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Mixed Ligand Complexes Derived from Semicarbazone Schiff Base and Heterocyclic Ligands: Structure and Antimicrobial Activity

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Abstract

A series of M(II) ternary complexes [M(L)Phen] and [M(L)Oxine], where M = Co(II), Ni(II), Cu(II), and Zn(II), L = ((2-hydroxynaphthalen-1-yl)methylene)-4-nitrobenzohydrazide, Phen = 1,10-phenanthroline and Oxine = 8-hydroxy chloroquinoline, were synthesized and characterized by UV-Vis, ESR, IR, mass spectra, and TG-DTA data. Morphology and crystallinity of the complex [Ni(L)Phen] were studied by scanning electron microscopy. The crystal systems of Cu(II) complexes were determined by powder X-ray diffraction. Biological activity of the ligand and its metal complexes has been screened against four bacterial strains.

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References

  1. Sujarani, S. and Ramu, A., J. Mol. Struct., 2014, vol. 1059, p. 299. doi 10.1016/j.molstruc.2013.11.038

    Article  CAS  Google Scholar 

  2. Abou-Melha, K.S. and Faruk, H., J. Coord. Chem., 2008, vol. 61, no. 12, p. 1862. doi 10.1080/00958970701768455

    Article  CAS  Google Scholar 

  3. Walcourt, A., Loyevsky, M., Lovejoy, D.B., Gordeuk, V.R., and Richardson, D.R., Int. J. Biochem. Cell Biol., 2004, vol. 36, no. 3, p. 401. doi 10.1016/S1357-2725(03) 00248-6

    Article  CAS  PubMed  Google Scholar 

  4. Richardson, D.R. and Bernhardt, P.V., J. Biol. Inorg. Chem., 1999, vol. 4, no. 3, p. 266. doi 10.1007/s007750050312

    Article  CAS  PubMed  Google Scholar 

  5. Yadawe, M.S. and Patil, S.A., Transition Met. Chem., 1997, vol. 22, no. 3, p. 220. doi 10.1023/A:1018400121316

    Article  CAS  Google Scholar 

  6. Zoroddu, M.A., Zanetti, S., Pogni, R., and Basosi, R., J. Inorg. Biochem., 1996, vol. 63, no. 4, p. 291. doi 10.1016/0162-0134(96)00015-3

    Article  CAS  PubMed  Google Scholar 

  7. Chikira, M., Tomizawa, Y., Fukita, D., Sugizaki, T., Sugawara, N., Yamazaki, T., Sasano, A., Shindo, H., Palaniandavar, M., and Antholine, W.E., J. Inorg. Biochem., 2002, vol. 89, no. 3–4, p. 163. doi 10.1016/S0162-0134(02)00378-1

    Article  CAS  PubMed  Google Scholar 

  8. Tardito, S. and Marchio, L., Curr. Med. Chem., 2009, vol. 16, no. 11, p. 1325. doi 10.2174/092986709787846532

    Article  CAS  PubMed  Google Scholar 

  9. Pushie, M.J., Nienaber, K.H., Summers, K.L., Cotelesage, J.J.H, Ponomarenko, O., Nichol, H.K., Pickering, I.J., and George, G.N., J. Inorg. Biochem., 2014, vol. 133, p. 50. doi 10.1016/j.jinorgbio.2014.01.003

    Article  CAS  PubMed  Google Scholar 

  10. Edward, J. T., Gauthier, M., Chub, F.L., and Ponka, P., J. Chem.Eng. Data, 1988, vol. 33, no. 4, p. 538. doi 10.1021/je00054a044

    Article  CAS  Google Scholar 

  11. Essays in Chemistry, Hathway, B.J., Bardley, G.N., and Gillard, R.D., Eds., New York: Academic Press, 1971.

    Google Scholar 

  12. Tharmaraj, P., Kodimunthiri, D., Sheela, C.D., and Priya C.S.S., J. Serb. Chem Soc., 2009, vol. 74, no. 8–9, p. 927. doi 10.2298/JSC0909927T

    Article  CAS  Google Scholar 

  13. Bindu, P. and Kurup, M.R.P., Transition Met. Chem., 1997, vol. 22, no. 6, p. 578. doi 10.1023/A:1018512708055

    Article  CAS  Google Scholar 

  14. Stamate, D., Ferbinteanu, M., Opreal, C.I., Panait, P., Cimpoesu, F., and Girtu, M.A., Abstracts of Papers, 1 Int. Electronic Conf. on Material, 2014.

