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Physicochemical Modeling of Sulfide Oxidation Processes in Tailing Dumps of the Kavalerovsky District and Their Impact on the Hydrosphere (Primorsky Krai)

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Abstract

Oxidation of tailings in the tailing dump of Vysokogorskoe deposit (Kavalerovsky district) in the temperature range from 0 to +45°C was simulated with successive exclusion of each of the sulfide minerals present therein (pyrite, pyrrhotite, galena, sphalerite, arsenopyrite, and chalcopyrite). The Eh-pH parameters for anthropogenic mineral formation were determined at different host rock–sulfide ratios (95: 5, 90: 10, 80: 20, 60: 40, 40: 60, 20: 80) in the tailings. Crystallization of supergene minerals was analyzed, qualitative and quantitative ionic compositions of solutions were determined, and their impact on the hydrosphere was assessed.

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Authors and Affiliations

  1. Far East Federal University, ul. Sukhanova 8, Vladivostok, 600091, Russia

    V. P. Zvereva & A. D. Pyatakov

  2. Far East Geological Institute, Far East Branch, Russian Academy of Science, pr. 100-letiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. P. Zvereva

  3. Pacific National University, ul. Tikhookeanskaya 136, Khabarovsk, 680035, Russia

    V. P. Zvereva

Authors
  1. V. P. Zvereva
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  2. A. D. Pyatakov
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Correspondence to V. P. Zvereva.

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Zvereva, V.P., Pyatakov, A.D. Physicochemical Modeling of Sulfide Oxidation Processes in Tailing Dumps of the Kavalerovsky District and Their Impact on the Hydrosphere (Primorsky Krai). Russ J Gen Chem 87, 3137–3143 (2017). https://doi.org/10.1134/S1070363217130059

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  • DOI: https://doi.org/10.1134/S1070363217130059

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