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Dispersion Oxidative Polymerization of Pyrrole in Aqueous Solutions of Polyvinyl Alcohol

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Abstract

Kinetics of the oxidative polymerization of pyrrole in an aqueous solution of poly(vinyl alcohol) under the action of ammonium peroxydisulfate has been studied. The obtained kinetic data has been quantitatively described with regard to the formation of a new phase, the values of activation energy for the non-catalytic and catalytic stages of the oxidative pyrrole polymerization have been determined. Various mechanisms of oxidative polymerization of pyrrole have been critically evaluated, and the calculated kinetic parameters have been compared with their values available in the literature for oxidative pyrrole polymerization in the absence of stabilizers.

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Funding

This study was financially supported by D.I. Mendeleev University of Chemical Technology (project no. 006-2018).

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Authors and Affiliations

  1. D.I. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    Ya. O. Mezhuev, I. V. Plyushchii, Yu. V. Korshak & M. I. Shtil’man

  2. M.V. Lomonosov Institute of Fine Chemical Technologies, Russian University of Technology, Moscow, Russia

    I. A. Gritskova

Authors
  1. Ya. O. Mezhuev
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  2. I. V. Plyushchii
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  3. Yu. V. Korshak
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  4. M. I. Shtil’man
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  5. I. A. Gritskova
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Correspondence to Ya. O. Mezhuev.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 7, pp. 1130–1139.

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Mezhuev, Y.O., Plyushchii, I.V., Korshak, Y.V. et al. Dispersion Oxidative Polymerization of Pyrrole in Aqueous Solutions of Polyvinyl Alcohol. Russ J Gen Chem 89, 1477–1484 (2019). https://doi.org/10.1134/S107036321907017X

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  • DOI: https://doi.org/10.1134/S107036321907017X

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