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Synthesis of Glass-Ceramics in Mixed Fluorozirconate–Phosphate Systems

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Abstract

Fluorozirconate-phosphate glasses of the ZrF4–BaF2–NaPO3(LiPO3) and ZrF4–BaF2–LaF3–AlF3–LiPO3 systems doped with EuF3, ErF3, and NdF3 were studied by the differential-thermal (DTA) and X-ray diffraction (XRD) analysis, luminescence spectroscopy, scanning and transmission electron microscopy (SEM and TEM) methods. Addition of the phosphate component up to 20 mol % decreases the glass transition temperature and increases the glass stability to crystallization. Heat treatment in the range >Tg–Tc1 of glass transition and first maxima of crystallization temperatures causes crystallization of nanosized β-BaZrF6 particles. At LiPO3 (NaPO3) concentrations of more than 80 mol %, glasses containing a crystalline phase are formed during the synthesis process.

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References

  1. Fedorov, P.P., Luginina, A.A., and Popov, A.I., J. Fluor. Chem., 2015, vol. 172, p. 22. https://doi.org/10.1016/j.jfluchem.2015.01.009

    Article  CAS  Google Scholar 

  2. Neo, J. and Liu, C., Photon. Electron. Prop. Fluor. Mater., 2016, p. 139. https://doi.org/10.1016/B978-0-12-801639-8.00007-6

    Google Scholar 

  3. Pisarski, W.A., Pisarska, J., Dorosz, D., and Dorosz, J., Mater. Chem. Phys., 2014, vol. 148, p. 485. https://doi.org/10.1016/j.matchemphys.2014.08.020

    Article  CAS  Google Scholar 

  4. Marqueesi, A.R., Delben, J.R.J., and Delben, A.A.S.T., J. Therm. Anal. Calorim., 2009, vol. 96, p. 403. https://doi.org/10.1007/s10973-008-9218-5

    Article  Google Scholar 

  5. Santos, F.A., Delben, J.R.J., Delben, A.A.S.T., Andrade, L.H.C., and Lima, S.M., J. Non-Cryst. Solids, 2011, vol. 357, p. 2907. https://doi.org/10.1016/j.jnoncrysol.2011.03.032

    Article  CAS  Google Scholar 

  6. Goncharuk, V.K., Maslennikova, I.G., Kharchenko, V.I., Kavun, V.Ya., Slobodyuk, A.B., and Sarin, S.A., J. Non. Cryst. Solids, 2016, vol. 431, p. 118. https://doi.org/10.1016/j.jnoncrysol.2015.05.011

    Article  CAS  Google Scholar 

  7. Goncharuk, V.K., Kavun, V.Ya., Slobodyuk, A.B., Silant’ev, V.E., Mamaev, A.Yu., Mirochnik, A.G, and Maslennikova, I.G., J. Non-Cryst. Solids, 2018, vol. 480, p. 61. https://doi.org/10.1016/j.jnoncrysol.2017.10.01

    Article  CAS  Google Scholar 

  8. Baricco, M., Battezzati, L., Braglia, M., Cocito, G., Kraus, J., and Modone, E., J. Non-Cryst. Solids, 1993, vol. 161, p. 60. https://doi.org/10.1016/0022-3093(93)90670-S

    Article  CAS  Google Scholar 

  9. Fedorov, V.D., Sakharov, V.V., Provorova, A.M., Baskov, P.V., Churbanov, M.F., Shiryaev, V.S., Poulain, Ma., Poulain, Mi., and Boutarfaia, A., J. Non-Cryst. Solids, 2001, vol. 284, p. 79. https://doi.org/10.1016/S0022-3093(01)00383-0

    Article  CAS  Google Scholar 

  10. Binnemans, K., Chem. Rev., 2009, vol. 109, p. 4283. https://doi.org/10.1021/cr8003983

    Article  CAS  Google Scholar 

  11. Binnemans, K., Coord. Chem., 2015, vol. 295, p. 1. https://doi.org/10.1016/j.ccr.2015.02.015

    Article  CAS  Google Scholar 

  12. Merkulov, E.B., Goncharuk, V.K., and Stepanov, S.A., J. Non-Cryst. Solids, 1994, vol. 170, p. 65. https://doi.org/10.1016/0022-3093(94)90104-X

    Article  CAS  Google Scholar 

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Funding

The work was carried out within the framework of the state task of the Institute of Chemistry, Far Eastern branch of the Russian Academy of Sciences (project no. 265-2018-0001).

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, 690022, Russia

    I. G. Maslennikova, V. K. Goncharuk, V. Ya. Kavun, V. E. Silant’ev & A. G. Mirochnik

  2. Makarov Pacific Higher Naval School, Vladivostok, 690062, Russia

    V. K. Goncharuk

Authors
  1. I. G. Maslennikova
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  2. V. K. Goncharuk
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  3. V. Ya. Kavun
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  4. V. E. Silant’ev
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  5. A. G. Mirochnik
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Corresponding author

Correspondence to I. G. Maslennikova.

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No conflict of interest was declared by the authors.

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Additional Information

The work was presented as an oral report at the “Solid Chemistry and Functional Materials” All-Russia Conference with International Participation (St. Petersburg, May 21–27, 2018).

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Maslennikova, I.G., Goncharuk, V.K., Kavun, V.Y. et al. Synthesis of Glass-Ceramics in Mixed Fluorozirconate–Phosphate Systems. Russ J Gen Chem 89, 2480–2486 (2019). https://doi.org/10.1134/S1070363219120247

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  • DOI: https://doi.org/10.1134/S1070363219120247

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