Skip to main content
SpringerLink
Log in

Hexanuclear Silver(I) Hexamethylene Dithiocarbamate Cluster [Ag6{S2CN(CH2)6}6]·2CH2Cl2: Preparation, Molecular Structure (Manifestation of Argentophilic Interaction), and Thermal Behavior

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A new silver(I) cyclohexamethylene dithiocarbamate has been isolated in the form of a hexanuclear solvated cluster [Ag6{S2CN(CH2)6}6]·2CH2Cl2. Structure of the obtained compound has been elucidated by IR spectroscopy, X-ray diffraction analysis, and simultaneous thermal analysis methods. Each of the dithiocarbamate ligands performs a μ3-bridging function, asymmetrically linking three silver atoms. The molecules of the complex are additionally stabilized by argentophilic Ag-Ag bonds (3.0204 Å) formed by each of the silver atoms with two nearest neighbors. The multistage thermal decomposition process of the resulting complex includes desolvation and thermolysis of a six-nuclear cluster with the formation of Ag2S and elemental silver as intermediate and final products, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tong, M.C., Chen, W., Sun, J., Ghosh, D., and Chen, S., J. Phys. Chem. (B), 2006, vol. 110, no. 39, p. 19238. doi https://doi.org/10.1021/jp0631174

    Article  CAS  Google Scholar 

  2. Reynoso-García, P.J., Güizado-Rodríguez, M., Barba, V., Ramos-Ortiz, G., and Martínez-Gutiérrez, H., Adv. Condens. Matter Phys., 2018, vol. 2018, p. 1. doi https://doi.org/10.1155/2018/4376051

    Article  CAS  Google Scholar 

  3. Sabaqian, S., Nemati, F., Nahzomi, H.T., and Heravi, M.M., Carbohydr. Polym., 2018, vol. 184, p. 221. doi https://doi.org/10.1016/j.carbpol.2017.12.045

    Article  CAS  PubMed  Google Scholar 

  4. Hussain, S.T., Bakar, S.A., Saima, B.B., and Muhammad, B., Appl. Surf. Sci., 2012, vol. 258, p. 9610. doi https://doi.org/10.1016/j.apsusc.2012.05.157

    Article  CAS  Google Scholar 

  5. Ehsan, M.A., Khaledi, H., Tahir, A.A., Ming, H.N., Wijayantha, K.G.U., and Mazhar, M., Thin Solid Films, 2013, vol. 536, p. 124. doi https://doi.org/10.1016/j.tsf.2013.03.092

    Article  CAS  Google Scholar 

  6. Mothes, R., Petzold, H., Jakob, A., Rüffer, T., and Lang, H., Inorg. Chim. Acta, 2015, vol. 429, p. 227. doi https://doi.org/10.1016/j.ica.2015.02.008

    Article  CAS  Google Scholar 

  7. Mothes, R., Jakob, A., Waechtler, T., Schulz, S.E., Gessner, T., and Lang, H., Eur. J. Inorg. Chem., 2015, vol. 2015, no. 10, p. 1726. doi https://doi.org/10.1002/ejic.201403182

    Article  CAS  Google Scholar 

  8. Zhang, Y., Hong, G., Zhang, Y., Chen, G., Li, F., Dai, H., and Wang, Q., ACS Nano, 2012, vol. 6, no. 5, p. 3695. doi https://doi.org/10.1021/nn301218z

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. Zhang, Y., Zhang, Y., Hong, G., He, W., Zhou, K., Yang, K., Li, F., Chen, G., Liu, Z., Dai, H., and Wang, Q., Biomaterials, 2013, vol. 34, no. 14, p. 3639. doi https://doi.org/10.1016/j.biomaterials.2013.01.089

    Article  CAS  PubMed  Google Scholar 

  10. Li, C., Zhang, Y., Wang, M., Zhang, Y., Chen, G., Li, L., Wu, D., and Wang, Q., Biomaterials, 2014, vol. 35, no. 1, p. 393. doi https://doi.org/10.1016/j.biomaterials.2013.10.010

    Article  CAS  PubMed  Google Scholar 

  11. Korneeva, E.V., Loseva, O.V., Smolentsev, A.I., and Ivanov, A.V., Russ. J. Gen. Chem., 2018, vol. 88, no. 8, p. 1681. doi https://doi.org/10.1134/S1070363218080200

