms in the 4 and 4,4′ Positions. Russ J Gen Chem 91, 1316–1324 (2021). https://doi.org/10.1134/S1070363221070097

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