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Synthesis and Some Chemical Transformations of Allylacetylenic 1,3-Dioxane Derivatives

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Abstract

A procedure has been proposed for the synthesis of allylacetylenic 1,3-dioxane derivatives by condensation of allylacetylenic glycols with formaldehyde in the presence of 40% sulfuric acid. The obtained compounds have been subjected to hydrosilylation, [2+1]- and [4+2]-cycloadditions, dehydrohalogenation, aminomethylation, and condensation to produce new 1,3-dioxane derivatives.

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Authors and Affiliations

  1. Institute of Polymer Materials, National Academy of Sciences of Azerbaijan, 5004, Sumgait, Azerbaijan

    M. I. Shatirova & L. I. Gadzhiyeva

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  1. M. I. Shatirova
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  2. L. I. Gadzhiyeva
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Correspondence to M. I. Shatirova.

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Shatirova, M.I., Gadzhiyeva, L.I. Synthesis and Some Chemical Transformations of Allylacetylenic 1,3-Dioxane Derivatives. Russ J Gen Chem 90, 936–942 (2020). https://doi.org/10.1134/S107036322006002X

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  • DOI: https://doi.org/10.1134/S107036322006002X

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