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One-Step Synthesis of Phosphorylated Vinylacethylene Derivatives

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Abstract

A one-step method for the preparation of 3-substituted 2-(diethylphosphoryl)but-1-en-3-ynes was developed based on the reaction of phosphorylated α-allene alcohols with methanesulfonic anhydride in the presence of triethylamine. The obtained vinylacetylene derivatives are of interest as promising precursors for the creation of organophosphorus heterocyclic compounds.

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Funding

This work was supported by the Russian Foundation for Basic Research (grant no. 18-03-00073). The NMR spectral study was performed with the support of the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Center for the Study of the Molecular Structure of the Institute of Organoelement Compounds of the Russian Academy of Sciences.

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Authors and Affiliations

  1. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow, 119991, Russia

    V. K. Brel

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  1. V. K. Brel
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Correspondence to V. K. Brel.

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No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 11, pp. 1692–1699.

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Brel, V.K. One-Step Synthesis of Phosphorylated Vinylacethylene Derivatives. Russ J Gen Chem 89, 2212–2218 (2019). https://doi.org/10.1134/S1070363219110082

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