    Article  CAS  Google Scholar 

  12. Korneeva, E.V., Smolentsev, A.I., Antzutkin, O.N., and Ivanov, A.V., Russ. Chem. Bull., 2019, vol. 68, no. 1, p. 40. doi https://doi.org/10.1007/s11172-019-2413-7

    Article  CAS  Google Scholar 

  13. Anacker-Eickhoff, H., Hesse, R., Jennische, P., and Wahlberg, A., Acta Chem. Scand. (A), 1982, vol. 36, no. 3, p. 251. doi https://doi.org/10.3891/acta.chem.scand.36a-0251

    Article  Google Scholar 

  14. Song, Y.-W., Yu, Z., and Zhang, Q.-F., Acta Crystallogr. (C), 2006, vol. 62, no. 5, p. m214. doi https://doi.org/10.1107/S0108270106006688

    Google Scholar 

  15. Yin, X., Xie, M.-B., Zhang, W.-G., and Fan, J., Acta Crystallogr. (E), 2007, vol. 63, no. 9, p. m2273. doi https://doi.org/10.1107/S1600536807035180

    CAS  Google Scholar 

  16. Hesse, R., Acta Crystallogr., 1960, vol. 13, no. 12, p. 1025. doi https://doi.org/10.1107/S0365110X60002430

    Google Scholar 

  17. Yamaguchi, H., Kido, A., Uechi, T., and Yasukouchi, K., Bull. Chem. Soc. Jpn., 1976, vol. 49, no. 5, p. 1271. doi https://doi.org/10.1246/bcsj.49.1271

    Article  CAS  Google Scholar 

  18. Hesse, R. and Nilson, L., Acta Chem. Scand., 1969, vol. 23, no. 3, p. 825. doi https://doi.org/10.3891/acta.chem.scand.23-0825

    Article  CAS  Google Scholar 

  19. Yin, X., Xie, M.-B., Zhang, W.-G., Fan, J., and Zeller, M., Acta Crystallogr. (E), 2007, vol. 63, no. 8, p. m2063. doi https://doi.org/10.1107/S1600536807031431

    CAS  Google Scholar 

  20. Zhang, W.-G., Zhong, Y., Tan, M.Y., Liu, W.-S., and Su, C.-Y., Chin. J. Chem., 2002, vol. 20, no. 5, p. 420. doi https://doi.org/10.1002/cjoc.20020200503

    Article  CAS  Google Scholar 

  21. Jennische, P. and Hesse, R., Acta Chem. Scand., 1971, vol. 25, no. 2, p. 423. doi https://doi.org/10.3891/acta.chem.scand.25-0423

    Article  CAS  Google Scholar 

  22. Liu, C.W., Liao, P.-K., Fang, C.-S., Saillard, J.-Y., Kahlal, S., and Wang, J.-C., Chem. Commun., 2011, vol. 47, no. 20, p. 5831. doi https://doi.org/10.1039/c1cc10168d

    Article  CAS  Google Scholar 

  23. Wang, Y., Shi, Y.-F., Zou, X.-C., Li, X.-B., Peng, Y., and He, Y.-C., Polyhedron, 2019, vol. 157, p. 321. doi https://doi.org/10.1016/j.poly.2018.10.006

    Article  CAS  Google Scholar 

  24. Huang, Z., Lei, X., Hong, M., and Liu, H., Inorg. Chem., 1992, vol. 31, no. 13, p. 2990. doi https://doi.org/10.1021/ic00039a060

    Article  CAS  Google Scholar 

  25. Zhang, Q.F., Cao, R., Hong, M.C., Su, W.P., and Liu, H.Q., Inorg. Chim. Acta, 1998, vol. 277, no. 2, p. 171. doi https://doi.org/10.1016/S0020-1693(97)06148-3

    Article  CAS  Google Scholar 

  26. Byr’ko, V.M., Ditiokarbamaty (Dithiocarbamates), Moscow: Nauka, 1984.

    Google Scholar 

  27. Kazitsyna, L.A. and Kupletskaya, N.B., Primenenie UF-, IK-, YaMR- i mass-spektroskopii v organicheskoi khimii (The Use of UV, IR, NMR, and Mass Spectroscopy in Organic Chemistry), Moscow: Mosk. Gos. Univ., 1979.

    Google Scholar 

  28. Gremlih, G.U., Yazyk spektrov. Vvedenie v interpretatsiyu spektrov organicheskikh soedinenii (The Language of the Spectra. Introduction to the Interpretation of the Spectra of Organic Compounds), Moscow: OOO «Bruker Optik», 2002.