    Google Scholar 

  15. Malghe, Y.S., Prabhu, R.C., and Raut, R.W., Acta Pol. Pharm., 2009, vol. 66, no. 1, p. 45.

    CAS  PubMed  Google Scholar 

  16. Procter, I.M., Hathaway, B.J., Billing, D.E., and Nicholls, P., J. Chem. Soc. A, 1968, p. 1678. doi 10.1039/J19680001678

    Google Scholar 

  17. Seena, E.B. and Kurup, M.R.P., Polyhedron, 2007, vol. 26, no. 4, p. 829. doi 10.1016/j.poly.2006.09.040

    Article  CAS  Google Scholar 

  18. Joseph, M. Suni, V., Kurup, M.R.P., Nethaji, M., Kishore, A., and Bhat, S.G., Polyhedron, 2004, vol. 23, no. 18, p. 3069. doi 10.1016/j.poly.2004.09.026.

    Article  CAS  Google Scholar 

  19. Maki, A.H. and McGarvey, B.R., J. Chem. Phys., 1958, vol. 35, no. 29, p. 2935. doi 10.1063/1.1744457

    Google Scholar 

  20. Chandra, S. and Gupta, L.K., Spectrochim. Acta, Part A, 2004, vol. 60, no. 13, p. 3079. doi 10.1016/j.saa.2004.01.030

    Article  CAS  Google Scholar 

  21. Chityala, V.K., Kumar, K.S., Macha, R., Tigulla, P., and Shivaraj, Bioinorg. Chem. Appl., 2014. doi 10.1155/2014/691260

    Google Scholar 

  22. Bessy Raj, B.N., Kurup, M.R.P., and Suresh, E., Spectrochim. Acta, Part A, 2008, vol. 71, no. 4, p. 1253. doi 10.1016/j.saa.2008.03.025

    Article  CAS  Google Scholar 

  23. Kumar, M.P., Vamsikrishna, N., Ramesh, G., Subhashini, N.J.P., Nanubolu, J.B., and Shivaraj, J. Coord. Chem., 2017, vol. 70, no. 8, p. 1368. doi 10.1080/00958972.2017.1292503

    Article  CAS  Google Scholar 

  24. Arish, D. and Nair, M.S., J. Mol. Struct., 2010, vol. 983, no. 1, p. 112. doi 10.1016/j.molstruc.2010.08.040

    Article  CAS  Google Scholar 

  25. Han, J., Xing, Y., Wang, C., Hou, P., Bai, F., Zeng, X., Zhang, X., and Ge, M., J. Coord. Chem., 2009, vol. 62, no. 5, p. 745. doi 10.1080/00958970802326161

    Article  CAS  Google Scholar 

  26. Ahamed, M.A.R., Azarudeen, R.S., and Kani, N.M., Bioinorg. Chem. Appl., 2014, doi 10.1155/2014/764085

    Google Scholar 

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Correspondence to Shivaraj.

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Ganga Rajam, K., Kumar, M.P., Jyothi Kiran, K. et al. Mixed Ligand Complexes Derived from Semicarbazone Schiff Base and Heterocyclic Ligands: Structure and Antimicrobial Activity. Russ J Gen Chem 88, 1000–1008 (2018). https://doi.org/10.1134/S1070363218050274

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  • DOI: https://doi.org/10.1134/S1070363218050274

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