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Some Transformations of Mono-and Dichloro(diethoxyphosphoryl)acetaldehydes

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Abstract

Addition of ethanol and diethyl phosphonate to the carbonyl group of 2,2-dichloro-2-(diethoxyphosphoryl)-acetaldehyde has been studied, and the corresponding α-chloro ether, acetal, and phosphorylated metrifonate have been obtained. α,α-Dichloro-α-phosphoryl carbonyl compounds have been found to undergo haloform cleavage by the action of bases. Perkow reaction of mono- and dichloro(diethoxyphosphoryl)acetaldehydes with triethyl phosphite afforded diethyl 2-(diethoxyphosphoryl)ethenyl phosphates.

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Authors and Affiliations

  1. Baku State University, Baku, AZ 1148, Azerbaijan

    V. M. Ismailov, N. D. Sadykhova, I. A. Mamedov & N. N. Yusubov

  2. Gyandzha State University, Gyandzha, AZ 2001, Azerbaijan

    G. E. Allakhverdieva

Authors
  1. V. M. Ismailov
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  2. G. E. Allakhverdieva
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  3. N. D. Sadykhova
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  4. I. A. Mamedov
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  5. N. N. Yusubov
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Correspondence to N. N. Yusubov.

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No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2020, published in Zhurnal Obshchei Khimii, 2020, Vol. 90, No. 1, pp. 117–121.

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Ismailov, V.M., Allakhverdieva, G.E., Sadykhova, N.D. et al. Some Transformations of Mono-and Dichloro(diethoxyphosphoryl)acetaldehydes. Russ J Gen Chem 90, 89–92 (2020). https://doi.org/10.1134/S1070363220010132

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  • DOI: https://doi.org/10.1134/S1070363220010132

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