    Google Scholar 

  29. Pentin, Yu.A. and Vilkov, L.V., Fizicheskie metody issledovaniya v khimii (Physical Research Methods in Chemistry), Moscow: Mir, OOO “Izdatel’stvo AST,” 2006.

    Google Scholar 

  30. Bondi, A., J. Phys. Chem., 1964, vol. 68, no. 3, p. 441. doi https://doi.org/10.1021/j100785a001

    Article  CAS  Google Scholar 

  31. Bondi, A., J. Phys. Chem., 1966, vol. 70, no. 9, p. 3006. doi https://doi.org/10.1021/j100881a503

    Article  CAS  Google Scholar 

  32. Alcock, N.W., Adv. Inorg. Chem. Radiochem., 1972, vol. 15, no. 1, p. 1. doi https://doi.org/10.1016/S0065-2792(08)60016-3

    CAS  Google Scholar 

  33. Winter, M., WebElements Periodic Table of the Elements. http://www.webelements.com (accessed January 2010).

  34. Greenwood, N.N. and Earnshaw, A., Chemistry of the Elements, Oxford: Pergamon Press, 1989.

    Google Scholar 

  35. Ivanov, A.V., Zinkin, S.A., Gerasimenko, A.V., Antzutkin, O.N., and Forsling, W., Russ. J. Coord. Chem., 2007, vol. 33, no. 1, p. 20. doi https://doi.org/10.1134/S1070328407010046

    Article  CAS  Google Scholar 

  36. Bocian, D.F., Pickett, H.M., Rounds, T.C., and Strauss, H.L., J. Am. Chem. Soc., 1975, vol. 97, no. 4, p. 687. doi https://doi.org/10.1021/ja00837a001

    Article  CAS  Google Scholar 

  37. Boessenkool, I.K. and Boeyens, J.C.A., J. Cryst. Mol. Struct., 1980, vol. 10, nos. 1–2, p. 11. doi https://doi.org/10.1007/BF01209549

    Article  CAS  Google Scholar 

  38. Martínez-Castanön, G.A., Sánchez-Loredo, M.G., Dorantes, H.J., Martínez-Mendoza, J.R., Ortega-Zarzosa, G., and Ruiz, F., Mater. Lett., 2005, vol. 59, no. 4, p. 529. doi https://doi.org/10.1016/j.matlet.2004.10.043

    Article  CAS  Google Scholar 

  39. Kracek, F.C., Trans. Am. Geophys. Union, 1946, vol. 27, no. 3, p. 364. doi https://doi.org/10.1029/TR027i003p00364

    Article  CAS  Google Scholar 

  40. Bruker, APEX2. Bruker AXS Inc., Madison, Wisconsin, USA, 2010.

  41. Bruker, SAINT. Bruker AXS Inc., Madison, Wisconsin, USA, 2010.

  42. Sheldrick, G.M., Acta Crystallogr. (A), 2008, vol. 64, no. 1, p. 112. doi https://doi.org/10.1107/S0108767307043930

    Article  CAS  Google Scholar 

  43. Loseva, O.V., Rodina, T.A., Ivanov, A.V., Lutsenko, I.A., Korneeva, E.V., Gerasimenko, A.V., and Smolentsev, A.I., Russ. J. Coord. Chem. 2018, vol. 44, no. 10, p. 604. doi https://doi.org/10.1134/S107032841810007X

    Article  CAS  Google Scholar 

  44. Ivanov, A.V., Ivakhnenko, E.V., and Gerasimenko, A.V., Forsling, W., Russ. J. Inorg. Chem., 2003, vol. 48, no. 1, p. 45.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences, per. Relochnyi 1, Blagoveschensk, 675000, Russia

    E. V. Korneeva, A. V. Ivanov, O. V. Loseva, E. V. Novikova & M. A. Ivanov

  2. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, Russia

    A. V. Gerasimenko

Authors
  1. E. V. Korneeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Gerasimenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Loseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. A. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Ivanov.

Additional information

Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 8, pp. 1260–1268.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Korneeva, E.V., Ivanov, A.V., Gerasimenko, A.V. et al. Hexanuclear Silver(I) Hexamethylene Dithiocarbamate Cluster [Ag6{S2CN(CH2)6}6]·2CH2Cl2: Preparation, Molecular Structure (Manifestation of Argentophilic Interaction), and Thermal Behavior. Russ J Gen Chem 89, 1642–1648 (2019). https://doi.org/10.1134/S1070363219080152

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363219080152

Keywords

Search

Navigation